TY - JOUR A1 - Adamkiewicz, Malgorzata A1 - O’Hagan, David A1 - Hähner, Georg T1 - Organic chemistry on surfaces: Direct cyclopropanation by dihalocarbene addition to vinyl terminated self-assembled monolayers (SAMs) JF - Beilstein Journal of Organic Chemistry PY - 2014/// VL - 10 SP - 2897 EP - 2902 SN - 1860-5397 DO - 10.3762/bjoc.10.307 PB - Beilstein-Institut JA - Beilstein J. Org. Chem. UR - https://doi.org/10.3762/bjoc.10.307 KW - difluoro- KW - dichloro- KW - dibromomethylenecyclopropanes KW - dihalocarbenes KW - self-assembled monolayers KW - surface coating N2 - C11-Vinyl-terminated self-assembled monolayers (SAMs) on silica surfaces are successfully modified in C–C bond forming reactions with dihalocarbenes to generate SAMs, terminated with dihalo- (fluoro, chloro, bromo) cyclopropane motifs with about 30% surface coverage. ER -