Electron interaction with copper(II) carboxylate compounds

• Michal Lacko,
• Peter Papp,
• Iwona B. Szymańska,
• Edward Szłyk and
• Štefan Matejčík

Beilstein J. Nanotechnol. 2018, 9, 384–398, doi:10.3762/bjnano.9.38

• other copper(I) β-diketonate complexes, namely, [Cu(hfac)VTMS], [Cu(hfac)DMB], and [Cu(hfac)MHY] the atomic ratios of Cu/C/O/Si were 20–45:35–70:8–14:2–10, 25–60:15–60:5–25:-, and 13:82:3:-, respectively. As-deposited freestanding rods from FEBID experiments with [Cu(hfac)VTMS] showed small Cu

UHV deposition and characterization of a mononuclear iron(III) β-diketonate complex on Au(111)

• Irene Cimatti,
• Silviya Ninova,
• Valeria Lanzilotto,
• Luigi Malavolti,
• Luca Rigamonti,
• Brunetto Cortigiani,
• Matteo Mannini,
• Elena Magnano,
• Federica Bondino,
• Federico Totti,
• Andrea Cornia and
• Roberta Sessoli

Beilstein J. Nanotechnol. 2014, 5, 2139–2148, doi:10.3762/bjnano.5.223

• ) in octahedral environment were observed. Keywords: Au(111); β-diketonate complexes; DFT; STM; thin films; UPS; XMCD; XPS; Introduction A renewed interest in mononuclear metal complexes has recently arisen due to the observation that systems of this class can behave as single molecule magnets (SMMs

• ). Despite the high deposition rate, longer doses (t6 = 10 min and t7 = 20 min) do not produce thicker films, which confirms that saturation of the coverage has been achieved. This behaviour is fully consistent with that reported for other metal β-diketonate complexes. Saturation coverage has been observed