Beilstein J. Nanotechnol.2014,5, 1016–1030, doi:10.3762/bjnano.5.115
][10]. The assumption of a surface CTC in the visible light catalysis was supported by subsequent work on various other types of systems, such as phenoliccompounds [11][12], fluoroquinolone antibacterial agents [13], and various colorless aromatic pollutants [14].
Despite the extensive experimental
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Figure 1:
Optimized structure of pollutants in neutral and deprotonated forms calculated at DFT/B3LYP/DZVP le...
Beilstein J. Nanotechnol.2014,5, 346–354, doi:10.3762/bjnano.5.39
electrocatalytic properties. However, it is rarely reported that ECNFs were utilized directly in the design of enzyme-based biosensors.
Phenoliccompounds, which widely occur in processes of agriculture and industry, often cause severe health problems in human beings and animals [28]. So it is important to develop
fast and effective methods to detect phenoliccompounds. Laccase (benzendiol:oxygen oxidoreductases; EC 1.10.3.2), a multicopper oxidase widely distributed in plant and fungal species, can reduce oxygen directly to water through a four-electron transfer step, and this chemical reaction does not produce
hydrogen peroxide (H2O2) [29]. Based on this, laccase has been utilized to fabricate a variety of biosensors, including biosensors for phenoliccompounds [30]. Nafion, a linear perfluorosulfonate polymer possesses good cation-exchange properties, biocompatibility and film-forming properties and has been
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Figure 1:
SEM images of the ECNFs (a) and the suface of laccase–Nafion–ECNFs/GCE (b). Insert: the diameter di...