Beilstein J. Nanotechnol.2011,2, 237–251, doi:10.3762/bjnano.2.28
on state-of-the-art X-ray absorption spectroscopy (XAS) on 3rd generation synchrotron sources such as the ESRF and BESSY II.
In general, XAS deals with the excitation of core-level electrons, with their element-specific binding energies, by incident X-rays. After absorption of an X-ray photon, a core
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Figure 1:
Effective backscattering amplitude of O, Fe, and Pt as a function of wave number and phase shift. A...
Beilstein J. Nanotechnol.2010,1, 24–47, doi:10.3762/bjnano.1.5
results.
Figure 6 shows Pt-4f and Fe-2p XP spectra of (9.8 ± 0.6) nm FePt NPs in the metallic state and after 24 h exposure to air. Oxidation in ambient air becomes obvious by a clear energy shift of the Fe 2p3/2 corelevel to about 711 eV with a shoulder at the metal position still present. By comparison
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Scheme 1:
Preparation of NPs by a reverse micelle technique. PS-b-P2VP or PS-b-P4VP is dispersed in anhydrous...