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Oxidative and reductive cyclization in stiff dithienylethenes

  • Michael Kleinwächter,
  • Ellen Teichmann,
  • Lutz Grubert,
  • Martin Herder and
  • Stefan Hecht

Beilstein J. Org. Chem. 2018, 14, 2812–2821, doi:10.3762/bjoc.14.259

Graphical Abstract
  • dithienylethenes bearing benzonitrile substituents an additional and rare reductive electrocyclization was observed. The mechanism underlying both observed electrocyclization pathways has been elucidated. Keywords: diarylethenes; electrochromism; molecular switches; (spectro)electrochemistry; Introduction
  • cyclovoltammetry (CV) and spectro-electrochemistry (SEC) [33]. Our present study is aiming to: 1) elucidate the influence of possible double bond isomerization on the electrochromism of sDTEs; 2) explore the structural effect of varying ring size as well as electronic modification; and 3) contribute to the
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Published 09 Nov 2018
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