1-n-Butyl-3-methylimidazolium-2-carboxylate: a versatile precatalyst for the ring-opening polymerization of ε-caprolactone and rac-lactide under solvent-free conditions

Scholarly Works

• Akkravijitkul, N.; Cheechana, N.; Rithchumpon, P.; Junpirom, T.; Limwanich, W.; Nalampang, K.; Thavornyutikarn, P.; Punyodom, W.; Meepowpan, P. Scalable and Room-Temperature Ring-Opening Polymerization of ε-Caprolactone Catalyzed by Active Lithium Tetramethylene-Tethered Bis[N-(N'-butylimidazol-2-ylidene)] N-Heterocyclic Carbene as a Lewis Acid Organocatalyst. The Journal of organic chemistry 2022, 87, 12052–12064. doi:10.1021/acs.joc.2c01062
• Gubin, A.; Sukhanov, P.; Kushnir, A.; Shikhaliev, K.; Potapov, M.; Kovaleva, E. Ionic-liquid-modified magnetite nanoparticles for MSPE-GC-MS determination of 2,4-D butyl ester and its metabolites in water, soil, and bottom sediments. Environmental Nanotechnology, Monitoring & Management 2022, 17, 100652. doi:10.1016/j.enmm.2022.100652
• Guillaume, S. M. Chapter 6:Organic Catalysis for the Polymerization of Lactide and Related Cyclic Diesters. Organic Catalysis for Polymerisation; The Royal Society of Chemistry, 2018; pp 224–273. doi:10.1039/9781788015738-00224
• Lambert, R.; Vignolle, J.; Taton, D. N‐Heterocyclic Carbenes in Organocatalysis; Wiley, 2018; pp 309–344. doi:10.1002/9783527809042.ch11
• Rezayan, A. H.; Firoozi, N.; Kheirjou, S.; Rezaei, S. J. T.; Nabid, M. R. Synthesis and Characterization of Biodegradable Semi-Interpenetrating Polymer Networks Based on Star-Shaped Copolymers of ɛ-Caprolactone and Lactide. Iranian journal of pharmaceutical research : IJPR 2017, 16, 63–73.
• Reitz, A. K.; Sun, Q.; Wilhelm, R.; Kuckling, D. The use of stable carbene‐CO2 adducts for the polymerization of trimethylene carbonate. Journal of Polymer Science Part A: Polymer Chemistry 2016, 55, 820–829. doi:10.1002/pola.28432
• Ottou, W. N.; Sardon, H.; Mecerreyes, D.; Vignolle, J.; Taton, D. Update and challenges in organo-mediated polymerization reactions. Progress in Polymer Science 2016, 56, 64–115. doi:10.1016/j.progpolymsci.2015.12.001
• Stewart, J. A.; Drexel, R.; Arstad, B.; Reubsaet, E.; Weckhuysen, B. M.; Bruijnincx, P. C. A. Homogeneous and heterogenised masked N-heterocyclic carbenes for bio-based cyclic carbonate synthesis. Green Chemistry 2016, 18, 1605–1618. doi:10.1039/c5gc02046h
• Bigot, S.; Daghrir, M.; Mhanna, A.; Boni, G.; Pourchet, S.; Lecamp, L.; Plasseraud, L. Undecylenic acid: A tunable bio-based synthon for materials applications. European Polymer Journal 2016, 74, 26–37. doi:10.1016/j.eurpolymj.2015.11.008
• Naumann, S.; Dove, A. P. N-Heterocyclic carbenes as organocatalysts for polymerizations: trends and frontiers. Polymer Chemistry 2015, 6, 3185–3200. doi:10.1039/c5py00145e
• Naumann, S.; Buchmeiser, M. R. Liberation of N-heterocyclic carbenes (NHCs) from thermally labile progenitors: protected NHCs as versatile tools in organo- and polymerization catalysis. Catal. Sci. Technol. 2014, 4, 2466–2479. doi:10.1039/c4cy00344f
• Reitz, A.; Wilhelm, R.; Kuckling, D. Ring Opening Polymerization of Organic Carbonates Using CO2 ‐ Carbene Adducts as Effective Organo Catalyst. Macromolecular Symposia 2013, 334, 92–97. doi:10.1002/masy.201300109
• Naumann, S.; Schmidt, F. G.; Frey, W.; Buchmeiser, M. R. Protected N-heterocyclic carbenes as latent pre-catalysts for the polymerization of ε-caprolactone. Polymer Chemistry 2013, 4, 4172–4181. doi:10.1039/c3py00548h

Explore citations to this article at