Beilstein J. Nanotechnol.2014,5, 2202–2215, doi:10.3762/bjnano.5.229
challenges for widespread application of CNFETs are additionally discussed.
Keywords: charge carrier transport; CNFET; electrical contact; metal–SWCNT interface; SWCNT; Review
Introduction
The unique crystalline and electronic structure of single-walled carbon nanotubes (SWCNTs) afford extraordinary
[9]. Recently, the concept of a CNFET-based single processor was successfully implemented by Shulaker et al. [10]. These achievements reflect the great progress in fabrication technology that is advancing carbon nanotube technology closer to reality.
For SWCNT-based devices, the nanotubes must be
can be estimated as
where and represent the work function of metal and SWCNT, respectively, and Eg is the band gap of the SWCNT, which is inversely proportional to its diameter (approximated as 0.71 ≈ 1.1/d [19][20][21]).
For a CNFET with a Schottky barrier (SB) at the contacts, the electrical
Beilstein J. Nanotechnol.2014,5, 2179–2191, doi:10.3762/bjnano.5.227
the gate voltage is to change the width of the Schottky barrier, which controls the current through the device. Carbon nanotube transistors often operate as Schottky-barrier field-effect transistors because the back-gated architecture that is typically employed for CNFET gas sensors covers the entire
architecture, with suspended or on-substrate tubes, and passivated or unpassivated contacts have been reported (Figure 1).
The conductivity of a CNFET can be influenced by surface adsorbates. In particular, the adsorption of electron-withdrawing gases, such as NO2, or electron-donating gases such as NH3 can
mechanisms behind the device response. They reported that the CNFET responded to gas exposure by showing a large shift of the transfer (Id–Vg) characteristics, with the direction of the shift dependent on the gas type.
The remarkable feature of the observations by Kong et al. [7] is that the nanotubes were
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Figure 1:
Examples of different back-gated device architectures employed for carbon nanotube field-effect tra...