Impact of device design on the electronic and optoelectronic properties of integrated Ru-terpyridine complexes

• Max Mennicken,
• Sophia Katharina Peter,
• Corinna Kaulen,
• Ulrich Simon and
• Silvia Karthäuser

Beilstein J. Nanotechnol. 2022, 13, 219–229, doi:10.3762/bjnano.13.16

• of gold nanoparticles and contacted by nanoelectrodes. The resulting small-area nanodevices were thoroughly electrically characterized as a function of temperature and light exposure. Differences in the resulting device conductance could be attributed to the device design and the respective transport

• nanoelectrodes separated by gaps of 8 to 20 nm. They are fabricated by electron beam lithography (EBL) in a lift-off process while using a self-aligned Al2O3 hard mask to define the nanogap size [20][21]. The resulting nanoelectrode pairs are used for the on-chip preparation of Ru(TP)2-complex wires according to

• the wire-growth protocol developed recently and, thus, to assemble Ru(TP)2-complex wire nanodevices [19]. Additionally, we will use our already successfully applied approach to fabricate nanodevices from ligand-stabilized gold nanoparticles (AuNPs) immobilized between nanoelectrodes [21][22][23][24

Uniform arrays of gold nanoelectrodes with tuneable recess depth

• Elena O. Gordeeva,
• Ilya V. Roslyakov,
• Alexey P. Leontiev,
• Alexey A. Klimenko and
• Kirill S. Napolskii

Beilstein J. Nanotechnol. 2021, 12, 957–964, doi:10.3762/bjnano.12.72

• surface of the porous template and the top surface of the nanoelectrodes. A set of complementary techniques, including chronoamperometry, coulometry, and scanning electron microscopy, are used to characterize the nanoelectrode arrays. The number of active nanoelectrodes is experimentally measured. The

• one to create NEAs with a narrow distribution of geometrical parameters (diameter of electrodes and distance between them) that can be tuned over a wide range [20][21]. The first attempt to prepare recessed nanoelectrodes based on AAO templates was made in 2002 [9]. The authors used commercially

• available porous AAO films with a highly irregular structure to prepare the Au nanowell electrodes with 600 nm depth by templated electrodeposition. It is worth noting that the percentage of nanoelectrodes in the array that are involved in electrochemical reactions has not been discussed in detail. At the

Nematic liquid crystal alignment on subwavelength metal gratings

• Irina V. Kasyanova,
• Artur R. Geivandov,
• Vladimir V. Artemov,
• Maxim V. Gorkunov and
• Serguei P. Palto

Beilstein J. Nanotechnol. 2018, 9, 42–47, doi:10.3762/bjnano.9.6

• ]. Meanwhile, these gratings can also be used as nanoelectrodes, which allow the LC to be driven by an electric field, enabling a very fast electro-optical effect due to the influence of the adjacent liquid crystal layer on the plasmonic resonance [10]. In all of these effects, the alignment of LC molecules on

Stable Au–C bonds to the substrate for fullerene-based nanostructures

• Taras Chutora,
• Jesús Redondo,
• Bruno de la Torre,
• Martin Švec,
• Pavel Jelínek and
• Héctor Vázquez

Beilstein J. Nanotechnol. 2017, 8, 1073–1079, doi:10.3762/bjnano.8.109

• electronic circuit is a small molecule connected to two nanoelectrodes, and molecular chemical properties determine the characteristics of current flow. The reliable preparation and characterization of such nanostructures has been made possible by state-of-the-art scanning probe methods with which individual

Dielectrophoresis of gold nanoparticles conjugated to DNA origami structures

• Anja Henning-Knechtel,
• Matthew Wiens,
• Mathias Lakatos,
• Andreas Heerwig,
• Frieder Ostermaier,
• Nora Haufe and
• Michael Mertig

Beilstein J. Nanotechnol. 2016, 7, 948–956, doi:10.3762/bjnano.7.87

• that DNA origami trapping can be considerably influenced by the attachment of nanometer-sized, polarizable particles that act as supported floating nanoelectrodes, and thus, as field concentrators. Results and Discussion For our studies, we focused on a 414 nm long, tubular DNA-origami structure, a so

• the need for increasing the applied voltages, these studies have shown that floating nanoelectrodes increase local DEP forces by orders of magnitudes. In the floating-electrode DEP (feDEP) approach, a local non-uniform field is obtained by introducing a passive, metallic element into an imposed field

Functional fusion of living systems with synthetic electrode interfaces

• Oskar Staufer,
• Sebastian Weber,
• C. Peter Bengtson,
• Hilmar Bading,
• Joachim P. Spatz and
• Amin Rustom

Beilstein J. Nanotechnol. 2016, 7, 296–301, doi:10.3762/bjnano.7.27

• : biointerface; biosensor; energy harvesting; nanoelectrodes; Physarum polycephalum; Findings The formation process of nanoelectrode interfaces (NEIs) was based on track-etch template synthesis as schematically shown in Figure 1a. First, monocrystalline gold (Au) nanowires in parallel arrangement featuring

• system was stable in most cases for the complete observation period, which lasted several days and sometimes up to one week (Supporting Information File 1, Figure S1b). In a few cases, the potential dropped more or less slowly, most likely reflecting successive ejection of nanoelectrodes from the

Electron and heat transport in porphyrin-based single-molecule transistors with electro-burnt graphene electrodes

• Hatef Sadeghi,
• Sara Sangtarash and
• Colin J. Lambert

Beilstein J. Nanotechnol. 2015, 6, 1413–1420, doi:10.3762/bjnano.6.146

• ), gold is widely employed [8] as the electrode material in order to avoid oxidation and degradation of the electrodes and because of its high atomic mobility. However, gold nanoelectrodes are unstable at room temperature [6]. Recently, an alternative strategy for the fabrication of stable electrodes with

Hollow plasmonic antennas for broadband SERS spectroscopy

• Gabriele C. Messina,
• Mario Malerba,
• Pierfrancesco Zilio,
• Ermanno Miele,
• Michele Dipalo,
• Lorenzo Ferrara and
• Francesco De Angelis

Beilstein J. Nanotechnol. 2015, 6, 492–498, doi:10.3762/bjnano.6.50

• important breakthrough, since it enables the combination of plasmonic with electrical functionalities: the antennas can be used also as nanoelectrodes for photovoltaic, electro-photochemical catalysis, optoelectronic and bio-electrochemical devices. As a final remark, it should also be considered that the

Carbon-based smart nanomaterials in biomedicine and neuroengineering

• Antonina M. Monaco and
• Michele Giugliano

Beilstein J. Nanotechnol. 2014, 5, 1849–1863, doi:10.3762/bjnano.5.196

• in brain implants, are within reach thanks to the advancements in nanotechnology. In particular, carbon-based nanostructured materials, such as graphene, carbon nanotubes (CNTs) and nanodiamonds (NDs), have demonstrated to be highly promising materials for designing and fabricating nanoelectrodes and

• high mechanical strength [7], while at the same time exhibiting a very low weight. Combined with a large surface area, these electronic and mechanical properties give CNTs a great potential for microelectronics and optics, and also for biomedical applications (e.g., as nanoelectrodes for neural

Review of nanostructured devices for thermoelectric applications

• Giovanni Pennelli

Beilstein J. Nanotechnol. 2014, 5, 1268–1284, doi:10.3762/bjnano.5.141

• for increasing this value up to several hundreds of μV/K, such as plasma etching treatments [11], have been carried out successfully. A great enhancement of S has been predicted in graphene nanoribbons [14][15], and the use of a suitable array of nanoelectrodes has been proposed for obtaining a giant

Controlled deposition and combing of DNA across lithographically defined patterns on silicon

• Zeinab Esmail Nazari and
• Leonid Gurevich

Beilstein J. Nanotechnol. 2013, 4, 72–76, doi:10.3762/bjnano.4.8

• –peptide conjugates, while the original recipe was proven to be ineffective for combing these materials [11]. Figure 3 represents the topography of combed dsDNA conjugated with various peptides. Combing across nanoelectrodes was also possible for DNA–peptide conjugates (Figure 3e). The gas-phase deposition

• before gas-phase deposition). Interestingly, on the nanoelectrodes, the observed density of deposited and combed DNA was significantly lower than that on flat silicon. This could be mainly attributed to the absence of silane functionalization on the platinum electrodes, which is also indicated by the

• recipes were ineffective for combing these materials. In the case of nanoelectrodes, despite the fact that the movement of the meniscus is disturbed when passing over the electrodes, DNA molecules were still combed across them in the desired direction, i.e., perpendicular to the electrodes. Conclusion In

Electron-beam patterned self-assembled monolayers as templates for Cu electrodeposition and lift-off

• Zhe She,
• Andrea DiFalco,
• Georg Hähner and
• Manfred Buck

Beilstein J. Nanotechnol. 2012, 3, 101–113, doi:10.3762/bjnano.3.11

• formation of nuclei and mushroom structures at defects in the SAM (Figure 1b). At this point the electrode surface can be described by a statistical array of nanoelectrodes. Subsequently the current becomes transport-limited and, therefore, passes a maximum after a given time, which becomes shorter with