Hoveyda–Grubbs type metathesis catalyst immobilized on mesoporous molecular sieves MCM-41 and SBA-15

Scholarly Works

• Shinde, T.; Jirimali, H. Ring closing metathesis reaction of citronellene by utilising simple mesoporousSBA-15 loaded ruthenium alkylidene supercatalyst. Research Square Platform LLC 2024. doi:10.21203/rs.3.rs-3926251/v1
• Nieres, P. D.; Vaillard, V. A.; Zelín, J.; Neuman, N. I.; Trasarti, A. F.; Apesteguía, C. R.; Vaillard, S. E. Stability of a Silica‐Supported Second Generation Hoveyda‐Grubbs Catalyst Under Atmospheric Conditions: Experimental and Computational Studies. ChemCatChem 2023, 15. doi:10.1002/cctc.202300010
• Zaera, F. Designing Sites in Heterogeneous Catalysis: Are We Reaching Selectivities Competitive With Those of Homogeneous Catalysts?. Chemical reviews 2022, 122, 8594–8757. doi:10.1021/acs.chemrev.1c00905
• Monsigny, L.; Czarnocki, S.; Sienkiewicz, M.; Kopcha, W.; Frankfurter, R.; Vogt, C.; Solodenko, W.; Kajetanowicz, A.; Kirschning, A.; Grela, K. Ruthenium Complex Bearing a Hydroxy Group Functionalised N‐Heterocyclic Carbene Ligand – A Universal Platform for Synthesis of Tagged and Immobilised Catalysts for Olefin Metathesis. European Journal of Organic Chemistry 2021, 2021, 6424–6434. doi:10.1002/ejoc.202101092
• Balcar, H.; Čejka, J. SBA-15 as a Support for Effective Olefin Metathesis Catalysts. Catalysts 2019, 9, 743. doi:10.3390/catal9090743
• Hasib-ur-Rahman, M.; Hamoudi, S.; Belkacemi, K. Heterogeneous olefin-metathesis: Comparative perspective of the activity with respect to unsaturated fatty acid methyl esters. The Canadian Journal of Chemical Engineering 2017, 95, 1850–1863. doi:10.1002/cjce.22845
• Zhong, R.; Lindhorst, A. C.; Groche, F. J.; Kühn, F. E. Immobilization of N-Heterocyclic Carbene Compounds: A Synthetic Perspective. Chemical reviews 2017, 117, 1970–2058. doi:10.1021/acs.chemrev.6b00631
• Dewaele, A.; Verpoort, F.; Sels, B. F. Opportunities of Immobilized Homogeneous Metathesis Complexes as Prominent Heterogeneous Catalysts. ChemCatChem 2016, 8, 3010–3030. doi:10.1002/cctc.201600591
• Nieres, P. D.; Zelin, J.; Trasarti, A. F.; Apesteguia, C. R. Heterogeneous catalysis for valorisation of vegetable oils via metathesis reactions: ethenolysis of methyl oleate. Catalysis Science & Technology 2016, 6, 6561–6568. doi:10.1039/c6cy01214k
• Dewaele, A.; Van Berlo, B.; Dijkmans, J.; Jacobs, P.; Sels, B. F. Immobilized Grubbs catalysts on mesoporous silica materials: insight into support characteristics and their impact on catalytic activity and product selectivity. Catalysis Science & Technology 2016, 6, 2580–2597. doi:10.1039/c5cy01897h
• Balcar, H.; Žilková, N.; Kubů, M.; Mazur, M.; Bastl, Z.; Čejka, J. Ru complexes of Hoveyda-Grubbs type immobilized on lamellar zeolites: activity in olefin metathesis reactions. Beilstein journal of organic chemistry 2015, 11, 2087–2096. doi:10.3762/bjoc.11.225
• Zelin, J.; Nieres, P. D.; Trasarti, A. F.; Apesteguia, C. R. Valorisation of vegetable oils via metathesis reactions on solid catalysts: Cross-metathesis of methyl oleate with 1-hexene. Applied Catalysis A: General 2015, 502, 410–417. doi:10.1016/j.apcata.2015.06.021
• Tosh, D. K.; Padia, J.; Salvemini, D.; Jacobson, K. A. Efficient, large-scale synthesis and preclinical studies of MRS5698, a highly selective A3 adenosine receptor agonist that protects against chronic neuropathic pain. Purinergic signalling 2015, 11, 371–387. doi:10.1007/s11302-015-9459-2
• Pastva, J.; Skowerski, K.; Czarnocki, S. J.; Žilková, N.; Čejka, J.; Bastl, Z.; Balcar, H. Ru-Based Complexes with Quaternary Ammonium Tags Immobilized on Mesoporous Silica as Olefin Metathesis Catalysts. ACS Catalysis 2014, 4, 3227–3236. doi:10.1021/cs500796u
• Buchmeiser, M. R. Olefin Metathesis; Wiley, 2014; pp 495–514. doi:10.1002/9781118711613.ch20
• Skowerski, K.; Gułajski, Ł. Olefin Metathesis; Wiley, 2014; pp 559–571. doi:10.1002/9781118711613.ch25
• Shinde, T.; Varga, V.; Polášek, M.; Horáček, M.; Žilková, N.; Balcar, H. Metathesis of cardanol over Ru catalysts supported on mesoporous molecular sieve SBA-15. Applied Catalysis A: General 2014, 478, 138–145. doi:10.1016/j.apcata.2014.03.036
• Van, C. T.; Zdobinsky, T.; Seebohm, G.; Nennstiel, D.; Zerbe, O.; Scherkenbeck, J. Structural Prerequisites for Receptor Binding of Helicokinin I, a Diuretic Insect Neuropeptide from Helicoverpa zea. European Journal of Organic Chemistry 2014, 2014, 2714–2725. doi:10.1002/ejoc.201301773
• Zelin, J.; Trasarti, A. F.; Apesteguia, C. R. Self-metathesis of methyl oleate on silica-supported Hoveyda–Grubbs catalysts. Catalysis Communications 2013, 42, 84–88. doi:10.1016/j.catcom.2013.08.007
• Balcar, H.; Čejka, J. Mesoporous molecular sieves as advanced supports for olefin metathesis catalysts. Coordination Chemistry Reviews 2013, 257, 3107–3124. doi:10.1016/j.ccr.2013.07.026

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