1 article(s) from Hrachowina, Lukas
- Full Research Paper
- Published 14 Feb 2018
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Figure 1: Structural arrangement of HFeCo3(CO)12 and H2FeRu3(CO)13 illustrating differences in symmetry and l...
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Figure 2: Isotope distribution of a) HFeCo3(CO)12 and b) H2FeRu3(CO)13. Isotope distribution for both compoun...
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Figure 3: Negative ion yield curves for the formation of a) [Fe(CO)n]− and b) [Ru(CO)n]− up on electron attac...
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Figure 4: Loss of Fe(CO)2 (panel a), Fe(CO)3 (panel b), Fe(CO)4 (panel c) and additional loss of up to 7 COs ...
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Figure 5: Negative ions formed through loss of Ru(CO)3 (panel a), Ru(CO)4 (panel b) and further loss of up to...
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Figure 6: Calculated spin density of the [H2FeRu3(CO)13]− anion; a) in the constrained geometry of neutral H2...
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Figure 7: Calculated MO diagrams of H2FeRu3(CO)13 and HFeCo3(CO)12. Red lines represent the unoccupied molecu...
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Figure 8: Electron impact ionization spectra of H2FeRu3(CO)13 recorded at electron energy of 70 eV, upper pan...
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Figure 9: Evolution of O 1s, Fe 2p and Ru 3d/C 1s XPS regions of a H2FeRu3(CO)13 film exposed to electron dos...
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Figure 10: Change in fractional coverage of oxygen atoms (red stars) and, Ru 3d5/2 peak position (blue open ci...
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Figure 11: Mass spectrum of neutral gas phase species desorbed from an H2FeRu3(CO)13 film during the course of...
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Figure 12: Changes in O 1s, Fe 2p and Ru 3d/C 1s XPS regions when an H2FeRu3(CO)13 film was exposed to electro...
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Figure 13: Initial decomposition/deposition of surface adsorbed H2FeRu3(CO)13 precursor, mediated by dissociat...
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Figure 14: Schematic showing the incorporation of partially decarbonylated intermediate of H2FeRu3(CO)13 into ...
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Figure 15: (a) AFM cross sections of deposits shown in the SEM micrograph (b) at the positions indicated by th...
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Figure 16: Transport measurements of as-grown Fe–Ru deposit and deposits grown under identical conditions afte...
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