Beilstein J. Org. Chem.2024,20, 272–279, doi:10.3762/bjoc.20.28
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Keywords: cycloadditions; DFT calculations; [70]fullerene; open-cage fullerenes; rhodium; Introduction
The discovery of C60 (buckminsterfullerene) in 1985 [1] initiated the search for possible technological applications of fullerenes. Nowadays, applications for these carbon-based molecules have
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Graphical Abstract
Scheme 1:
Rhodium(I)-catalyzed cycloaddition of C60 with diynes to afford bis(fulleroid) derivatives [33].