Beilstein J. Nanotechnol.2012,3, 65–74, doi:10.3762/bjnano.3.8
transmittance T and reflectance R at a wavelength of 532 nm and normal incidence was determined. The respective data are summarized in Table 1. Taking into account the transmittance and reflectance data allows one to calculate the absorbance A and the effective absorption coefficient αAu of the films from [12
distinct immersion times on a single sample (Figure 8). After etching, the samples were rinsed in deionized water and blown dry with argon.
For the characterization of bare and HDT-coated substrates, UV–vis spectroscopy, laser reflectance and transmittance measurements, contact angle measurements and
infrared reflection–absorption spectroscopy (IRRAS) were used. UV–vis spectra were measured with a Perkin Elmer UV–vis spectrometer (Lambda 950). Laser reflectance and transmittance measurements were carried out at λ = 532 nm by using the DPSS laser of the patterning setup and a power meter with a thermal
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Figure 1:
Schematic diagram of the process flow: (a) SAM formation upon immersion in an ethanolic solution of...
Beilstein J. Nanotechnol.2011,2, 448–458, doi:10.3762/bjnano.2.49
evaporated on top of hemispherical structures of epoxy resin with different radii, and the reflectance and transmittance were measured for optical wavelengths. Experimental results show that the reflectivity of coated hemispheres is lower than that of coated polystyrene spheres of the same size, for certain
wavelength bands. The spectral position of these bands correlates with the size of the hemispheres. In contrast, etched structures on quartz coated with gold films exhibit low reflectance and transmittance values for all wavelengths measured. Low transmittance and reflectance indicate high absorbance, which
Figure 2, AFM images of coated beads and coated hemispheres are shown. For further details on the fabrication, see the Experimental section.
Reflectance and transmittance measurements on coated spheres and hemispheres of the same size permit a comparison of the resonances and their spectral positions
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Figure 1:
Fabrication of arrays of metal film coated hemispheres. Main steps: (a) Preparation of 2D colloidal...