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1 article(s) from Mori, Satoru

Synthesis and application of trifluoroethoxy-substituted phthalocyanines and subphthalocyanines

Satoru Mori and
Norio Shibata

Beilstein J. Org. Chem. 2017, 13, 2273–2296, doi:10.3762/bjoc.13.224

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Graphical Abstract

Scheme 1: Synthesis of trifluoroethoxy-substituted phthalocyanine.

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Scheme 2: Synthesis of trifluoroethoxy-substituted binuclear phthalocyanine 5 in Solkane^® 365 mfc.

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Scheme 3: Synthesis of trifluoroethoxy-substituted unsymmetrical phthalocyanines.

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Scheme 4: Synthesis of trifluoroethoxy-substituted phthalocyanine dimers linked at the β-position.

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Figure 1: Structure of trifluoroethoxy-substituted phthalocyanine dimers linked at the α-position.

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Figure 2: Structure of trifluoroethoxy-substituted dimer via a diacetylene linker.

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Figure 3: UV–vis spectra of 9 (A) and 5 (B).

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Figure 4: Structure of binuclear phthalocyanines linked by a triazole linker.

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Figure 5: Structure of trinuclear phthalocyanines linked by a triazole linker, and windmill-like molecular st...

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Scheme 5: Synthesis of trifluoroethoxy-substituted phthalocyanines conjugated with peptides.

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Scheme 6: Synthesis of trifluoroethoxy-substituted phthalocyanines conjugated with deoxyribonucleosides.

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Scheme 7: Synthesis of trifluoroethoxy-substituted phthalocyanines conjugated with cyclodextrin.

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Figure 6: Direction of energy transfer of phthalocyanine–fullerene conjugates.

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Scheme 8: Synthesis of fluoropolymer-bearing phthalocyanine side groups.

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Scheme 9: Synthesis of trifluoroethoxy-substituted double-decker type phthalocyanines.

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Scheme 10: Synthesis of trifluoroethoxy-substituted subphthalocyanine.

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Figure 7: Structure of axial ligand substituted subphthalocyanine hybrid dyes.

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Scheme 11: Synthesis of subphthalocyanine homodimers.

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Scheme 12: Synthesis of subphthalocyanine heterodimers.

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Figure 8: Energy transfer between subphthalocyanine units.

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Figure 9: Structure of phthalocyanine and subphthalocyanine benzene-fused homodimers.

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Scheme 13: Synthesis of a phthalocyanine and subphthalocyanine benzene-fused heterodimer.

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Figure 10: X-ray crystallography of Pc-subPc (left) and UV–vis spectra of benzene-fused dimers.

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Review

Published 27 Oct 2017

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