Beilstein J. Org. Chem.2014,10, 1651–1656, doi:10.3762/bjoc.10.172
-hydroxy group on the anomeric carbon, with the iodide as a good leaving group. This compound is a good precursor for building blocks for the construction of 1→6 linkages.
Keywords: 1,6-anhydro-α-D-Galf; galactofuranosyl iodide; galactofuranosyl precursor; per-tert-butyldimethylsilyl-β-D-galactofuranose
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Graphical Abstract
Figure 1:
Possible 1,6-anydro derivatives for D-galactose.