Beilstein J. Org. Chem.2023,19, 1858–1866, doi:10.3762/bjoc.19.138
reaction is believed to occur via electron transfer, followed by the radical coupling of La@C2v-C82 and benzyl radicals, rather than by bimolecular nucleophilic substitution reaction of La@C2v-C82 anion with 1.
Keywords: electron transfer; metallofullerene; radical; reduction; Introduction
Fullerenes
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Graphical Abstract
Scheme 1:
Reaction of the La@C2v-C82 anion with benzyl bromide derivatives.
Beilstein J. Org. Chem.2014,10, 714–721, doi:10.3762/bjoc.10.65
metallofullerene derivatives for the use in material science.
Keywords: carbon nanomaterials; dynamic NMR; endofullerenes; La2@C80; La@C82; sultine; Introduction
Endohedral metallofullerenes (EMFs) are a family of nanocarbons, which encapsulated one or more metal atoms inside a hollow carbon cage [1][2][3][4
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Graphical Abstract
Scheme 1:
Synthesis of [4 + 2] adducts of La2@C80.