Beilstein J. Org. Chem.2015,11, 678–686, doi:10.3762/bjoc.11.77
[25] and various paths to obtain ZnO colloids have been reviewed by Spanhel [26]. Suitable methods for the synthesis of pure and doped ZnO NPs involve colloidal, sol–gel or solvo-/hydrothermal methods [27], microemulsion and miniemulsion methods [28] or non-aqueous sol–gel routes [29]. Recently, some
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Graphical Abstract
Figure 1:
A) Schematic drawing of a bifunctional anchor molecule and its immobilization on a nanoparticle (NP...
Beilstein J. Org. Chem.2010,6, 1132–1148, doi:10.3762/bjoc.6.130
Daniel Crespy Katharina Landfester Max Planck Institute for Polymer Research, Ackermannweg 10, 55128 Mainz, Germany 10.3762/bjoc.6.130 Abstract The miniemulsion technique is a particular case in the family of heterophase polymerizations, which allows the formation of functionalized polymers by
polymerization or modification of polymers in stable nanodroplets. We present here an overview of the different polymer syntheses within the miniemulsion droplets as reported in the literature, and of the current trends in the field.
Keywords: functionalized polymers; heterophase polymerization; miniemulsion
-free miniemulsions can be formed in direct or inverse systems. Polymers can be synthesized in a miniemulsion system in the dispersed phase, at the interface of the droplets, or in the continuous phase, although only the two first possibilities are usually found in the literature. In principle, the
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Graphical Abstract
Figure 1:
Copolymerization of 2 monomers A and B with different polarities in direct miniemlusions with the d...