A T-shape diphosphinoborane palladium(0) complex

Patrick Steinhoff and Michael E. Tauchert
Beilstein J. Org. Chem. 2016, 12, 1573–1576. https://doi.org/10.3762/bjoc.12.152

Supporting Information

Supporting Information File 1: Experimental procedures and characterization data; crystallographic information for 9; 1H, 11B, 13C and 31P NMR spectra.
Format: PDF Size: 1.2 MB Download
Supporting Information File 2: CIF file of 9, CCDC 1471929.
Format: CIF Size: 22.5 KB Download

Cite the Following Article

A T-shape diphosphinoborane palladium(0) complex
Patrick Steinhoff and Michael E. Tauchert
Beilstein J. Org. Chem. 2016, 12, 1573–1576. https://doi.org/10.3762/bjoc.12.152

How to Cite

Steinhoff, P.; Tauchert, M. E. Beilstein J. Org. Chem. 2016, 12, 1573–1576. doi:10.3762/bjoc.12.152

Download Citation

Citation data can be downloaded as file using the "Download" button or used for copy/paste from the text window below.
Citation data in RIS format can be imported by all major citation management software, including EndNote, ProCite, RefWorks, and Zotero.

Presentation Graphic

Picture with graphical abstract, title and authors for social media postings and presentations.
Format: PNG Size: 473.4 KB Download

Citations to This Article

Up to 20 of the most recent references are displayed here.

Scholarly Works

  • Wehmeyer, F.-U.; Langer, R. A hampered oxidative addition of pre-coordinated pincer ligands can favour alternative pathways of activation. Chemical communications (Cambridge, England) 2023, 59, 6004–6007. doi:10.1039/d3cc00874f
  • Eltester, M. A.; Gildenast, H.; Rabatinová, K.; Pütz, C.; Cremer, C.; Lanzerath, P.; Schroers, J. P.; Tauchert, M. E. Au → M bonds promote catalytic alkyne hydrofunctionalisation. Chemical communications (Cambridge, England) 2023, 59, 5459–5462. doi:10.1039/d3cc01008b
  • Schroers, J. P.; Kliemann, M. N.; Kollath, J. M. A.; Tauchert, M. E. How Cationic Metalloligands Affect the Coordination of Lewis Basic Ligands in RhI Complexes. Organometallics 2021, 40, 3893–3906. doi:10.1021/acs.organomet.1c00449
  • Cabeza, J. A.; Fernández, I.; García-Álvarez, P.; García-Soriano, R.; Laglera-Gándara, C. J.; Toral, R. Stannylenes based on pyrrole-phosphane and dipyrromethane-diphosphane scaffolds: syntheses and behavior as precursors to PSnP pincer palladium(II), palladium(0) and gold(I) complexes. Dalton transactions (Cambridge, England : 2003) 2021, 50, 16122–16132. doi:10.1039/d1dt02967c
  • Furan, S.; Molkenthin, M.; Winkels, K.; Lork, E.; Mebs, S.; Hupf, E.; Beckmann, J. Tris(6-diphenylphosphinoacenaphth-5-yl)gallium: Z-Type Ligand and Transmetalation Reagent. Organometallics 2021, 40, 3785–3796. doi:10.1021/acs.organomet.1c00522
  • Huynh, W.; Taylor, J. W.; Harman, W. H.; Conley, M. P. Solid-state 11B NMR studies of coinage metal complexes containing a phosphine substituted diboraanthracene ligand. Dalton transactions (Cambridge, England : 2003) 2021, 50, 14855–14863. doi:10.1039/d1dt02981a
  • Boudjelel, M.; Sadek, O.; Mallet-Ladeira, S.; García-Rodeja, Y.; Carrizo, E. D. S.; Miqueu, K.; Bouhadir, G.; Bourissou, D. Phosphine–Borane Ligands Induce Chemoselective Activation and Catalytic Coupling of Acyl Chlorides at Palladium. ACS Catalysis 2021, 11, 3822–3829. doi:10.1021/acscatal.0c04287
  • Tiddens, M. R.; Moret, M.-E. Metal-Ligand Cooperation at Phosphine-Based Acceptor Pincer Ligands. Topics in Organometallic Chemistry; Springer Berlin Heidelberg, 2020; pp 25–69. doi:10.1007/3418_2020_70
  • Cabeza, J. A.; García-Álvarez, P.; Laglera-Gándara, C. J.; Pérez-Carreño, E. A Z-type PGeP pincer germylene ligand in a T-shaped palladium(0) complex. Chemical communications (Cambridge, England) 2020, 56, 14095–14097. doi:10.1039/d0cc06614a
  • Ritter, F.; John, L.; Schindler, T.; Schroers, J. P.; Teeuwen, S.; Tauchert, M. E. Evaluation of Pd→B Interactions in Diphosphinoborane Complexes and Impact on Inner-Sphere Reductive Elimination. Chemistry (Weinheim an der Bergstrasse, Germany) 2020, 26, 13436–13444. doi:10.1002/chem.202001189
  • Vogt, M.; Langer, R. The Pincer Platform Beyond Classical Coordination Patterns. European Journal of Inorganic Chemistry 2020, 2020, 3885–3898. doi:10.1002/ejic.202000513
  • Kameo, H.; Yamamoto, J.; Asada, A.; Nakazawa, H.; Matsuzaka, H.; Bourissou, D. Palladium–Borane Cooperation: Evidence for an Anionic Pathway and Its Application to Catalytic Hydro‐/Deutero‐dechlorination. Angewandte Chemie 2019, 131, 18959–18963. doi:10.1002/ange.201909675
  • Kameo, H.; Yamamoto, J.; Asada, A.; Nakazawa, H.; Matsuzaka, H.; Bourissou, D. Palladium-Borane Cooperation: Evidence for an Anionic Pathway and Its Application to Catalytic Hydro-/Deutero-dechlorination. Angewandte Chemie (International ed. in English) 2019, 58, 18783–18787. doi:10.1002/anie.201909675
  • Cao, Y.; Shih, W.-C.; Bhuvanesh, N.; Ozerov, O. V. Silver halide complexes of a borane/bis(phosphine) ligand. Dalton transactions (Cambridge, England : 2003) 2019, 48, 9959–9961. doi:10.1039/c9dt02100k
  • Hill, A. F.; Schwich, T.; Xiong, Y. 5-Mercaptotetrazolyl-derived metallaboratranes. Dalton transactions (Cambridge, England : 2003) 2019, 48, 2367–2376. doi:10.1039/c8dt05036h
  • Ma, C.; Hill, A. F. Methimazolyl based diptych bicyclo-[3.3.0]-ruthenaboratranes. Dalton transactions (Cambridge, England : 2003) 2019, 48, 1976–1992. doi:10.1039/c8dt04813d
  • Steinhoff, P.; Paul, M.; Schroers, J. P.; Tauchert, M. E. Highly efficient palladium-catalysed carbon dioxide hydrosilylation employing PMP ligands. Dalton transactions (Cambridge, England : 2003) 2019, 48, 1017–1022. doi:10.1039/c8dt03777a
  • St J. Foreman, M. R.; Hill, A. F.; Ma, C.; Tshabang, N.; White, A. J. P. Synthesis and ligand substitution reactions of κ4-B,S,S',S''-ruthenaboratranes. Dalton transactions (Cambridge, England : 2003) 2018, 48, 209–219. doi:10.1039/c8dt04278k
  • Steinhoff, P.; Steinbock, R.; Friedrich, A.; Schieweck, B. G.; Cremer, C.; Truong, K.-N.; Tauchert, M. E. Synthesis and properties of heterobimetallic rhodium complexes featuring LiI, CuI or ZnII as a Lewis acidic metalloligand. Dalton transactions (Cambridge, England : 2003) 2018, 47, 10439–10442. doi:10.1039/c8dt01267a
  • Schuhknecht, D.; Ritter, F.; Tauchert, M. E. Isolation and properties of a palladium PBP pincer complex featuring an ambiphilic boryl site. Chemical communications (Cambridge, England) 2016, 52, 11823–11826. doi:10.1039/c6cc07079e
Other Beilstein-Institut Open Science Activities