Nanoscale isoindigo-carriers: self-assembly and tunable properties

• Tatiana N. Pashirova,
• Andrei V. Bogdanov,
• Lenar I. Musin,
• Julia K. Voronina,
• Irek R. Nizameev,
• Marsil K. Kadirov,
• Vladimir F. Mironov,
• Lucia Ya. Zakharova,
• Shamil K. Latypov and
• Oleg G. Sinyashin

Beilstein J. Nanotechnol. 2017, 8, 313–324, doi:10.3762/bjnano.8.34

• -order cumulant expansion methods. The effective hydrodynamic radius (RH) was calculated according to the Einstein–Stokes equation: D = kBT/6πηRH, in which D is the diffusion coefficient, kB is the Boltzmann constant, T is the absolute temperature, and η is the viscosity. The diffusion coefficient was

Nanocrystalline ZrO₂ and Pt-doped ZrO₂ catalysts for low-temperature CO oxidation

• Amit Singhania and
• Shipra Mital Gupta

Beilstein J. Nanotechnol. 2017, 8, 264–271, doi:10.3762/bjnano.8.29

• anthropogenic activities. The catalytic CO oxidation is a very well established and exploited process. So far, noble metals such as Pt, Pd, Rh and Au dominated as catalysts for CO oxidation [10][11][12]. Various supports such as Al2O3, TiO2, SiO2, CeO2, Fe2O3 and carbon nanotubes (CNTs) have also been used for

• CO oxidation by different researchers [13][14][15][16]. The addition of precious metals such as Pd, Pt and Rh increased the reactivity of the support by increasing its oxygen mobility and number of oxygen vacancies (the source of oxygen in CO oxidation) [10][11][12]. In recent years, ZrO2 has been

Nanocrystalline TiO₂/SnO₂ heterostructures for gas sensing

• Barbara Lyson-Sypien,
• Anna Kusior,
• Mieczylaw Rekas,
• Jan Zukrowski,
• Marta Gajewska,
• Katarzyna Michalow-Mauke,
• Thomas Graule,
• Marta Radecka and
• Katarzyna Zakrzewska

Beilstein J. Nanotechnol. 2017, 8, 108–122, doi:10.3762/bjnano.8.12

• were carried out in dry atmosphere. The synthetic air contained less than 1 ppm of water vapor while that of hydrogen + argon mixture had less than 10 ppm of contaminants. The relative humidity level was verified to be of about 0–1% RH at room temperature. Dynamic changes in the electrical resistance

Cubic chemically ordered FeRh and FeCo nanomagnets prepared by mass-selected low-energy cluster-beam deposition: a comparative study

• Veronique Dupuis,
• Anthony Robert,
• Arnaud Hillion,
• Ghassan Khadra,
• Nils Blanc,
• Damien Le Roy,
• Florent Tournus,
• Clement Albin,
• Olivier Boisron and
• Alexandre Tamion

Beilstein J. Nanotechnol. 2016, 7, 1850–1860, doi:10.3762/bjnano.7.177

• of chemical ordering in the B2 phase for equiatomic AB alloys. The B2 structure can be seen as the imbrication of two simple cubic sub-lattices, each occupied by either A or B atoms (with A = Fe and B = Rh/Co for FeRh/FeCo). Indeed, the structure factor is expected to present two maxima at fA + fB

• spectroscopy experiments at each specific Fe and Rh M edge (respectively the Co L edge), at the “X-Treme” beamline at the Swiss Light Source for the FeRh sample and at the “DEIMOS” beamline at the SOLEIL synchrotron for FeCo for various nanocluster sizes (Figure 9); before and after annealing of the same

• obtained the experimental persistence of high ferromagnetic magnetization down to 3 K for size-selected chemically ordered B2-like FeRh nanocrystals up to 5 nm in diameter. In particular, magnetic measurements on annealed 3.3 nm FeRh samples, have demonstrated ferromagnetic alignment of Fe and Rh at low

Role of RGO support and irradiation source on the photocatalytic activity of CdS–ZnO semiconductor nanostructures

• Suneel Kumar,
• Rahul Sharma,
• Vipul Sharma,
• Gurunarayanan Harith,
• Vaidyanathan Sivakumar and
• Venkata Krishnan

Beilstein J. Nanotechnol. 2016, 7, 1684–1697, doi:10.3762/bjnano.7.161

• degradation of MO under irradiation from natural sun light. Comparison of photocatalytic activities of CdS–ZnO–RGO based nanocomposites for degradation of pollutants, including methylene blue (MB), rhodamine B (Rh B) and MO. Acknowledgements We are thankful to Advanced Materials Research Centre (AMRC), IIT

Development of adsorptive membranes by confinement of activated biochar into electrospun nanofibers

• Mehrdad Taheran,
• Mitra Naghdi,
• Satinder K. Brar,
• Emile Knystautas,
• Mausam Verma,
• Rao. Y. Surampalli and
• Jose. R. Valero

Beilstein J. Nanotechnol. 2016, 7, 1556–1563, doi:10.3762/bjnano.7.149

• concentration of 10 wt % and stirred until a clear solution was obtained. Activated biochar at ratios of 0, 0.5, 1, 1.5 and 2% (w/w) of the polymer was added to the solution and the mixture was stirred for 48 h. Nanofibrous membranes were fabricated via electrospinning under ambient conditions (T = 25 °C, RH

A composite structure based on reduced graphene oxide and metal oxide nanomaterials for chemical sensors

• Vardan Galstyan,
• Elisabetta Comini,
• Iskandar Kholmanov,
• Andrea Ponzoni,
• Veronica Sberveglieri,
• Nicola Poli,
• Guido Faglia and
• Giorgio Sberveglieri

Beilstein J. Nanotechnol. 2016, 7, 1421–1427, doi:10.3762/bjnano.7.133

• and ZnO annealed at 250 °C. Dynamical response of ZnO and RGO–ZnO structures at 250 °C and RH = 50% @ 20 °C: (a) towards 50 and 100 ppm of acetone and (b) towards 100 and 250 ppm of ethanol. Schematic diagram of the sensing mechanism between acetone and the RGO–ZnO structure: Oxygen is absorbed on the

• ethanol at a working temperature of 250 °C and in humid air (relative humidity RH = 50% @ 20 °C). Calibration curve for acetone at an operating temperature of 250 °C and in a humid air background (RH = 50% @ 20 °C). The results of the compositional analysis of as-prepared and annealed samples (at 100 and

Microwave synthesis of high-quality and uniform 4 nm ZnFe₂O₄ nanocrystals for application in energy storage and nanomagnetics

• Christian Suchomski,
• Ben Breitung,
• Ralf Witte,
• Michael Knapp,
• Sondes Bauer,
• Tilo Baumbach,
• Christian Reitz and
• Torsten Brezesinski

Beilstein J. Nanotechnol. 2016, 7, 1350–1360, doi:10.3762/bjnano.7.126

• in a Rh matrix. The center shifts are quoted relative to α-Fe foil at room temperature. The spectra were analyzed using the WinNORMOS software [24]. Transmission electron microscopy was performed on a Tecnai G2-F20ST microscope (FEI) operated at 200 keV. The bright-field images were analyzed using

Influence of ambient humidity on the attachment ability of ladybird beetles (Coccinella septempunctata)

• Lars Heepe,
• Jonas O. Wolff and
• Stanislav N. Gorb

Beilstein J. Nanotechnol. 2016, 7, 1322–1329, doi:10.3762/bjnano.7.123

• atmosphere Traction force experiments were performed in a polymethylmethacrylate (PMMA) chamber (30 × 14 × 14 cm) in which relative humidity could be manipulated by the controlled mixture of dry and wetted air (Figure 2, for details see [14]). For this experiment, three levels of relative humidity (RH) were

• used: 15%, 60% and 99%. The RH was monitored with a P330 digital hygrometer (Dostmann electronic GmbH, Wertheim-Reicholzheim, Germany). To generate humid conditions, air was passed through a water bottle, so that the vapour concentration in the air increased. To reach 99% of relative humidity, slight

• . Additionally, to the three previously used humidity adjustments (RH of 15%, 60% and 99%), we made some observations at RH higher than 99%, when water began to condense on the substrate. Results Observational experiments We observed that the beetle’s attachment is affected, as the water begins to condense on

On the pathway of cellular uptake: new insight into the interaction between the cell membrane and very small nanoparticles

• Claudia Messerschmidt,
• Daniel Hofmann,
• Anja Kroeger,
• Katharina Landfester,
• Volker Mailänder and
• Ingo Lieberwirth

Beilstein J. Nanotechnol. 2016, 7, 1296–1311, doi:10.3762/bjnano.7.121

• rn and the z-weighted radius rz from the entirety of measured particles with The values for the effective z-average Stokes–Einstein hydrodynamic radii RH as well as the polydispersity index PDI (determined by the Cumulant method) are given in Supporting Information File 1, Table S1. In order to

Cantilever bending based on humidity-actuated mesoporous silica/silicon bilayers

• Christian Ganser,
• Gerhard Fritz-Popovski,
• Roland Morak,
• Parvin Sharifi,
• Benedetta Marmiroli,
• Barbara Sartori,
• Heinz Amenitsch,
• Thomas Griesser,
• Christian Teichert and
• Oskar Paris

Beilstein J. Nanotechnol. 2016, 7, 637–644, doi:10.3762/bjnano.7.56

• structures that swell anisotropically and differently between the two layers upon the change of relative humidity (RH) [8]. This bilayer principle has been used to build simple artificial actuators based on the swelling of paper–plastic bilayers [9], and also more general routes have been proposed to create

• method [18] was used to calibrate the cantilevers and was performed directly before every measurement. In order to start every experiment under the same conditions, the first step was to reduce RH to the lowest possible value (around 5%). The cantilever was left in these conditions for several hours to

• equilibrate RH and the cantilever deflection to a stationary value. From this point, the adsorption curve followed by the desorption curve were recorded stepwise with 30–45 min equilibration time before reading out the cantilever deflection for each step. A cross section of the AFM cantilever after the

Case studies on the formation of chalcogenide self-assembled monolayers on surfaces and dissociative processes

• Yongfeng Tong,
• Tingming Jiang,
• Azzedine Bendounan,
• Makri Nimbegondi Kotresh Harish,
• Angelo Giglia,
• Stefan Kubsky,
• Fausto Sirotti,
• Luca Pasquali,
• Srinivasan Sampath and
• Vladimir A. Esaulov

Beilstein J. Nanotechnol. 2016, 7, 263–277, doi:10.3762/bjnano.7.24

• . Interestingly, on transition metals such as Rh, W and Ni, there are observations of multicomponent S 2p spectra [66][67][68], which could be due to some type of interface sulfide layers. Understanding the interfaces in these situations is thus very important. A good knowledge of monolayer atomic chalcogen

pH-Triggered release from surface-modified poly(lactic-co-glycolic acid) nanoparticles

• Manuel Häuser,
• Klaus Langer and
• Monika Schönhoff

Beilstein J. Nanotechnol. 2015, 6, 2504–2512, doi:10.3762/bjnano.6.260

• polymer than PDADMAC. Released amount of PDADMAC per surface area in dependence of the pH. The amount of released PDADMAC was related to the total particle surface to yield the released amount per surface area. Zeta potential (ζ) and hydrodynamic radii (RH) of PAA-coated PLGA-PEI nanoparticles in

Lower nanometer-scale size limit for the deformation of a metallic glass by shear transformations revealed by quantitative AFM indentation

• Arnaud Caron and
• Roland Bennewitz

Beilstein J. Nanotechnol. 2015, 6, 1721–1732, doi:10.3762/bjnano.6.176

• radiation and differential scanning calorimetry (DSC). We observed a broad diffraction peak at 39.866 degrees of 2θ, a clear glass transition at Tg = 223 °C, and crystallization at Tx = 295 °C using a heating rate RH = 0.67 K/s. The surface of an as-spun Pt-based metallic glass ribbon was prepared by

Structural and magnetic properties of iron nanowires and iron nanoparticles fabricated through a reduction reaction

• Marcin Krajewski,
• Wei Syuan Lin,
• Hong Ming Lin,
• Katarzyna Brzozka,
• Sabina Lewinska,
• Natalia Nedelko,
• Anna Slawska-Waniewska,
• Jolanta Borysiuk and
• Dariusz Wasik

Beilstein J. Nanotechnol. 2015, 6, 1652–1660, doi:10.3762/bjnano.6.167

• = 0.1542 nm) and a LYNXEYE detector and also a standard Mössbauer spectrometer (POLON) equipped with a 57Co/Rh source of γ-radiation placed on a vibrator, working in a constant acceleration mode. Magnetic properties were determined by means of an Oxford Instruments Ltd. vibrating sample magnetometer (VSM

Possibilities and limitations of advanced transmission electron microscopy for carbon-based nanomaterials

• Xiaoxing Ke,
• Carla Bittencourt and
• Gustaaf Van Tendeloo

Beilstein J. Nanotechnol. 2015, 6, 1541–1557, doi:10.3762/bjnano.6.158

• ]. Systematic studies of different metals on CNTs has been reported, including Au, Pt, Pd, Rh, Cu and Ti [67][70][71][72][73][74][75]. Early studies using HRTEM have revealed that Au and Pt form mostly well-crystallized nanocrystal islands with limited contact areas with the CNTs walls, whereas Pd and Rh form

Pt- and Pd-decorated MWCNTs for vapour and gas detection at room temperature

• Hamdi Baccar,
• Atef Thamri,
• Pierrick Clément,
• Eduard Llobet and
• Adnane Abdelghani

Beilstein J. Nanotechnol. 2015, 6, 919–927, doi:10.3762/bjnano.6.95

• multiwalled carbon nanotubes decorated with Au, Pd or Ni nanoparticles (formed by evaporation of metals) and also with Rh or Pt nanoparticles (from a colloidal solution) for detecting benzene, nitrogen dioxide and hydrogen sulphide [34][35][36]. Although the detection could be performed at room temperature

• within the sensor chamber was 10% RH. Results and Discussion Morphological and compositional studies The morphology of the plasma-treated, metal-decorated, multiwalled carbon nanotubes was studied by TEM and the main results are summarised in Figure 1. It can be derived that the sputtering technique

• with bare oxygen-plasma-treated or Rh- and FeO-decorated MWCNTs, which were found to be responsive to aromatic VOCs [24][36][38]. Pd- and Pt-decorated MWCNT sensors were responsive to the non-aromatic VOCs tested. Typical response and recovery cycles toward non-aromatic VOCs are shown Figure 3 and

Capillary and van der Waals interactions on CaF₂ crystals from amplitude modulation AFM force reconstruction profiles under ambient conditions

• Annalisa Calò,
• Oriol Vidal Robles,
• Sergio Santos and
• Albert Verdaguer

Beilstein J. Nanotechnol. 2015, 6, 809–819, doi:10.3762/bjnano.6.84

• Figure 1a. At ambient temperature and RH (RH ca. 40%) water accumulates at the flat terraces on the crystal surface forming rounded islands [40] (see Figure 1b and Experimental section) over a time scale of few minutes. Under our experimental conditions, the islands exhibited a typical thickness of 1–1.5

• the one shown in Figure 2b. A similar distance of 3.93 ± 0.40 nm from the jump-to-contact to the point of zero separation is found in the approach path of force curves collected in contact mode on CaF2 crystals with adsorbed water layers on top of the surface (see Figure 2c) at ca. 40% RH. Force

• of hydrated CaF2 and the expected thickness of the water layer on top of the tip (1 nm at room temperature, RH ca. 40% and in the absence of contamination) [46]. This distance indicates that water meniscus forms upon geometrical contact of the absorbed water layers on top of the tip and the crystal

Magnetic properties of self-organized Co dimer nanolines on Si/Ag(110)

• Lisa Michez,
• Kai Chen,
• Fabien Cheynis,
• Frédéric Leroy,
• Alain Ranguis,
• Haik Jamgotchian,
• Margrit Hanbücken and
• Laurence Masson

Beilstein J. Nanotechnol. 2015, 6, 777–784, doi:10.3762/bjnano.6.80

• ]. Although the shoulder at +4 eV from the L3 edge can be observed for other Co nanostructures (e.g., an ultrathin 1.25 ML Co film grown on Rh(111) [33] or a superlattice of 0.35 ML 2D Co nanoparticles on Au(788) [4]) this feature is more pronounced in the case of our Co nanolines, especially for low Co

Nanoparticle shapes by using Wulff constructions and first-principles calculations

• Georgios D. Barmparis,
• Zbigniew Lodziana,
• Nuria Lopez and
• Ioannis N. Remediakis

Beilstein J. Nanotechnol. 2015, 6, 361–368, doi:10.3762/bjnano.6.35

• ], Si in amorphous SiO2 [37], diamond in amorphous C [38], Rh and Pd under oxidizing conditions [39], Cu in N gas [40], Au under oxidizing conditions [41], noble metals with an environment [42], complex metal hydrides [43], iron carbides [44] and dawsonites [45][46], just to name a few. Atomistic Wulff

Boosting the local anodic oxidation of silicon through carbon nanofiber atomic force microscopy probes

• Gemma Rius,
• Matteo Lorenzoni,
• Soichiro Matsui,
• Masaki Tanemura and
• Francesc Perez-Murano

Beilstein J. Nanotechnol. 2015, 6, 215–222, doi:10.3762/bjnano.6.20

• voltage is 20 V, relative humidity (RH) is 36%. Results of LAO-AFM on Si with CNF (a) and Si (b) probes as a function of the bias voltage (in V). Writing speed is 1 μm/s, RH is 36%. Monitoring chemical and mechanical stability of CNF probes for LAO-AFM. SEM images before (a) and after (c) the definition

• common writing speed is 4 μm/s, RH is 30%. Kinetics of LAO-AFM on Si by using CNF versus Si probes. a) Line height upon writing speed for a bias voltage of 20 V. b) Line height upon bias voltage for a writing speed of 1 μm/s. Full width at half maximum (FWHM) of the same features upon writing speed (c

The capillary adhesion technique: a versatile method for determining the liquid adhesion force and sample stiffness

• Daniel Gandyra,
• Stefan Walheim,
• Stanislav Gorb,
• Wilhelm Barthlott and
• Thomas Schimmel

Beilstein J. Nanotechnol. 2015, 6, 11–18, doi:10.3762/bjnano.6.2

• humidity during the measurements was roughly RH = 50% and the temperature was 22 °C. Literature values citing Young’s modulus of human head hair are scarce. For example, in [27] a value of 3.89 × 105 N/cm2 (RH = 60%) was indicated. In [28], a range between 1.5 and 4.6 × 105 N/cm2 (RH = 65%) was indicated

• for 2–92 year-old humans, and in [29] a range of 1.23–4.10 × 105 N/cm2 (RH = 30%) was given for 15–35 year-old humans. Thus, our results (3.04 × 105 N/cm2, RH = 50%, hairs from a 29 year-old human) are in good agreement with these literature values, indicating that CAT yields reliable results

Synthesis and characterization of fluorescence-labelled silica core-shell and noble metal-decorated ceria nanoparticles

• Rudolf Herrmann,
• Markus Rennhak and
• Armin Reller

Beilstein J. Nanotechnol. 2014, 5, 2413–2423, doi:10.3762/bjnano.5.251

• determination of the number of thiol groups and an estimate for the number of fluorescent molecules per nanoparticles, including a scattering correction, have been developed. Ceria nanoparticles decorated with noble metals (Pt, Pd, Rh) are models for the decomposition products of automobile catalytic converters

• which serve as models for the particles formed by mechanical decomposition of automobile catalytic converters. We succeeded in controlling the agglomeration of small (8–10 nm) ceria NP and obtaining almost monodisperse agglomerates (40–260 nm) which can be decorated with noble metal NP (Pt, Pd, Rh, 2–5

Inorganic Janus particles for biomedical applications

• Isabel Schick,
• Steffen Lorenz,
• Dominik Gehrig,
• Stefan Tenzer,
• Wiebke Storck,
• Karl Fischer,
• Dennis Strand,
• Frédéric Laquai and
• Wolfgang Tremel

Beilstein J. Nanotechnol. 2014, 5, 2346–2362, doi:10.3762/bjnano.5.244

• highly monodisperse with sizes of Rh(Au) = 6.5 nm, Rh(Au@Fe3O4) = 12.8 nm, and Rh(Au@Fe3O4@SiO2) = 19.5 nm. The progressive increase of the hydrodynamic radii is in good accordance with the increase in particle diameter. The thickness of the silica shell was determined by TEM, and matches the expected

The gut wall provides an effective barrier against nanoparticle uptake

• Heike Sinnecker,
• Thorsten Krause,
• Sabine Koelling,
• Ingmar Lautenschläger and
• Andreas Frey

Beilstein J. Nanotechnol. 2014, 5, 2092–2101, doi:10.3762/bjnano.5.218

• volume of 5 mL. An internal standard (rhodium, Rh) was added to every sample. The mass of europium 153Eu and internal standard 103Rh was measured with a PE-Elan DRC II ICP-MS, the amount of europium in the samples was derived from a standard curve, established with Eu standard solution (Bernd Kraft GmbH