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1 article(s) from Kimber, Marc C

A complementary approach to conjugated N-acyliminium formation through photoredox-catalyzed intermolecular radical addition to allenamides and allencarbamates

Olusesan K. Koleoso,
Matthew Turner,
Felix Plasser and
Marc C. Kimber

Letter
Published 12 Aug 2020

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1. Graphical Abstract
2. Scheme 1: Electrophilic activation of allenamides.
  
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3. Scheme 2: The planned intramolecular radical addition to allenamides generating the conjugated N-acyliminium ...
  
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4. Scheme 3: Photoredox Ir-catalyzed intermolecular addition of bromide 18 and aniline 16 to allenamide 15.
  
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5. Scheme 4: Reaction scope (a) allenamide; (b) arylamine nucleophile; (c) alcohol nucleophile.
  
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6. Scheme 5: (a) Tentative mechanism for the photoredox-catalyzed formation of the conjugated N-acyliminium inte...
  
  Jump to Scheme 5
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Graphical Abstract

Beilstein J. Org. Chem. 2020, 16, 1983–1990, doi:10.3762/bjoc.16.165

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