Copolymerization and terpolymerization of carbon dioxide/propylene oxide/phthalic anhydride using a (salen)Co(III) complex tethering four quaternary ammonium salts

Jong Yeob Jeon, Seong Chan Eo, Jobi Kodiyan Varghese and Bun Yeoul Lee
Beilstein J. Org. Chem. 2014, 10, 1787–1795. https://doi.org/10.3762/bjoc.10.187

Supporting Information

Supporting Information File 1: 1H NMR spectra, 13C NMR spectra, GPC curves, and the pictures of the isolated polymers in PO/PA alternating polymerizations and PO/CO2/PA terpolymerizations.
Format: PDF Size: 1.1 MB Download

Cite the Following Article

Copolymerization and terpolymerization of carbon dioxide/propylene oxide/phthalic anhydride using a (salen)Co(III) complex tethering four quaternary ammonium salts
Jong Yeob Jeon, Seong Chan Eo, Jobi Kodiyan Varghese and Bun Yeoul Lee
Beilstein J. Org. Chem. 2014, 10, 1787–1795. https://doi.org/10.3762/bjoc.10.187

How to Cite

Jeon, J. Y.; Eo, S. C.; Varghese, J. K.; Lee, B. Y. Beilstein J. Org. Chem. 2014, 10, 1787–1795. doi:10.3762/bjoc.10.187

Download Citation

Citation data can be downloaded as file using the "Download" button or used for copy/paste from the text window below.
Citation data in RIS format can be imported by all major citation management software, including EndNote, ProCite, RefWorks, and Zotero.

Citations to This Article

Up to 20 of the most recent references are displayed here.

Scholarly Works

  • Zhao, T.; Chen, S.; Huang, X.; Yin, J.; Wang, S.; Han, D.; Huang, S.; Huang, Z.; Xiao, M.; Meng, Y. Metal-Free Synthesis of Biodegradable CO2-Based Oligo(carbonate-ester) Diols as Building Blocks for Thermoplastic Polyurethanes. ACS Applied Polymer Materials 2024, 6, 1813–1822. doi:10.1021/acsapm.3c02652
  • Shellard, E. J. K.; Diment, W. T.; Resendiz-Lara, D. A.; Fiorentini, F.; Gregory, G. L.; Williams, C. K. Al(III)/K(I) Heterodinuclear Polymerization Catalysts Showing Fast Rates and High Selectivity for Polyester Polyols. ACS catalysis 2024, 14, 1363–1374. doi:10.1021/acscatal.3c05712
  • Xu, X.; Li, H.; Mehmood, A.; Chi, K.; Shi, D.; Wang, Z.; Wang, B.; Li, Y.; Luo, Y. Mechanistic Studies on Aluminum-Catalyzed Ring-Opening Alternating Copolymerization of Maleic Anhydride with Epoxides: Ligand Effects and Quantitative Structure-Activity Relationship Model. Molecules (Basel, Switzerland) 2023, 28, 7279. doi:10.3390/molecules28217279
  • Niknam, F.; Denk, A.; Buonerba, A.; Rieger, B.; Grassi, A.; Capacchione, C. Dinuclear chromium complexes with [OSSO]-type ligands in the copolymerization of epoxides with CO2and phthalic anhydride. Catalysis Science & Technology 2023, 13, 4684–4692. doi:10.1039/d3cy00832k
  • Manjarrez, Y.; Clark, A. M.; Fieser, M. E. Rare Earth Metal‐Containing Ionic Liquid Catalysts for Synthesis of Epoxide/Cyclic Anhydride Copolymers. ChemCatChem 2023, 15. doi:10.1002/cctc.202300319
  • Liang, J.; Wang, S.; Wu, C.; Wang, S.; Han, D.; Huang, S.; Huang, Z.; Xiao, M.; Meng, Y. A new biodegradable CO2-based poly(ester-co-carbonate): Molecular chain building up with crosslinkable domain. Journal of CO2 Utilization 2023, 69, 102403. doi:10.1016/j.jcou.2023.102403
  • Haslewood, M. N. D.; Farmer, T. J.; North, M. Synthesis and chemoselective crosslinking of functionalized polyesters from bio‐based epoxides and cyclic anhydrides. Journal of Polymer Science 2022, 61, 311–322. doi:10.1002/pol.20220552
  • Wood, Z. A.; Assefa, M. K.; Fieser, M. E. Simple yttrium salts as highly active and controlled catalysts for the atom-efficient synthesis of high molecular weight polyesters. Chemical science 2022, 13, 10437–10447. doi:10.1039/d2sc02745c
  • Wang, Z.; Yin, G.; Wang, Z.; Yin, Y. Synthesis of anionic rare-earth metal salan complexes as catalysts for copolymerization of cyclohexene oxide with cyclic anhydrides. Inorganic Chemistry Communications 2022, 143, 109805. doi:10.1016/j.inoche.2022.109805
  • Lidston, C. A. L.; Severson, S. M.; Abel, B. A.; Coates, G. W. Multifunctional Catalysts for Ring-Opening Copolymerizations. ACS Catalysis 2022, 12, 11037–11070. doi:10.1021/acscatal.2c02524
  • Liang, J.; Ye, S.; Wang, S.; Wang, S.; Han, D.; Huang, S.; Huang, Z.; Liu, W.; Xiao, M.; Sun, L.; Meng, Y. Biodegradable Copolymers from CO2, Epoxides, and Anhydrides Catalyzed by Organoborane/Tertiary Amine Pairs: High Selectivity and Productivity. Macromolecules 2022, 55, 6120–6130. doi:10.1021/acs.macromol.2c01118
  • Cui, L.; Liu, Y.; Ren, B.-H.; Lu, X.-B. Preparation of Sequence-Controlled Polyester and Polycarbonate Materials via Epoxide Copolymerization Mediated by Trinuclear Co(III) Complexes. Macromolecules 2022, 55, 3541–3549. doi:10.1021/acs.macromol.2c00501
  • Manjarrez, Y.; Cheng-Tan, M. D. C. L.; Fieser, M. E. Perfectly Alternating Copolymerization of Cyclic Anhydrides and Epoxides with Yttrium β-Diketiminate Complexes. Inorganic chemistry 2022, 61, 7088–7094. doi:10.1021/acs.inorgchem.2c00529
  • Wang, Y.; Wang, M.; Shi, Y.; Chen, X.; Song, D.; Li, Y.; Wang, B. Switchable Copolymerization of Maleic Anhydride/Epoxides/Lactide Mixtures: A Straightforward Approach to Block Copolymers with Unsaturated Polyester Sequences. Macromolecular Chemistry and Physics 2022, 223. doi:10.1002/macp.202200079
  • Chen, X.-L.; Wang, B.; Pan, L.; Li, Y.-S. Synthesis of Unsaturated (Co)polyesters from Ring-Opening Copolymerization by Aluminum Bipyridine Bisphenolate Complexes with Improved Protonic Impurities Tolerance. Macromolecules 2022, 55, 3502–3512. doi:10.1021/acs.macromol.2c00034
  • Li, Y.-N.; Liu, Y.; Yang, H.-H.; Zhang, W.-F.; Lu, X.-B. Intramolecular Partners in Asymmetric Catalysis Copolymerization: Highly Enantioselective and Controllable at Enhanced Temperatures and Low Loadings. Angewandte Chemie (International ed. in English) 2022, 61, e202202585. doi:10.1002/anie.202202585
  • Li, Y.; Liu, Y.; Yang, H.; Zhang, W.; Lu, X. Intramolecular Partners in Asymmetric Catalysis Copolymerization: Highly Enantioselective and Controllable at Enhanced Temperatures and Low Loadings. Angewandte Chemie 2022, 134. doi:10.1002/ange.202202585
  • Wang, W.-J.; Ye, S.-X.; Liang, J.-X.; Fan, C.-X.; Zhu, Y.-L.; Wang, S.-J.; Xiao, M.; Meng, Y.-Z. Architecting Branch Structure in Terpolymer of CO2, Propylene Oxide and Phthalic Anhydride: An Enhancement in Thermal and Mechanical Performances. Chinese Journal of Polymer Science 2022, 40, 462–468. doi:10.1007/s10118-022-2686-4
  • Reis, N. V.; Deacy, A. C.; Rosetto, G.; Durr, C. B.; Williams, C. K. Heterodinuclear Mg(II)M(II) (M=Cr, Mn, Fe, Co, Ni, Cu and Zn) Complexes for the Ring Opening Copolymerization of Carbon Dioxide/Epoxide and Anhydride/Epoxide. Chemistry (Weinheim an der Bergstrasse, Germany) 2022, 28, e202104198. doi:10.1002/chem.202104198
  • Zhu, X.; Kou, X. Organic bases and protic acids as binary catalysts for ring-opening alternating copolymerization of epoxides and cycle anhydrides. Chemical Papers 2022, 76, 2145–2152. doi:10.1007/s11696-021-01980-6

Patents

  • WEI HUAIJIAN; LI HONGGUO; LI YIGE; GAO YUFEI; FU HAI; DONG LIANG. METHOD FOR PREPARING CARBON DIOXIDE-BASED QUATERNARY COPOLYMER. WO 2023045887 A1, March 30, 2023.
  • LI HONGGUO; WANG XUNLIN; LI YIGE; ZHANG JUNLING; GAO SHEN; HU WENDA. CARBON DIOXIDE COPOLYMER COMPOSITION AND PREPARATION METHOD THEREFOR. WO 2023045888 A1, March 30, 2023.
  • KEMBER MICHAEL; LEELAND JAMES; RILEY KERRY. (POLY)OL BLOCK COPOLYMER. WO 2022096889 A1, May 12, 2022.
Other Beilstein-Institut Open Science Activities