Beilstein J. Nanotechnol.2011,2, 318–326, doi:10.3762/bjnano.2.37
Garching, Germany 10.3762/bjnano.2.37 Abstract The fabrication of precise 2D Au nanoparticle arrays over a large area is presented. The technique was based on pre-patterning of the substrate before the deposition of a thin Au film, and the creation of periodic particle arrays by subsequent dewetting
induced by annealing. Two types of pre-patterned substrates were used: The first comprised an array of pyramidal pits and the second an array of circular holes. For the dewetting of Au films on the pyramidal pit substrate, the structural curvature-driven diffusion cooperates with capillarity-driven
diffusion, resulting in the formation of precise 2D particle arrays for films within a structure dependent thickness-window. For the dewetting of Au films on the circular hole substrate, the periodic discontinuities in the films, induced by the deposition, can limit the diffusion paths and lead to the
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Figure 1:
SEM images at 45° tilt of (a) a square array of pyramidal pits (substrate A) and (b) an array of ci...
Beilstein J. Nanotechnol.2010,1, 21–23, doi:10.3762/bjnano.1.4
minimizing dewetting process on top of an appropriately chosen substrate [5].
Bottom up approaches mainly can be divided into gas phase condensation [2] or various wet chemical routes [1]. Besides scientific curiosity, the motivation behind all these preparational efforts is certainly to obtain NPs optimized