5 article(s) from Hernández, José G
Beilstein J. Org. Chem. 2019, 15, 1521–1522, doi:10.3762/bjoc.15.154
Biologically relevant molecules made, used or derivatized by mechanochemistry.
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Isomeric diacyl-sn-glycerols (DAGs).
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Synthetic route to access protected DAGs; PG = protecting group.
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Protection of glycidol (1) with TBDMSCl in the ball mill. MM = mixer mill, PBM = planetary ball mil...
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Cobalt-catalyzed epoxide ring-opening in the ball mill.
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Mechanosynthesis of DAGs 5.
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Conjugation of DAG 5a with 7-hydroxycoumarin (9).
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UV−vis spectra of DAG 6a (dotted line) and conjugated DAGs 10a and 10a’ as a mixture (10a/10a’ 72:2...
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Beilstein J. Org. Chem. 2019, 15, 811–817, doi:10.3762/bjoc.15.78
Beilstein J. Org. Chem. 2017, 13, 2372–2373, doi:10.3762/bjoc.13.234
Enzymatic reactions under ball milling conditions.
(a) Molecular representation of lignin. (b) Lignin model compound erythro-1a.
Chemical and enzymatic esterification of erythro-1a with isopropenyl acetate (2a) in the ball mill....
CALB-catalyzed esterification of lignin model compounds in the ball mill.
Selective esterification of erythro-1a using long-chain vinyl esters as acyl donors in the ball mil...
Beilstein J. Org. Chem. 2017, 13, 1788–1795, doi:10.3762/bjoc.13.173
(a) Cartoon representing the merging of light and mechanical energy. (b) 25 mL transparent PMMA mil...
Borylation of 1a in the presence of 1,1-diphenylethene (4).
Light-mediated LAG borylation of 1a. aDetermined by 1H NMR spectroscopy using internal standard. bA...
Beilstein J. Org. Chem. 2017, 13, 1463–1469, doi:10.3762/bjoc.13.144
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