Synthesis and crystal structures of multifunctional tosylates as basis for star-shaped poly(2-ethyl-2-oxazoline)s

Richard Hoogenboom, Martin W. M. Fijten, Guido Kickelbick and Ulrich S. Schubert
Beilstein J. Org. Chem. 2010, 6, 773–783. https://doi.org/10.3762/bjoc.6.96

Supporting Information

Supporting Information File 1: Details of the reported crystal structures.
Format: PDF Size: 128.2 KB Download

Cite the Following Article

Synthesis and crystal structures of multifunctional tosylates as basis for star-shaped poly(2-ethyl-2-oxazoline)s
Richard Hoogenboom, Martin W. M. Fijten, Guido Kickelbick and Ulrich S. Schubert
Beilstein J. Org. Chem. 2010, 6, 773–783. https://doi.org/10.3762/bjoc.6.96

How to Cite

Hoogenboom, R.; Fijten, M. W. M.; Kickelbick, G.; Schubert, U. S. Beilstein J. Org. Chem. 2010, 6, 773–783. doi:10.3762/bjoc.6.96

Download Citation

Citation data can be downloaded as file using the "Download" button or used for copy/paste from the text window below.
Citation data in RIS format can be imported by all major citation management software, including EndNote, ProCite, RefWorks, and Zotero.

Citations to This Article

Up to 20 of the most recent references are displayed here.

Scholarly Works

  • Engel, N.; Hoffmann, T.; Behrendt, F.; Liebing, P.; Weber, C.; Gottschaldt, M.; Schubert, U. S. Cryogels Based on Poly(2-oxazoline)s through Development of Bi- and Trifunctional Cross-Linkers Incorporating End Groups with Adjustable Stability. Macromolecules 2024, 57, 2915–2927. doi:10.1021/acs.macromol.3c02030
  • Kozina, N.; Blokhin, A.; Kirila, T.; Razina, A.; Bursian, A.; Kurlykin, M.; Filippov, A.; Tenkovtsev, A. Synthesis of novel star-shaped calix[4]arene-based poly(2-oxazoline)s and study of their complexation with curcumin. Materials Today Communications 2023, 34, 105403. doi:10.1016/j.mtcomm.2023.105403
  • Leiske, M. N. Poly(2-oxazoline)-derived star-shaped polymers as potential materials for biomedical applications: A review. European Polymer Journal 2023, 185, 111832. doi:10.1016/j.eurpolymj.2023.111832
  • Blokhin, A. N.; Dudkina, M. M.; Tenkovtsev, A. V. Ionic Ring-Opening Polymerization for the Synthesis of Star-Shaped Polymers. Polymer Science, Series C 2022, 64, 161–175. doi:10.1134/s1811238222700187
  • Van Guyse, J. F. R.; Hoogenboom, R. doi:10.1002/9783527815562.mme0012
  • Blokhin, A. N.; Razina, A. B.; Tenkovtsev, A. V. Novel Amphiphilic Star-Shaped Poly(2-Oxazoline)s with Calix[4]Arene Branching Center. Key Engineering Materials 2021, 899, 300–308. doi:10.4028/www.scientific.net/kem.899.300
  • Bullet, J.-R.; Korchagina, E.; Winnik, F. M. High-Sensitivity Microcalorimetry and Gel Permeation Chromatography in Tandem Reveal the Complexity of the Synthesis of Poly-(2-isopropyl-2-oxazoline) Stars. Macromolecules 2021, 54, 6161–6170. doi:10.1021/acs.macromol.1c00746
  • Sánchez-Fernández, J.; Cué-Sampedro, R. Biopolymers and their composites for drug delivery. Green Biocomposites for Biomedical Engineering; Elsevier, 2021; pp 363–387. doi:10.1016/b978-0-12-821553-1.00018-1
  • Akhan, S.; Oktay, B.; Ozdemir, O. K.; Madakbaş, S.; Apohan, N. K. Polyurethane graphene nanocomposites with self-healing properties by azide-alkyne click reaction. Materials Chemistry and Physics 2020, 254, 123315. doi:10.1016/j.matchemphys.2020.123315
  • Moura, S. L.; Martí, M.; Pividori, M. I. Matrix Effect in the Isolation of Breast Cancer-Derived Nanovesicles by Immunomagnetic Separation and Electrochemical Immunosensing-A Comparative Study. Sensors (Basel, Switzerland) 2020, 20, 965. doi:10.3390/s20040965
  • Plet, L.; Delecourt, G.; Hanafi, M.; Pantoustier, N.; Pembouong, G.; Midoux, P.; Bennevault, V.; Guégan, P. Controlled star poly(2-oxazoline)s: Synthesis, characterization. European Polymer Journal 2020, 122, 109323. doi:10.1016/j.eurpolymj.2019.109323
  • Lezov, A. A.; Gubarev, A. S.; Mikhailova, M. A.; Lezova, A. A.; Mikusheva, N. G.; Kalganov, V. D.; Dudkina, M. M.; Tenkovtsev, A. V.; Nekrasova, T. N.; Andreeva, L. N.; Saprykina, N.; Smyslov, R. Y.; Gorshkova, Y.; Romanov, D. P.; Höppener, S.; Perevyazko, I.; Tsvetkov, N. V. Star-Shaped Poly(2-ethyl-2-oxazoline) and Poly(2-isopropyl-2-oxazoline) with Central Thiacalix[4]Arene Fragments: Reduction and Stabilization of Silver Nanoparticles. Polymers 2019, 11, 2006. doi:10.3390/polym11122006
  • Lezov, A. A.; Gubarev, A. S.; Podseval’nikova, A. N.; Senchukova, A. S.; Lebedeva, E. V.; Dudkina, M. M.; Tenkovtsev, A. V.; Nekrasova, T. N.; Andreeva, L. N.; Smyslov, R. Y.; Gorshkova, Y. E.; Kopitsa, G. P.; Rǎdulescu, A.; Pipich, V.; Tsvetkov, N. V. Temperature-responsive star-shaped poly(2-ethyl-2-oxazoline) and poly(2-isopropyl-2-oxazoline) with central thiacalix[4]arene fragments: structure and properties in solutions. Colloid and Polymer Science 2019, 297, 285–296. doi:10.1007/s00396-018-4458-9
  • Tenkovtsev, A. V.; Amirova, A.; Filippov, A. P. Temperature‐Responsive Polymers; Wiley, 2018; pp 67–92. doi:10.1002/9781119157830.ch3
  • Verbraeken, B.; Monnery, B. D.; Lava, K.; Hoogenboom, R. doi:10.1002/0471440264.pst626.pub2
  • Amirova, A.; Tobolina, A.; Kirila, T.; Blokhin, A.; Razina, A. B.; Tenkovtsev, A. V.; Filippov, A. P. Influence of core configuration and arm structure on solution properties of new thermosensitive star-shaped poly(2-alkyl-2-oxazolines). International Journal of Polymer Analysis and Characterization 2018, 23, 278–285. doi:10.1080/1023666x.2018.1441483
  • Alvaradejo, G. G.; Glassner, M.; Hoogenboom, R.; Delaittre, G. Maleimide end-functionalized poly(2-oxazoline)s by the functional initiator route: synthesis and (bio)conjugation. RSC advances 2018, 8, 9471–9479. doi:10.1039/c8ra00948a
  • Ali, M. W.; Gao, Y.; Siddiq, M.; Ye, X. A Novel Initiator Containing Alkyne Group for the Polymerization of 2-Ethyl-2-oxazoline. Chinese Journal of Chemical Physics 2018, 31, 77–84. doi:10.1063/1674-0068/31/cjcp1709171
  • Wilson, P.; Ke, P. C.; Davis, T. P.; Kempe, K. Poly(2-oxazoline)-based micro- and nanoparticles: A review. European Polymer Journal 2017, 88, 486–515. doi:10.1016/j.eurpolymj.2016.09.011
  • Verbraeken, B.; Monnery, B. D.; Lava, K.; Hoogenboom, R. Encyclopedia of Polymer Science and Technology - The chemistry of poly(2-oxazoline)s ☆. European Polymer Journal 2017, 88, 451–469. doi:10.1016/j.eurpolymj.2016.11.016

Patents

  • DELANEY JR JOSEPH T; GROSSO PAUL V; KUMMAILIL JOHN; DYNDIKOVA TATYANA; REHDER CAREY. Multi-armed polyoxazolines and compositions, systems and methods pertaining to the same. US 11807720 B2, Nov 7, 2023.
  • DELANEY JR; GROSSO PAUL V; KUMMAILIL JOHN; DYNDIKOVA TATYANA; REHDER CAREY. MULTI-ARMED POLYOXAZOLINES AND COMPOSITIONS, SYSTEMS AND METHODS PERTAINING TO THE SAME. WO 2021041222 A1, March 4, 2021.
  • BRASLAU REBECCA L; HIGA CHAD M. Non-migratory internal plasticizers attached to a pendant covalent linkage. US 10927245 B2, Feb 23, 2021.
Other Beilstein-Institut Open Science Activities