1 article(s) from Ayadi, Awatef
- Full Research Paper
- Published 07 Aug 2015
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Graphical Abstract
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Scheme 1: Multifunctional TTF-appended azine ligands.
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Scheme 2: Synthetic scheme for TTF-based azine ligands L1 and L2.
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Figure 1: Crystal structure of ligand L1 with atom numbering scheme (top) and a side view of the molecule (bo...
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Figure 2: Partial crystal packing of ligand L1 with formation of head to tail dimers that stack along a-axis ...
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Figure 3: Packing diagram of L1 showing the orientation of the columns of head to tail dimers.
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Figure 4: UV–visible absorption spectra of ligands L1 and L2 (c 2.5 × 10−5 M in (dichloromethane/acetonitrile...
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Figure 5: HOMO–LUMO Frontier orbitals representation for ligands L1 and L2.
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Figure 6: Cyclic voltammograms of ligands L1 and L2 (2 × 10−5 M) in CH2Cl2/CH3CN (9:1, v/v) at 100 mV·s−1 on ...
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Figure 7: UV–visible spectral changes of ligand L2 (2 × 10−5 M in CH2Cl2/CH3CN, 9/1) upon addition of TBAF.
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Figure 8: 1H NMR spectra of ligand L2 (4·10−3 M in DMSO-d6) upon addition of successive aliquots of TBAF (DMS...
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Figure 9: Crystal structure of complex 3 with atom numbering scheme (top) and a side view of the molecule (bo...
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Figure 10: Pattern of intramolecular and intermolecular contacts in 3. Two molecules are linked by pairs of st...
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Figure 11: Layered structure of complex 3 viewed along the a-axis. The dimers are linked together through hydr...
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