Green and sustainable approaches for the Friedel–Crafts reaction between aldehydes and indoles

• Periklis X. Kolagkis,
• Eirini M. Galathri and
• Christoforos G. Kokotos

Beilstein J. Org. Chem. 2024, 20, 379–426, doi:10.3762/bjoc.20.36

Radical chemistry in polymer science: an overview and recent advances

• Zixiao Wang,
• Feichen Cui,
• Yang Sui and
• Jiajun Yan

Beilstein J. Org. Chem. 2023, 19, 1580–1603, doi:10.3762/bjoc.19.116

• photocrosslinking of polymers is also feasible in the presence of photoinitiators or photoresponsive moieties [136][137][138]. Sophisticatedly designed photocrosslinking of polymers finds broad applications in modern 3D printing/additive manufacturing [139][140][141][142]. Radical chemistry has been demonstrated as

Towards new NIR dyes for free radical photopolymerization processes

• Haifaa Mokbel,
• Guillaume Noirbent,
• Didier Gigmes,
• Frédéric Dumur and
• Jacques Lalevée

Beilstein J. Org. Chem. 2021, 17, 2067–2076, doi:10.3762/bjoc.17.133

• (wavelength of the irradiation used). The visible–NIR spectra of IR 813 (Scheme 2) considered as a reference is given in Figure S1 in Supporting Information File 1. NIR polymerization initiating ability Due to the good NIR absorption properties, the proposed dyes have been tested as photoinitiators in

Photoinduced post-modification of graphitic carbon nitride-embedded hydrogels: synthesis of 'hydrophobic hydrogels' and pore substructuring

• Cansu Esen and
• Baris Kumru

Beilstein J. Org. Chem. 2021, 17, 1323–1334, doi:10.3762/bjoc.17.92

• ), then it was freeze-dried overnight (HGCM). Despite the fact that g-CN-based hydrogels are appealing as g-CN nanosheets can be employed as photoinitiators to form covalent species, in this study external initiators were employed to embed g-CN nanosheets within hydrogel network [36]. In addition, a

Synthesis, crystal structures and properties of carbazole-based [6]helicenes fused with an azine ring

• Daria I. Tonkoglazova,
• Anna V. Gulevskaya,
• Konstantin A. Chistyakov and
• Olga I. Askalepova

Beilstein J. Org. Chem. 2021, 17, 11–21, doi:10.3762/bjoc.17.2

• electroactive materials [52][53][54]. Carbazole-based [6]helicenes [42] and [7]helicenes [50] showed deep blue electroluminescence and have been investigated in OLED devices. Some carbazole-based [5]- and [6]helicenes have been used as visible light photoinitiators for cationic and radical polymerization [41

Aldehydes as powerful initiators for photochemical transformations

• Maria A. Theodoropoulou,
• Nikolaos F. Nikitas and
• Christoforos G. Kokotos

Beilstein J. Org. Chem. 2020, 16, 833–857, doi:10.3762/bjoc.16.76

• ) aldehydes have as photoinitiators. The photophysical properties and photoreactivity of benzaldehyde are initially provided, followed by applications of aldehydes as initiators for polymerization reactions. Finally, the applications to date regarding aldehydes as photoinitiators in organic synthesis are

• similar derivatives have already been used in a plethora of chemical transformations, and their photochemical properties have been studied extensively [11]. In an attempt to mimic the potential of ketones, various aldehydes have been employed as photocatalysts or photoinitiators. Even if aromatic ketones

• are useful photocatalysts, the corresponding aldehydes are not so widely utilized to promote chemical reactions. In this review, our goal was to summarize the photophysical properties of aromatic aldehydes, highlight the use of aldehydes as photoinitiators in polymerization reactions, and provide all

Photophysics and photochemistry of NIR absorbers derived from cyanines: key to new technologies based on chemistry 4.0

• Bernd Strehmel,
• Christian Schmitz,
• Ceren Kütahya,
• Yulian Pang,
• Anke Drewitz and
• Heinz Mustroph

Beilstein J. Org. Chem. 2020, 16, 415–444, doi:10.3762/bjoc.16.40

• metal ions. In this process, basically, in the presence of photoactive materials (PAs) such as photoinitiators, photosensitizers or photoredox catalysts, the photoexcitation of a photoredox system results in formation of reactive radicals. Those reactive radicals add monomer and the polymerization

• -free ATRP strategy [132][133][134][135][136][137]. Latter reference provided a comprehensive overview demonstrating the function of phenothiazine derivatives, perylene, diaryl dihydrophenazines, anthracene or pyrene. In addition, type II photoinitiators including benzophenone, and thioxanthones were

Organometallic vs organic photoredox catalysts for photocuring reactions in the visible region

• Aude-Héloise Bonardi,
• Frédéric Dumur,
• Guillaume Noirbent,
• Jacques Lalevée and
• Didier Gigmes

Beilstein J. Org. Chem. 2018, 14, 3025–3046, doi:10.3762/bjoc.14.282

• chemistry. Thanks to the development of photoredox catalysts of polymerization, a drastic reduction of the amount of photoinitiators could be achieved, addressing the toxicity and the extractability issues; high performance initiating abilities are still obtained due to the catalytic approach which

• used to produce the polymers. At present, most of the photoinitiating systems in use in the industry required high light intensity, the emission of these lamps being mainly centered in the UV range. To create safer photoinitiating systems, photoinitiators exhibiting a strong absorption in the near UV

• or visible range with high molar extinction coefficients are actively researched. As far as the extractability of the photoinitiators and the side-products that can be formed during the polymerization process is concerned, a good strategy is to reduce the amount of photoinitiator. Thus, inspired by

Metal and metal-free photocatalysts: mechanistic approach and application as photoinitiators of photopolymerization

• Jacques Lalevée,
• Sofia Telitel,
• Pu Xiao,
• Marc Lepeltier,
• Frédéric Dumur,
• Fabrice Morlet-Savary,
• Didier Gigmes and
• Jean-Pierre Fouassier

Beilstein J. Org. Chem. 2014, 10, 863–876, doi:10.3762/bjoc.10.83

• formerly: University of Haute Alsace/ENSCMu, 3 rue Alfred Werner, 68093 Mulhouse Cedex, France 10.3762/bjoc.10.83 Abstract In the present paper, the photoredox catalysis is presented as a unique approach in the field of photoinitiators of polymerization. The principal photocatalysts already reported as

• -trapping, laser flash photolysis, steady state photolysis, cyclic voltammetry and luminescence experiments. Keywords: LEDs; photoinitiators; photopolymerization; photoredox catalysis; Introduction Photoredox catalysis is now well-known and largely used in organic synthesis, especially in the development

• cationic photopolymerization (FRPCP, Scheme 1, reactions 5–7) or acid and base-catalyzed photocrosslinking (reactions 8 and 9) are initiated using photoinitiators (PI) which generate reactive species (radicals, cations, anions, radical cations, acids, bases). These PIs are often incorporated into

The synthesis of well-defined poly(vinylbenzyl chloride)-grafted nanoparticles via RAFT polymerization

• John Moraes,
• Kohji Ohno,
• Guillaume Gody,
• Thomas Maschmeyer and
• Sébastien Perrier

Beilstein J. Org. Chem. 2013, 9, 1226–1234, doi:10.3762/bjoc.9.139

• thermal or photoinitiators, the amount of which is kept low in comparison with the amount of CTA introduced (i.e., high ratio CTA/initiator) in order to minimise the fraction of dead chains produced. Therefore, it is commonly assumed that the ratio of monomer to RAFT agent gives the average degree of

• polymer chains. Results and Discussion Previous literature on the RAFT-mediated polymerization of vinylbenzyl chloride has utilized either thermal autoinitiation [29], or azoinitiators [25][26][27][28][32] and photoinitiators [33]. Of these investigations only two were concerned with polymers greater than

New core-pyrene π structure organophotocatalysts usable as highly efficient photoinitiators

• Sofia Telitel,
• Frédéric Dumur,
• Thomas Faury,
• Bernadette Graff,
• Mohamad-Ali Tehfe,
• Didier Gigmes,
• Jean-Pierre Fouassier and
• Jacques Lalevée

Beilstein J. Org. Chem. 2013, 9, 877–890, doi:10.3762/bjoc.9.101

• ; photocatalysts; photoinitiators; radical photopolymerization; Introduction Free radical sources are encountered in various areas such as organic chemistry, biochemistry and polymer chemistry. In the field of polymer photochemistry applied to photopolymerization reactions, they are referred to as photoinitiators

• , we have demonstrated the true occurrence of a unique oxidation cycle). Conclusion In this paper, the core-pyrene π structures Co_Pys appear as interesting photoinitiators. Successful cationic and radical photopolymerization reactions were carried out under near-UV–vis irradiation. A photocatalytic

• provided by Cytec. Photopolymerization procedures TMPTA was irradiated at room temperature under lamination conditions: the formulation (25 μm thick) is sandwiched between two polypropylene films. The weight percentages for the photoinitiators are given in the figure captions. The evolution of the acrylate

Synthesis, characterization and photoinduced curing of polysulfones with (meth)acrylate functionalities

• Cemil Dizman,
• Sahin Ates,
• Lokman Torun and
• Yusuf Yagci

Beilstein J. Org. Chem. 2010, 6, No. 56, doi:10.3762/bjoc.6.56

• , production-line adjustability, low temperature processing, non-polluting and solvent-free formulations, and uncomplicated designed system. Organic materials (monomers, oligomers, polymers) with photoinitiators can be used in UV-curing systems. There are several photoinitiators acting in the UV and visible

Synthesis of bis(3-{[2-(allyloxy)ethoxy]methyl}-2,4,6-trimethylbenzoyl)(phenyl)phosphine oxide – a tailor-made photoinitiator for dental adhesives

• Norbert Moszner,
• Iris Lamparth,
• Jörg Angermann,
• Urs Karl Fischer,
• Frank Zeuner,
• Thorsten Bock,
• Robert Liska and
• Volker Rheinberger

Beilstein J. Org. Chem. 2010, 6, No. 26, doi:10.3762/bjoc.6.26

• -butyl]acrylate [3] or 1,3-bis(methacrylamido)propane-2-yl dihydrogen phosphate (BMAMHP) [4], which show improved hydrolytic stability under acidic aqueous conditions. The visible-light (VL) photoinitiators (PIs) in current SEAs are based on mixtures of camphorquinone (CQ) and tertiary amines (A) [5