Tandem catalysis of ring-closing metathesis/atom transfer radical reactions with homobimetallic ruthenium–arene complexes

Yannick Borguet, Xavier Sauvage, Guillermo Zaragoza, Albert Demonceau and Lionel Delaude
Beilstein J. Org. Chem. 2010, 6, 1167–1173. https://doi.org/10.3762/bjoc.6.133

Supporting Information

Full experimental procedures and spectral data for the new compounds, detailed crystallographic analysis of [(p-cymene)Ru(μ-Cl)3RuCl2(PCy3)] (7), and a cif file with crystallographic data for complex 7.

Supporting Information File 1: Experimental procedures and spectral data.
Format: PDF Size: 92.4 KB Download
Supporting Information File 2: Detailed crystallographic analysis of complex 7.
Format: PDF Size: 442.6 KB Download
Supporting Information File 3: X-ray crystal data for complex 7.
Format: CIF Size: 63.1 KB Download

Cite the Following Article

Tandem catalysis of ring-closing metathesis/atom transfer radical reactions with homobimetallic ruthenium–arene complexes
Yannick Borguet, Xavier Sauvage, Guillermo Zaragoza, Albert Demonceau and Lionel Delaude
Beilstein J. Org. Chem. 2010, 6, 1167–1173. https://doi.org/10.3762/bjoc.6.133

How to Cite

Borguet, Y.; Sauvage, X.; Zaragoza, G.; Demonceau, A.; Delaude, L. Beilstein J. Org. Chem. 2010, 6, 1167–1173. doi:10.3762/bjoc.6.133

Download Citation

Citation data can be downloaded as file using the "Download" button or used for copy/paste from the text window below.
Citation data in RIS format can be imported by all major citation management software, including EndNote, ProCite, RefWorks, and Zotero.

Citations to This Article

Up to 20 of the most recent references are displayed here.

Scholarly Works

  • Nikoshvili, L. Z.; Matveeva, V. G. Recent Progress in Pd-Catalyzed Tandem Processes. Catalysts 2023, 13, 1213. doi:10.3390/catal13081213
  • Patra, S.; Maity, N. Recent advances in (hetero)dimetallic systems towards tandem catalysis. Coordination Chemistry Reviews 2021, 434, 213803. doi:10.1016/j.ccr.2021.213803
  • Cruz, T. R.; Silva, R. A. N.; Machado, A. E.; Lima-Neto, B. S.; Goi, B. E.; Carvalho, V. P. New dmso–ruthenium catalysts bearing N-heterocyclic carbene ligands for the ring-opening metathesis of norbornene. New Journal of Chemistry 2019, 43, 6220–6227. doi:10.1039/c9nj00810a
  • Biancalana, L.; Zacchini, S.; Ferri, N.; Lupo, M. G.; Pampaloni, G.; Marchetti, F. Tuning the cytotoxicity of ruthenium(II) para-cymene complexes by mono-substitution at a triphenylphosphine/phenoxydiphenylphosphine ligand. Dalton transactions (Cambridge, England : 2003) 2017, 46, 16589–16604. doi:10.1039/c7dt03385k
  • Fuwa, H.; Sasaki, M. Exploiting Ruthenium Carbene-Catalyzed Reactions in Total Synthesis of Marine Oxacyclic Natural Products. Bulletin of the Chemical Society of Japan 2016, 89, 1403–1415. doi:10.1246/bcsj.20160224
  • Lee, J.; Grandner, J. M.; Engle, K. M.; Houk, K. N.; Grubbs, R. H. In Situ Catalyst Modification in Atom Transfer Radical Reactions with Ruthenium Benzylidene Complexes. Journal of the American Chemical Society 2016, 138, 7171–7177. doi:10.1021/jacs.6b03767
  • Dragutan, I.; Dragutan, V.; Demonceau, A. Editorial of Special Issue Ruthenium Complex: The Expanding Chemistry of the Ruthenium Complexes. Molecules (Basel, Switzerland) 2015, 20, 17244–17274. doi:10.3390/molecules200917244
  • Nam, Y. H.; Snapper, M. L. Handbook of Metathesis; Wiley, 2015; pp 311–380. doi:10.1002/9783527674107.ch18
  • Dixneuf, P. H.; Bruneau, C. Handbook of Metathesis; Wiley, 2015; pp 389–416. doi:10.1002/9783527674107.ch14
  • Diaba, F.; Martínez-Laporta, A.; Bonjoch, J. Atom Transfer Radical Cyclization of Trichloroacetamides to Electron-Rich Acceptors Using Grubbs’ Catalysts: Synthesis of the Tricyclic Framework of FR901483. The Journal of organic chemistry 2014, 79, 9365–9372. doi:10.1021/jo501110c
  • Risse, J.; Dutta, B.; Solari, E.; Scopelliti, R.; Severin, K. Contributions to the Chemistry of the Cyclopentadienyl Complex [Cp∧RuCl2]2 (“Cp‐roof” = η5‐1‐Methoxy‐2,4‐tert‐butyl‐3‐neopentylcyclopentadienyl). Zeitschrift für anorganische und allgemeine Chemie 2014, 640, 1322–1329. doi:10.1002/zaac.201400048
  • Öztürk, B. Ö.; Bucak, E.; Karabulut, S. In situ modification of the Grubbs first generation catalyst: A highly controllable metathesis catalyst bearing tridentate Schiff base ligands. Journal of Molecular Catalysis A: Chemical 2013, 376, 53–62. doi:10.1016/j.molcata.2013.04.010
  • Petersen, M. T.; Nielsen, T. E. Tandem ring-closing metathesis/isomerization reactions for the total synthesis of violacein. Organic letters 2013, 15, 1986–1989. doi:10.1021/ol400654r
  • Fuwa, H.; Noguchi, T.; Noto, K.; Sasaki, M. Tandem catalysis in domino olefin cross-metathesis/intramolecular oxa-conjugate cyclization: concise synthesis of 2,6-cis-substituted tetrahydropyran derivatives. Organic & biomolecular chemistry 2012, 10, 8108–8112. doi:10.1039/c2ob26189h
  • Tskhovrebov, A. G.; Solari, E.; Scopelliti, R.; Severin, K. Activation of Nitrous Oxide by Dinuclear Ruthenium Complexes. Organometallics 2012, 31, 7235–7240. doi:10.1021/om300786f
  • Herndon, J. W. The chemistry of the carbon–transition metal double and triple bond: Annual survey covering the year 2010 ☆. Coordination Chemistry Reviews 2012, 256, 1281–1376. doi:10.1016/j.ccr.2012.02.015
  • Borguet, Y.; Delaude, L.; Demonceau, A. Homobimetallic Ethylene− and Vinylidene−Ruthenium Complexes for ATRP. ACS Symposium Series; American Chemical Society, 2012; pp 115–132. doi:10.1021/bk-2012-1100.ch008
  • Kiefer, G.; Ruiz, J.; Solari, E.; Hilt, G.; Severin, K. Ruthenium-Catalyzed Sequential Enyne Cross-Metathesis/ATRA Reactions. European Journal of Organic Chemistry 2011, 2012, 93–98. doi:10.1002/ejoc.201101263
  • Muñoz-Molina, J. M.; Belderrain, T. R.; Pérez, P. J. Atom Transfer Radical Reactions as a Tool for Olefin Functionalization – On the Way to Practical Applications. European Journal of Inorganic Chemistry 2011, 2011, 3155–3164. doi:10.1002/ejic.201100379
  • Fernandez‐Zumel, M. A.; Buron, C.; Severin, K. Sequential ATRA-Reductive Cyclopropanation Reactions with a Ruthenium Catalyst in the Presence of Manganese. European Journal of Organic Chemistry 2011, 2011, 2272–2277. doi:10.1002/ejoc.201100175
Other Beilstein-Institut Open Science Activities