Beilstein J. Org. Chem.2017,13, 845–854, doi:10.3762/bjoc.13.85
performed in vivo substrate promiscuity tests following a combinatorial approach [41][66]. The resulting products entailed pimarane- and abietane-type diterpenes as well as the trans-clerodane type diterpene kolavenol, a putative intermediate in the salvinorin A biosynthesis.
Other bifunctional diterpene
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Graphical Abstract
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Isoprenoid biosynthetic pathways and examples for their engineering in heterologous production syst...
Beilstein J. Org. Chem.2014,10, 276–281, doi:10.3762/bjoc.10.23
, University of Würzburg, Am Hubland, Würzburg 97074, Germany Government Degree College at Amadala valasa, Srikakulam District, Andhra Pradesh 532185, India 10.3762/bjoc.10.23 Abstract Decandrinin (1), an unprecedented C9-spiro-fused 7,8-seco-ent-abietane, was obtained from the bark of an Indian mangrove
combination with quantum-chemical calculations. Decandrinin is the first 7,8-seco-ent-abietane.
Keywords: abietane; absolute configuration; Ceriops decandra; circular dichroism; decandrinin; Rhizophoraceae; Introduction
Ceriops decandra is a mangrove of the family Rhizophoraceae. It is widely distributed
, five kauranes, and 16 lupanes). Recently, some of us have reported on the isolation of eleven new diterpenes from this plant, named decandrins A–K [7], of which nine belong to the group of abietanes.
Seco-abietane diterpenoids are a small group of natural products. To date, a total of 58 such compounds