Supporting Information
Experimental details and characterization data for all products; determination of enantiomeric ratios and determination of major calix[4]arene diastereomer.
| Supporting Information File 1: Synthetic procedures and spectral data for all new compounds. | ||
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Cite the Following Article
Inherently chiral calix[4]arenes via oxazoline directed ortholithiation: synthesis and probe of chiral space
Simon A. Herbert, Laura J. van Laeren, Dominic C. Castell and Gareth E. Arnott
Beilstein J. Org. Chem. 2014, 10, 2751–2755.
https://doi.org/10.3762/bjoc.10.291
How to Cite
Herbert, S. A.; van Laeren, L. J.; Castell, D. C.; Arnott, G. E. Beilstein J. Org. Chem. 2014, 10, 2751–2755. doi:10.3762/bjoc.10.291
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- Durmaz, M.; Halay, E.; Bozkurt, S. Recent applications of chiral calixarenes in asymmetric catalysis. Beilstein journal of organic chemistry 2018, 14, 1389–1412. doi:10.3762/bjoc.14.117
- Karpus, A.; Yesypenko, O. A.; Boiko, V. I.; Daran, J.-C.; Voitenko, Z.; Kalchenko, V. I.; Manoury, E. Synthesis of an Enantiomerically Pure Inherently Chiral Calix[4]Arene Phosphonic Acid and Its Evaluation as an Organocatalyst. The Journal of organic chemistry 2018, 83, 1146–1153. doi:10.1021/acs.joc.7b02312
- Arnott, G. E. Inherently Chiral Calixarenes: Synthesis and Applications. Chemistry (Weinheim an der Bergstrasse, Germany) 2017, 24, 1744–1754. doi:10.1002/chem.201703367
- Castell, D. C.; Lesotho, N.; Nikolayenko, V. I.; Arnott, G. E. Inherently Chiral Calix[4]arenes: A Chiral Sulfoxide as an Ortholithiation Director. European Journal of Organic Chemistry 2017, 2017, 4328–4333. doi:10.1002/ejoc.201700701
- Kundrat, O.; Lhoták, P. Meta Substitution of Calixarenes. Calixarenes and Beyond; Springer International Publishing, 2016; pp 43–73. doi:10.1007/978-3-319-31867-7_3
- Karpus, A.; Yesypenko, O. A.; Boiko, V. I.; Poli, R.; Daran, J.-C.; Voitenko, Z.; Kalchenko, V. I.; Manoury, E. Chiral Phosphinoferrocenyl-Calixarenes. European Journal of Organic Chemistry 2016, 2016, 3386–3394. doi:10.1002/ejoc.201600208
- Boyko, V. I.; Rozhenko, A. B.; Pirozhenko, V. V.; Shishkina, S. V.; Shishkin, O. V.; Kalchenko, V. I. Diastereoselective reaction of 1,3-dihydroxy calixarene with acylisocyanates: new and easy approach for preparing inherently chiral calyx[4]arenes. Structural Chemistry 2016, 27, 261–272. doi:10.1007/s11224-015-0706-5
