Beilstein J. Nanotechnol.2013,4, 868–874, doi:10.3762/bjnano.4.98
indirectly confirmed the flexibility of the solution route in preparation of semiconductors with controlled elemental composition.
We recently successfully demonstrated electroless deposition of molecular precursors (Cu- and In-oximato complexes and thiourea) into track-etched polycarbonate templates and the
synthesis of stoichiometric ternary CuInS2 nanorod arrays [9]. In the present work, we extend our method to the photochemically even more active CuInSe2 material and demonstrate the synthesis of uniform polycrystalline CuInSe2 nanorod arrays. Selenourea was used as a Se source analogous to thiourea in our
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Scheme 1:
Reaction scheme of the ternary CuInSe2 compound obtained by the precursor synthesis method employin...
Beilstein J. Nanotechnol.2012,3, 277–284, doi:10.3762/bjnano.3.31
solution containing thiourea (Scharlau) and cadmium chloride (CdCl2) (Merck) as sources of S2− and Cd2+, respectively. The thickness of the films was ~80 nm, as measured with a Veeco Dektak 150 surface profiler. For specific experimental conditions see [22].
ZnS films were grown by coevaporation of
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Figure 1:
XPS measurements on Cu3BiS3 and Cu3BiS3 etched in NH3. (a) Overview spectrum showing that Na, oxide...