2 article(s) from Saito, Norimichi
- Full Research Paper
- Published 07 Feb 2018
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Figure 1: Compounds used for the biological study.
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Figure 2: Compounds 1–4 induced cell death in U937 cells. Briefly, U937 cells (1 × 104 cells/mL) were incubat...
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Scheme 1: Synthesis of pentafluoro-(2-iodophenyl)-λ6-sulfane (7).
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Scheme 2: Synthesis of unsymmetrical ortho-SF5 diaryliodonium salts 3p, 4b, 5a and 6a.
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Figure 3: X-ray crystallographic structure of 3p drawn at 50% probability (CCDC 1573953).
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Figure 4: Ortho-SF5 phenyl iodonium salts 3p and 5a and their structural components 7 and 9 induced cell deat...
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Figure 5: 3k, 3m and 3p induced cell death in AGLCL, a human normal B cell line. Briefly, AGLCL cells (1 × 104...
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- Full Research Paper
- Published 29 Mar 2012
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Scheme 1: Preparation of ArSF4Cl 2.
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Scheme 2: Preparation of Ar(SF4Cl)n from Ar(SH)n (n = 2, 3).
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Scheme 3: Reaction mechanism for the formation of ArSF4Cl.
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Scheme 4: Reaction mechanism for the formation of trans and cis-ArSF4Cl.
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Scheme 5: Preparation of ArSF5 with ZnF2.
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Scheme 6: Preparation of PhSF5 with anhydrous HF.
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Scheme 7: Preparation of 3a with HF–pyridine.
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Scheme 8: Preparation of polyfluorinated ArSF5.
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Scheme 9: Preparation of aryl bis- and tris(sulfur pentafluorides), Ar(SF5)n (n = 2,3).
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