A stretchable triboelectric nanogenerator made of silver-coated glass microspheres for human motion energy harvesting and self-powered sensing applications

• Hui Li,
• Yaju Zhang,
• Yonghui Wu,
• Hui Zhao,
• Weichao Wang,
• Xu He and
• Haiwu Zheng

Beilstein J. Nanotechnol. 2021, 12, 402–412, doi:10.3762/bjnano.12.32

• sustainable electricity. However, there is a need for improvement regarding the output performance and the complex fabrication of TENG devices. Here, a triboelectric nanogenerator in single-electrode mode is fabricated by a simple strategy, which involves a sandwich structure of silicone rubber and silver

• motion energy; silver-coated glass microsphere; single-electrode mode; triboelectric nanogenerator; wearable; Introduction Traditional batteries cannot provide a durable and reliable power supply for small portable electronic devices, personalized healthcare, and Internet-of-Things (IoT) devices [1][2

• ]. This form of energy conversion can not only provide sustainable power for electronic systems, but also provide reliable solutions for active sensing and human–computer interfaces [14]. A stretchable TENG with double-helix structure was previously designed. It consisted of silver-coated glass

Exploring the fabrication and transfer mechanism of metallic nanostructures on carbon nanomembranes via focused electron beam induced processing

• Christian Preischl,
• Linh Hoang Le,
• Elif Bilgilisoy,
• Armin Gölzhäuser and
• Hubertus Marbach

Beilstein J. Nanotechnol. 2021, 12, 319–329, doi:10.3762/bjnano.12.26

• nanostructures by investigating the fabrication and transfer on the example of a SAM of TPT on a silver substrate. Consequently, a different chemical etching process is needed for the lift-off process during the transfer. In the case of gold, an etching solution of KI/I2/H2O is used. Whereas in this approach

• in Figure 2f. In Figure 2e no obvious deposit is visible in the SE micrograph after dosing Co(CO)3NO. The faint square shape possibly comes from beam damage. The local AE spectrum acquired in the irradiated area exhibits no Co signals but carbon and silver signals, which can be assigned to the

• (NO3)3 solution dissolves the cobalt oxide structures along with the silver substrate. In summary, the results from the transfer process of EBID structures on a SAM grown on silver indicate that, in the case of iron, the structures are decreasing in height. Also a bright circular shape, most probably

Doxorubicin-loaded gold nanorods: a multifunctional chemo-photothermal nanoplatform for cancer management

• Uzma Azeem Awan,
• Abida Raza,
• Shaukat Ali,
• Rida Fatima Saeed and
• Nosheen Akhtar

Beilstein J. Nanotechnol. 2021, 12, 295–303, doi:10.3762/bjnano.12.24

• -related side effects in cancer management. Experimental Materials CTAB (99.9%), hydrogen tetrachloroaurate(III) trihydrate (HAuCl4·3H2O 99%), ʟ-ascorbic acid (C6H8O6, 99%), sodium borohydride (NaBH4, 98%), silver nitrate (AgNO3, 99%), doxorubicin, (98%) poly(sodium 4-styrenesulfonate) (PSS; Mw = 70,000

Characterization, bio-uptake and toxicity of polymer-coated silver nanoparticles and their interaction with human peripheral blood mononuclear cells

• Sahar Pourhoseini,
• Reilly T. Enos,
• Angela E. Murphy,
• Bo Cai and
• Jamie R. Lead

Beilstein J. Nanotechnol. 2021, 12, 282–294, doi:10.3762/bjnano.12.23

• , Columbia, SC, 29208, United States 10.3762/bjnano.12.23 Abstract Silver nanoparticles (AgNPs) are widely used in medical applications due to their antibacterial and antiviral properties. Despite the extensive study of AgNPs, their toxicity and their effect on human health is poorly understood, as a result

• , characterization, and study of transformations to obtain a better understanding of NP uptake and toxicity. Statistical analysis indicated that there might be an individual variability in response to NPs, although more research is required. Keywords: human peripheral blood mononuclear cells; silver ions; silver

• applications [2]. NPs are present in numerous commercial products such as cosmetics, electronics, and textiles. Also, they are widely used in industry, including various biomedical and drug-delivery applications for the treatment of diseases [3][4][5][6]. Silver nanoparticles (AgNPs) are one of the most

Gold(I) N-heterocyclic carbene precursors for focused electron beam-induced deposition

• Cristiano Glessi,
• Aya Mahgoub,
• Cornelis W. Hagen and
• Mats Tilset

Beilstein J. Nanotechnol. 2021, 12, 257–269, doi:10.3762/bjnano.12.21

• under electron irradiation. However, this trend is not extended to the recently reported silver carboxylates [39][40]. In gold(I) complexes, only two ligands are present in the coordination sphere, a neutral ligand L and an anionic ligand X. Both ligands influence the complex stability, with an

• iodides [48]. For the triazolium salt the two alkylation reactions were carried out together in a one-pot synthesis [36]. The resulting salts were then reacted with silver oxide to generate the respective Ag(I) NHC complexes. Upon the addition of 1 equiv of gold precursor Au(SMe2)Cl in situ, a

A review on the biological effects of nanomaterials on silkworm (Bombyx mori)

• Sandra Senyo Fometu,
• Guohua Wu,
• Lin Ma and
• Joan Shine Davids

Beilstein J. Nanotechnol. 2021, 12, 190–202, doi:10.3762/bjnano.12.15

• ), graphene oxide, silver nanoparticles (Ag NPs) [24][25][26], quantum dots, and superparamagnetic particles [27] have been reported to have antibacterial properties against Streptococcus mutans [28] and Xanthomonas perforans, antifungal properties against Fusarium oxysporum [27] and Fusarium graminearum [29

• packaging [53]. There is a need to improve food packaging quality to reduce food spoilage caused by pests and also to enhance the shelf life of food products. Nanomaterials are used as an additive in food packaging [54]. Silver nanoparticles, for example, were used as an additive in the manufacture of food

• µg) did not increase the production of ROS and it was suggested that the its effect on hematopoiesis was self-repaired and the damage to the hematopoietic tissues was limited. Zou et al. [155] studied the efficacy in using silver nanoparticle colloids (AgNPC) to reduce the infection caused by BmNPV

Paper-based triboelectric nanogenerators and their applications: a review

• Jing Han,
• Nuo Xu,
• Yuchen Liang,
• Mei Ding,
• Junyi Zhai,
• Qijun Sun and
• Zhong Lin Wang

Beilstein J. Nanotechnol. 2021, 12, 151–171, doi:10.3762/bjnano.12.12

• flexible conductive materials, metallic materials (e.g., copper, zinc, silver, and gold) are still frequently used as electrodes for flexible electronics due to their excellent electrical conductivity. By using the Kapton tape to attach soft stencils to paper, various metals can be deposited through the

• main materials utilized on those P-TENGs were commercial tissue paper and silver nanowires (Ag NWs), which were key to their feasibility. The P-TENGs were built with two conductive paper pieces as the electrodes, which were sandwiched between two commercial tissue paper pieces. Three basic operation

A review on the green and sustainable synthesis of silver nanoparticles and one-dimensional silver nanostructures

• Sina Kaabipour and
• Shohreh Hemmati

Beilstein J. Nanotechnol. 2021, 12, 102–136, doi:10.3762/bjnano.12.9

• Sina Kaabipour Shohreh Hemmati School of Chemical Engineering, Oklahoma State University, Stillwater, Oklahoma, 74078, USA 10.3762/bjnano.12.9 Abstract The significance of silver nanostructures has been growing considerably, thanks to their ubiquitous presence in numerous applications, including

• but not limited to renewable energy, electronics, biosensors, wastewater treatment, medicine, and clinical equipment. The properties of silver nanostructures, such as size, size distribution, and morphology, are strongly dependent on synthesis process conditions such as the process type, equipment

• type, reagent type, precursor concentration, temperature, process duration, and pH. Physical and chemical methods have been among the most common methods to synthesize silver nanostructures; however, they possess substantial disadvantages and short-comings, especially compared to green synthesis

Piezotronic effect in AlGaN/AlN/GaN heterojunction nanowires used as a flexible strain sensor

• Jianqi Dong,
• Liang Chen,
• Yuqing Yang and
• Xingfu Wang

Beilstein J. Nanotechnol. 2020, 11, 1847–1853, doi:10.3762/bjnano.11.166

• silver paste and connected to the anode of the electrolytic cell, and the cathode was the Pt sheet. Oxalic solution (0.3 M) was used as the electrolyte. The applied voltage was 20 V and the duration of its application was 10 min. After selective EC wet etching, the sample with suspended NWs was placed in

Nanocasting synthesis of BiFeO₃ nanoparticles with enhanced visible-light photocatalytic activity

• Thomas Cadenbach,
• Maria J. Benitez,
• A. Lucia Morales,
• Cesar Costa Vera,
• Luis Lascano,
• Francisco Quiroz,
• Alexis Debut and
• Karla Vizuete

Beilstein J. Nanotechnol. 2020, 11, 1822–1833, doi:10.3762/bjnano.11.164

• radicals are the main active species in photocatalytic degradation reactions [22]. The addition of silver nitrate (AgNO3, 2 mM) to the photocatalytic reaction leads to an improvement of the overall efficiency resulting in a complete degradation of RhB after 240 min (Figure 12). This is explained by the

Seebeck coefficient of silicon nanowire forests doped by thermal diffusion

• Shaimaa Elyamny,
• Elisabetta Dimaggio and
• Giovanni Pennelli

Beilstein J. Nanotechnol. 2020, 11, 1707–1713, doi:10.3762/bjnano.11.153

• etching) have been fabricated for this work. At the end of the MACE process step, the chips were covered with granular silver, which has been removed by etching in a HNO3/H2O 1:1 solution for 2 min. SEM inspection confirmed the complete removal of silver from the SiNW forests, which are covered by a thin

Oxidation of Au/Ag films by oxygen plasma: phase separation and generation of nanoporosity

• Abdel-Aziz El Mel,
• Said A. Mansour,
• Mujaheed Pasha,
• Atef Zekri,
• Janarthanan Ponraj,
• Akshath Shetty and
• Yousef Haik

Beilstein J. Nanotechnol. 2020, 11, 1608–1614, doi:10.3762/bjnano.11.143

• silver and gold. In addition, it was shown that the preferential oxidation of silver resulted in a solid-state diffusion of silver toward the surface where it oxidized and formed nanoporous microspheres. The gold phase remaining in the film exhibited nanoporosity due to the injected vacancies at the

• metal/silver oxide interface. Based on the scanning transmission electron microscopy analysis coupled with energy dispersive X-ray mapping a mechanism was proposed based on solid-state diffusion and the Kirkendall effect to explain the different steps occurring during the oxidation process. Keywords

• : metal alloys; nanoporous; oxygen plasma; silver; thin films; Introduction Silver corrosion upon exposure to atomic oxygen is a phenomenon that was highly studied in the 1980s. At that time, the main aim was to avoid the degradation of silver interconnects and switches used in satellites navigating in

High-responsivity hybrid α-Ag₂S/Si photodetector prepared by pulsed laser ablation in liquid

• Raid A. Ismail,
• Hanan A. Rawdhan and
• Duha S. Ahmed

Beilstein J. Nanotechnol. 2020, 11, 1596–1607, doi:10.3762/bjnano.11.142

• Raid A. Ismail Hanan A. Rawdhan Duha S. Ahmed Department of Applied Science, University of Technology, Baghdad, Iraq 10.3762/bjnano.11.142 Abstract We report the synthesis of α-Ag2S nanoparticles (NPs) by one-step laser ablation of a silver target in aqueous solution of thiourea (Tu, CH4N2S

• . Keywords: cetyltrimethylammonium bromide (CTAB); laser ablation; monodisperse; photodetector; silver(I) sulfide (Ag2S); thiourea; Introduction Nanomaterials have attracted considerable attention due to their superior chemical and physical properties. The size-dependent properties of nanomaterials have

• enabled them to be used in many promising applications, for example, catalysis and electronic and optoelectronic devices [1][2][3]. In this regard, controlling particle sizes and attaining them within a narrow size distribution are important. Silver sulfide is an important semiconducting material with a

Optically and electrically driven nanoantennas

• Monika Fleischer,
• Dai Zhang and
• Alfred J. Meixner

Beilstein J. Nanotechnol. 2020, 11, 1542–1545, doi:10.3762/bjnano.11.136

• deposition [41], or on dense silver island films created by pulsed laser deposition [42] or physical vapor deposition [43]. In [44], individual plasmonic nanotags are prepared by coating gold nanoparticle clusters with Raman reporters. This work explores the minimum number of tags required for obtaining a

• ][51]. A recent example of the strong coupling between silver nanorods and photochromic molecules is demonstrated in [52]. Due to the high local field intensity in the gap of a nanodimer, strong polarization of the particle, and consequently, strong SHG from the particle surface, may be expected

Antimicrobial metal-based nanoparticles: a review on their synthesis, types and antimicrobial action

• Matías Guerrero Correa,
• Fernanda B. Martínez,
• Cristian Patiño Vidal,
• Camilo Streitt,
• Juan Escrig and
• Carol Lopez de Dicastillo

Beilstein J. Nanotechnol. 2020, 11, 1450–1469, doi:10.3762/bjnano.11.129

• -based NPs have demonstrated antimicrobial activity over the last years. Several metal and metal oxide NPs, such as silver, copper, zinc oxide, titanium oxide, copper oxide, and nickel oxide NPs, are known to display antimicrobial activity [15][16][17] that depends on their composition, surface

• irradiation time. For example, while Tan et al. [31] obtained spherical silver nanoparticles, Zhou et al. [32] obtained plate-like triangles. Another method used is the pulsed laser ablation technique which is used to synthesize colloidal solutions of Ag [33], Au [34], MgO [35], and ZnO [36] NPs, among others

• bacteria (inhibition zone diameter of E. coli: 22 ± 0.86 mm) and Gram-positive bacteria (inhibition zone diameter of B. subtilis: 23 ± 0.9 mm) [88]. Bio-reduction of silver nitrate with Parkia speciosa leaf extract generated spherical Ag NPs with an average particle size of 31 nm [89]. A major

Wafer-level integration of self-aligned high aspect ratio silicon 3D structures using the MACE method with Au, Pd, Pt, Cu, and Ir

• Mathias Franz,
• Romy Junghans,
• Paul Schmitt,
• Adriana Szeghalmi and
• Stefan E. Schulz

Beilstein J. Nanotechnol. 2020, 11, 1439–1449, doi:10.3762/bjnano.11.128

• layer for the wet etching of silicon. The MACE process has been extensively studied over the last decade [13][14][15][16]. In theory, the process works with a wide range of noble metals. The main focus in research has been set on the noble metals gold (Au) and silver (Ag) [2][17][18][19]. Other studies

Impact of fluorination on interface energetics and growth of pentacene on Ag(111)

• Qi Wang,
• Meng-Ting Chen,
• Antoni Franco-Cañellas,
• Bin Shen,
• Thomas Geiger,
• Holger F. Bettinger,
• Frank Schreiber,
• Ingo Salzmann,
• Alexander Gerlach and
• Steffen Duhm

Beilstein J. Nanotechnol. 2020, 11, 1361–1370, doi:10.3762/bjnano.11.120

• the photon energy, which allowed to determine the coherent position (PH) and the coherent fraction (fH) of the adsorbate atoms [66][69]. The former gave the adsorption distance in terms of the lattice spacing of the silver substrate: dH = d0(n + PH) (typical precision < 0.05 Å), with n being an

Ultrasensitive detection of cadmium ions using a microcantilever-based piezoresistive sensor for groundwater

• Dinesh Rotake,
• Anand Darji and
• Nitin Kale

Beilstein J. Nanotechnol. 2020, 11, 1242–1253, doi:10.3762/bjnano.11.108

• phosphate buffer saline (PBS, pH 7) according to [34] was prepared. The cysteamine SAM was allowed to cross-link with the ᴅʟ-glyceraldehyde solution for at least 2–3 hours by covering the container using silver foil. Stock solutions of 1 mM/10 mL of different salts (AlCl3, MnCl2, CrCl3, HgCl2, PbCl2, CdCl2

Photothermally active nanoparticles as a promising tool for eliminating bacteria and biofilms

• Mykola Borzenkov,
• Piersandro Pallavicini,
• Angelo Taglietti,
• Laura D’Alfonso,
• Maddalena Collini and
• Giuseppe Chirico

Beilstein J. Nanotechnol. 2020, 11, 1134–1146, doi:10.3762/bjnano.11.98

• results regarding antibacterial activity. The advances in the field of nanomaterials exhibiting antibacterial activity are well summarized in recent reviews [1][7][8][9]. In particular, the antibacterial properties of silver nanoparticles (Ag NPs) and Ag-NP-based polymeric materials are the most

• nanoparticles are due to the resonant oscillation of the surface electrons, called surface plasmons (e.g., plasmonic gold and silver nanoparticles) [38], or they are due to the energy of the band transitions (e.g., Cu2+ d–d transition in CuS nanoparticles) [39]. Under visible–NIR light irradiation, these

• field regarding the use of several gold nanostructures, such as nanocages, nanorods, nanostars, and core–shell silver/gold nanoparticles for laser-driven hyperthermal ablation of multi-drug resistant bacteria [52]. Therefore, we will focus here on the latest achievements in this field including the

Gram-scale synthesis of splat-shaped Ag–TiO₂ nanocomposites for enhanced antimicrobial properties

• Mohammad Jaber,
• Asim Mushtaq,
• Kebiao Zhang,
• Jindan Wu,
• Dandan Luo,
• Zihan Yi,
• M. Zubair Iqbal and
• Xiangdong Kong

Beilstein J. Nanotechnol. 2020, 11, 1119–1125, doi:10.3762/bjnano.11.96

• antibacterial properties of TiO2 in the presence of silver were examined. The formation of Ag–TiO2 NCs was analyzed through various characterization techniques. The cell viability experimental results demonstrated that the Ag–TiO2 NCs have good biocompatibility. The antibacterial activity of the prepared Ag

• . The improvement in the antibacterial activity was attributed to the synergistic effect of the hybrid nature of TiO2 nanoparticles in the presence of Ag. Keywords: antimicrobial properties; biomaterials; nanocomposites; silver nanoparticles; titanium dioxide; Introduction The rapid industrial

• , silver (Ag), zinc oxide (ZnO), copper oxide (CuO), iron oxide (Fe3O4) and titanium oxide (TiO2) are well recognized options due to their outstanding antibacterial properties. These nanoparticles have antibacterial activity due to the production of reactive oxygen species (ROS) [9][10][11]; more

Applications of superparamagnetic iron oxide nanoparticles in drug and therapeutic delivery, and biotechnological advancements

• Maria Suciu,
• Corina M. Ionescu,
• Alexandra Ciorita,
• Septimiu C. Tripon,
• Dragos Nica,
• Hani Al-Salami and
• Lucian Barbu-Tudoran

Beilstein J. Nanotechnol. 2020, 11, 1092–1109, doi:10.3762/bjnano.11.94

• microscopy (EM), iron oxide magnetic beads for the separation of cells and molecules, gold and silver nanoparticles as fiducials for EM, for immuno-EM labeling and surface-enhanced Raman spectroscopy, or for gene transfection, liposomes for drug delivery, and gadolinium or iron oxide nanoparticles for

Gas-sensing features of nanostructured tellurium thin films

• Dumitru Tsiulyanu

Beilstein J. Nanotechnol. 2020, 11, 1010–1018, doi:10.3762/bjnano.11.85

• the high-vacuum deposition technique in order to grow Te nanotubes on silicon substrates containing previously deposited nanoparticles of silver or gold [22]. In both cases, 50 nm diameter Te nanotubes were obtained. When exposed to low concentrations of different toxic gases, including NO2, the Te

• , identified in our preliminary works as ohmics [25][26], which form electrically transparent contacts with Te. The gold or copper wires were then attached to the electrodes with a silver paste. Figure 1A shows the surface morphology of a Te film grown on a Pyrex glass substrate at a rate of 10 nm/s. As shown

Wet-spinning of magneto-responsive helical chitosan microfibers

• Dorothea Brüggemann,
• Johanna Michel,
• Naiana Suter,
• Matheus Grande de Aguiar and
• Michael Maas

Beilstein J. Nanotechnol. 2020, 11, 991–999, doi:10.3762/bjnano.11.83

• ]. Additionally, by using either wet-spinning or electrospinning techniques, nanoparticles can be suspended into the viscous spinning solution and embedded into the fiber matrix. For example, silver nanoparticles have been incorporated into electrospun chitosan fibers enabling antibacterial activity in wound

Electrochemical nanostructuring of (111) oriented GaAs crystals: from porous structures to nanowires

• Elena I. Monaico,
• Eduard V. Monaico,
• Veaceslav V. Ursaki,
• Shashank Honnali,
• Vitalie Postolache,
• Karin Leistner,
• Kornelius Nielsch and
• Ion M. Tiginyanu

Beilstein J. Nanotechnol. 2020, 11, 966–975, doi:10.3762/bjnano.11.81

• sonicated in acetone for 15 min, cleaned in distilled water and dried. In order to remove the native oxide from the surface, the samples were dipped in a HCl/H2O (1:3) solution for 2 min. The electrical contacts to the sample were prepared with silver paste, then the samples were pressed against an O-ring

Simulations of the 2D self-assembly of tripod-shaped building blocks

• Łukasz Baran,
• Wojciech Rżysko and
• Edyta Słyk

Beilstein J. Nanotechnol. 2020, 11, 884–890, doi:10.3762/bjnano.11.73

• structures, which are not reproducible with off-lattice simulations. Acknowledgements Calculations were carried out at the Academic Computer Centre in Gdansk. a–d) Schematic representation of the models used in this work. Silver and red circles correspond to the components of the backbone and “phantom