2 article(s) from Allain, Magali
Multifunctional TTF-appended azine ligands.
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Synthetic scheme for TTF-based azine ligands L1 and L2.
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Crystal structure of ligand L1 with atom numbering scheme (top) and a side view of the molecule (bo...
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Partial crystal packing of ligand L1 with formation of head to tail dimers that stack along a-axis ...
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Packing diagram of L1 showing the orientation of the columns of head to tail dimers.
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UV–visible absorption spectra of ligands L1 and L2 (c 2.5 × 10−5 M in (dichloromethane/acetonitrile...
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HOMO–LUMO Frontier orbitals representation for ligands L1 and L2.
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Cyclic voltammograms of ligands L1 and L2 (2 × 10−5 M) in CH2Cl2/CH3CN (9:1, v/v) at 100 mV·s−1 on ...
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UV–visible spectral changes of ligand L2 (2 × 10−5 M in CH2Cl2/CH3CN, 9/1) upon addition of TBAF.
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1H NMR spectra of ligand L2 (4·10−3 M in DMSO-d6) upon addition of successive aliquots of TBAF (DMS...
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Crystal structure of complex 3 with atom numbering scheme (top) and a side view of the molecule (bo...
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Pattern of intramolecular and intermolecular contacts in 3. Two molecules are linked by pairs of st...
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Layered structure of complex 3 viewed along the a-axis. The dimers are linked together through hydr...
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Beilstein J. Org. Chem. 2015, 11, 1379–1391, doi:10.3762/bjoc.11.149
Synthesis of ligand L1, self-assemblies M4L2 and M6L3.
X-ray crystal structures of: (a) ligand L1, (b) self-assembly M4L2. For clarity, H atoms and TfO− c...
1H NMR, downfield region (α and β signals correspond respectively to α and β pyridyl protons): (a) ...
X-ray crystal structure of self-assembly M6L3. For clarity, H atoms and TfO− counteranions have bee...
Geometry (from XRD) around two Pd centers in M4L2 (a) and M6L3 (b). The exTTF moieties have been cu...
Cyclic voltammogram of L1 (c = 10−3 M, CH3CN/CH2Cl2 (v/v 50/50), 0.1 M n-Bu4NPF6, 100 mV·s−1, Pt), M...
Beilstein J. Org. Chem. 2015, 11, 966–971, doi:10.3762/bjoc.11.108
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