New reactive intermediates in organic chemistry

  1. editorImage
  1. Editor: Prof. Götz Bucher
    University of Glasgow

Research into reactive intermediates has historically been part of the work involved in product studies. In order to characterize a reactive intermediate, it had to be trapped. Using internal quenchers (molecular clocks) providing well-defined competing reactions, product studies can even yield accurate values for intermolecular quenching reactions of reactive intermediates. More recent techniques to characterise reactive intermediates include matrix isolation spectroscopy, laser flash photolysis, or specialised mass-spectrometric techniques.

  • Editorial
  • Published 26 Mar 2013

Beilstein J. Org. Chem. 2013, 9, 613–614, doi:10.3762/bjoc.9.67

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  • Published 29 Jan 2013

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Beilstein J. Org. Chem. 2013, 9, 185–196, doi:10.3762/bjoc.9.22

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  1. Quynh Nhu N. Nguyen and
  2. Dean J. Tantillo
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  • Published 13 Feb 2013

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Beilstein J. Org. Chem. 2013, 9, 323–331, doi:10.3762/bjoc.9.37

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  • Published 26 Feb 2013

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Beilstein J. Org. Chem. 2013, 9, 437–446, doi:10.3762/bjoc.9.46

A new intermediate in the Prins reaction

  1. Shinichi Yamabe,
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  3. Shoko Yamazaki
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  • Published 05 Mar 2013

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Beilstein J. Org. Chem. 2013, 9, 476–485, doi:10.3762/bjoc.9.51

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  • Published 21 Mar 2013

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Beilstein J. Org. Chem. 2013, 9, 594–601, doi:10.3762/bjoc.9.64

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  • Published 26 Mar 2013

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Beilstein J. Org. Chem. 2013, 9, 615–620, doi:10.3762/bjoc.9.68

Photoionisation of the tropyl radical

  1. Kathrin H. Fischer,
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  3. Andras Bodi and
  4. Ingo Fischer
  • Full Research Paper
  • Published 09 Apr 2013

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Beilstein J. Org. Chem. 2013, 9, 681–688, doi:10.3762/bjoc.9.77

High-spin intermediates of the photolysis of 2,4,6-triazido-3-chloro-5-fluoropyridine

  1. Sergei V. Chapyshev,
  2. Denis V. Korchagin,
  3. Patrik Neuhaus and
  4. Wolfram Sander
  • Full Research Paper
  • Published 16 Apr 2013

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Beilstein J. Org. Chem. 2013, 9, 733–742, doi:10.3762/bjoc.9.83

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  • Published 17 Apr 2013

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Beilstein J. Org. Chem. 2013, 9, 743–753, doi:10.3762/bjoc.9.84

4-Pyridylnitrene and 2-pyrazinylcarbene

  1. Curt Wentrup,
  2. Ales Reisinger and
  3. David Kvaskoff
  • Full Research Paper
  • Published 17 Apr 2013

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Beilstein J. Org. Chem. 2013, 9, 754–760, doi:10.3762/bjoc.9.85

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  • Published 18 Apr 2013

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Beilstein J. Org. Chem. 2013, 9, 761–766, doi:10.3762/bjoc.9.86

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  • Published 23 Apr 2013

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Beilstein J. Org. Chem. 2013, 9, 791–799, doi:10.3762/bjoc.9.90

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  • Published 24 Apr 2013

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Beilstein J. Org. Chem. 2013, 9, 800–808, doi:10.3762/bjoc.9.91

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  • Published 14 May 2013

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Beilstein J. Org. Chem. 2013, 9, 925–933, doi:10.3762/bjoc.9.106

An aniline dication-like transition state in the Bamberger rearrangement

  1. Shinichi Yamabe,
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  3. Wei Guan and
  4. Shigeyoshi Sakaki
  • Full Research Paper
  • Published 03 Jun 2013

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Beilstein J. Org. Chem. 2013, 9, 1073–1082, doi:10.3762/bjoc.9.119

True and masked three-coordinate T-shaped platinum(II) intermediates

  1. Manuel A. Ortuño,
  2. Salvador Conejero and
  3. Agustí Lledós
  • Review
  • Published 09 Jul 2013

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Beilstein J. Org. Chem. 2013, 9, 1352–1382, doi:10.3762/bjoc.9.153

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  • Published 19 Jul 2013

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Beilstein J. Org. Chem. 2013, 9, 1448–1454, doi:10.3762/bjoc.9.164

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  • Published 22 Jul 2013

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Beilstein J. Org. Chem. 2013, 9, 1455–1462, doi:10.3762/bjoc.9.165

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  • Published 15 Aug 2013

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Beilstein J. Org. Chem. 2013, 9, 1668–1676, doi:10.3762/bjoc.9.191

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