Beilstein J. Nanotechnol.2010,1, 101–107, doi:10.3762/bjnano.1.12
, such as the presence of regions with two overlapping layers, missing particles (voids), and dislocations separating domains of hexagonal order. Aside from the presence of local defects, the spin-coating technique has proven to be able to produce long range hexagonal order over areas of 10 × 10 mm2 with
schematically depicted in the inset of Figure 5. The Co film does not cover all NPs equally, but only the top layer of NPs. In a 'monolayer' of NPs (that means one layer of particles on average) there exist not only holes and dislocations in the array but also areas with a second layer (see Figure 1). Hence
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Figure 1:
AFM (a) and SEM (b) images showing the self-assembly of the NPs in a close-packed hexagonal structu...