C–H-Functionalization logic guides the synthesis of a carbacyclopamine analog

Sebastian Rabe, Johann Moschner, Marina Bantzi, Philipp Heretsch and Athanassios Giannis
Beilstein J. Org. Chem. 2014, 10, 1564–1569. https://doi.org/10.3762/bjoc.10.161

Supporting Information

Supporting Information File 1: Experimental procedures, characterization data, and copies of 1H and 13C NMR spectra for new compounds.
Format: PDF Size: 7.2 MB Download

Cite the Following Article

C–H-Functionalization logic guides the synthesis of a carbacyclopamine analog
Sebastian Rabe, Johann Moschner, Marina Bantzi, Philipp Heretsch and Athanassios Giannis
Beilstein J. Org. Chem. 2014, 10, 1564–1569. https://doi.org/10.3762/bjoc.10.161

How to Cite

Rabe, S.; Moschner, J.; Bantzi, M.; Heretsch, P.; Giannis, A. Beilstein J. Org. Chem. 2014, 10, 1564–1569. doi:10.3762/bjoc.10.161

Download Citation

Citation data can be downloaded as file using the "Download" button or used for copy/paste from the text window below.
Citation data in RIS format can be imported by all major citation management software, including EndNote, ProCite, RefWorks, and Zotero.

Citations to This Article

Up to 20 of the most recent references are displayed here.

Scholarly Works

  • Reese, P. B. Remote functionalization reactions in steroids: discovery and application. Steroids 2024, 204, 109362. doi:10.1016/j.steroids.2023.109362
  • Chen, D.; Huang, J.; Xiao, S.; Cheng, G.; Liu, Y.; Zhao, T.; Chen, C.; Yi, Y.; Peng, Y.; Cao, J. Synthesis, anti-leukemia activity, and molecular docking of novel 3,16-androstenedione derivatives. Steroids 2023, 199, 109290. doi:10.1016/j.steroids.2023.109290
  • Arcadi, A.; Morlacci, V.; Palombi, L. Synthesis of Nitrogen-Containing Heterocyclic Scaffolds through Sequential Reactions of Aminoalkynes with Carbonyls. Molecules (Basel, Switzerland) 2023, 28, 4725. doi:10.3390/molecules28124725
  • Wang, X.; Huang, G.; Wang, Y.; Gui, J. Asymmetric Total Synthesis of the Rearranged Steroid Phomarol Enabled by a Biomimetic SN2' Cyclization. Journal of the American Chemical Society 2023, 145, 9354–9363. doi:10.1021/jacs.3c02817
  • de Lucca Jr, E. C.; Santana, V. C. S.; Fernandes, M. C. V.; Cappuccelli, I.; Richieri, A. C. G. Metal-Catalyzed C–H Bond Oxidation in the Total Synthesis of Natural and Unnatural Products. Synthesis 2022, 54, 5337–5359. doi:10.1055/a-1918-4338
  • Chen, X.; Zhang, D.; Xu, D.; Zhou, H.; Xu, G. Remote C-H Activation Strategy Enables Total Syntheses of Nortriterpenoids (±)-Walsucochin B and (±)-Walsucochinoids M and N. Organic letters 2020, 22, 6993–6997. doi:10.1021/acs.orglett.0c02548
  • Horwitz, M. A.; Robins, J. G.; Johnson, J. S. De Novo Synthesis of the DEF-Ring Stereotriad Core of the Veratrum Alkaloids. The Journal of organic chemistry 2020, 85, 6808–6814. doi:10.1021/acs.joc.0c00685
  • Mousavizadeh, F.; Meyer, D.; Giannis, A. Synthesis of C-Nor-D-homo-steroidal Alkaloids and Their Derivatives. Synthesis 2018, 50, 1587–1600. doi:10.1055/s-0036-1591965
  • Trammell, R.; See, Y. Y.; Herrmann, A. T.; Xie, N.; Diaz, D. E.; Siegler, M. A.; Baran, P. S.; Garcia-Bosch, I. Decoding the Mechanism of Intramolecular Cu-Directed Hydroxylation of sp3 C–H Bonds. The Journal of organic chemistry 2017, 82, 7887–7904. doi:10.1021/acs.joc.7b01069
  • See, Y. Y.; Herrmann, A. T.; Aihara, Y.; Baran, P. S. Scalable C–H Oxidation with Copper: Synthesis of Polyoxypregnanes. Journal of the American Chemical Society 2015, 137, 13776–13779. doi:10.1021/jacs.5b09463
  • Heretsch, P.; Giannis, A. The Veratrum and Solanum Alkaloids. The Alkaloids. Chemistry and biology 2015, 74, 201–232. doi:10.1016/bs.alkal.2014.11.002
Other Beilstein-Institut Open Science Activities