3 article(s) from Saito, Norimichi
Ratios of CF3-containing drugs in marketed fluoro-pharmaceuticals and registered fluoro-agrochemica...
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Selected examples of CF3-containing biologically active molecules.
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Transformation of acyl fluorides to trifluoromethyl compounds. a) Deoxyfluorination of acyl fluorid...
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The substrate scope of acyl fluorides. Reaction conditions: 1 (0.3 mmol), FLUOLEAD® (0.9 mmol, 3.0 ...
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Mechanism of deoxyfluorination of acyl fluorides 1 with FLUOLEAD®/Olah’s reagent to trifluoromethyl...
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Beilstein J. Org. Chem. 2020, 16, 3052–3058, doi:10.3762/bjoc.16.254
Compounds used for the biological study.
Compounds 1–4 induced cell death in U937 cells. Briefly, U937 cells (1 × 104 cells/mL) were incubat...
Synthesis of pentafluoro-(2-iodophenyl)-λ6-sulfane (7).
Synthesis of unsymmetrical ortho-SF5 diaryliodonium salts 3p, 4b, 5a and 6a.
X-ray crystallographic structure of 3p drawn at 50% probability (CCDC 1573953).
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Ortho-SF5 phenyl iodonium salts 3p and 5a and their structural components 7 and 9 induced cell deat...
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3k, 3m and 3p induced cell death in AGLCL, a human normal B cell line. Briefly, AGLCL cells (1 × 104...
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Beilstein J. Org. Chem. 2018, 14, 364–372, doi:10.3762/bjoc.14.24
Preparation of ArSF4Cl 2.
Preparation of Ar(SF4Cl)n from Ar(SH)n (n = 2, 3).
Reaction mechanism for the formation of ArSF4Cl.
Reaction mechanism for the formation of trans and cis-ArSF4Cl.
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Preparation of ArSF5 with ZnF2.
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Preparation of PhSF5 with anhydrous HF.
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Preparation of 3a with HF–pyridine.
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Preparation of polyfluorinated ArSF5.
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Preparation of aryl bis- and tris(sulfur pentafluorides), Ar(SF5)n (n = 2,3).
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Beilstein J. Org. Chem. 2012, 8, 461–471, doi:10.3762/bjoc.8.53
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