Beilstein J. Nanotechnol.2015,6, 293–299, doi:10.3762/bjnano.6.27
assigned to small silver clusters. The correlation between the evolution of the surface plasmon band and the decrease of the silver cluster band in the UV confirms the conversion of silver clusters to plasmonic silver nanoparticles. Remaining single small silver clusters on the surface of the plasmonic
nanoparticles give rise to a strong surface enhanced multicolor luminescence.
Experimental
Preparation of fruit extract
Ananas comosus: The pineapple extract was prepared by cutting away all parts except the yellow pulp of the pineapple. This was then sliced and blended after which the pulp was filtered through
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Figure 1:
Time evolvement of UV–vis spectra of ≈1:10 orange extract/AgNO3 solution between 5 and 65 minutes a...
Beilstein J. Nanotechnol.2014,5, 696–710, doi:10.3762/bjnano.5.82
][86][87].
In comparison with quantum dots sensitized semiconductors the usage of plasmonicnanoparticles as photosensitizers is more stable and environmentally friendlier. The shortcoming of these plasmonic metals is their high price. This holds true for gold in particular. Moreover, the
photoconversion efficiency of plasmonicnanoparticles photosensitized semiconductors is not as good as that of quantum dots sensitized semiconductors. Plasmon-enhanced photocatalysis is still in an early research stage and the underlying mechanism is unclear. Furthermore, there are contradictory phenomena
that the resonant wavelength and SPR intensity depend not only on the nature of the metal, but also on the size and shape of the metallic nanostructures. The control of parameters such as composition, size and shape of plasmonicnanoparticles facilitates the design of nanostructures interacting with
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Figure 1:
Schematic steps for the photocatalytic reactions occuring on the surface of a semiconductor. Adapte...