Beilstein J. Nanotechnol.2014,5, 1738–1748, doi:10.3762/bjnano.5.184
Danny E. P. Vanpoucke Jan W. Jaeken Stijn De Baerdemacker Kurt Lejaeghere Veronique Van Speybroeck Center for Molecular Modeling, Ghent University, Technologiepark 903, Zwijnaarde 9052, Belgium 10.3762/bjnano.5.184 Abstract The geometric and electronic structure of the MIL-47(V) metal-organic
antiferromagnetic transition pressures. Mapping DFT energies onto a simple-spin Hamiltonian shows both the intra- and inter-chain coupling to be antiferromagnetic, with the latter coupling constant being two orders of magnitude smaller than the former, suggesting the MIL-47(V) to present quasi-1D behavior. The
dispersion along the the direction of the VO6 chains, similar as for other quasi-1D materials.
Keywords: band structure; density functional theory (DFT); low-dimensional electronics; metal-organic frameworks (MOFs); MIL-47; Introduction
Metal-organic frameworks (MOFs) present a class of materials located
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Figure 1:
(a) Ball-and-stick representation of the MIL-47(V) MOF. Pink, red, black, and white spheres indicat...