SERS and DFT study of copper surfaces coated with corrosion inhibitor

• Maurizio Muniz-Miranda,
• Francesco Muniz-Miranda and
• Stefano Caporali

Beilstein J. Nanotechnol. 2014, 5, 2489–2497, doi:10.3762/bjnano.5.258

• environmentally friendly agent. In this study, we have analyzed the adsorption of 1,2,4-triazole on copper by taking advantage of the surface-enhanced Raman scattering (SERS) effect, which highlights the vibrational features of organic ligand monolayers adhering to rough surfaces of some metals such as gold

• more widely but is not environmentally friendly. The adsorption of various organic ligands onto smooth surfaces of copper was previously studied by means of surface-enhanced Raman scattering (SERS) spectroscopy [8]. Due to the huge amplification of the Raman signal of the adsorbed molecules, this

Interaction of dermatologically relevant nanoparticles with skin cells and skin

• Annika Vogt,
• Fiorenza Rancan,
• Sebastian Ahlberg,
• Berouz Nazemi,
• Chun Sik Choe,
• Maxim E. Darvin,
• Sabrina Hadam,
• Ulrike Blume-Peytavi,
• Kateryna Loza,
• Jörg Diendorf,
• Matthias Epple,
• Christina Graf,
• Eckart Rühl,
• Martina C. Meinke and
• Jürgen Lademann

Beilstein J. Nanotechnol. 2014, 5, 2363–2373, doi:10.3762/bjnano.5.245

• by the highly sensitive tracking of the surface enhanced Raman scattering (SERS) signal of single AgNP. Here, the penetration depth was found to be 19 ± 10 µm for intact skin, compared to 22 ± 5 µm for skin pre-treated with 20 tape stripes. This effect is well known for AgNP of this type and size [20

• the skin surface down to a depth of 50 µm, in 2 µm steps. The measurement time for one spectrum was 5 s. The surface enhanced Raman scattering (SERS) signal as a result of interaction between AgNPs and the porcine skin was generated by using the same excitation conditions. The utilized Raman

Localized surface plasmon resonances in nanostructures to enhance nonlinear vibrational spectroscopies: towards an astonishing molecular sensitivity

• Dan Lis and
• Francesca Cecchet

Beilstein J. Nanotechnol. 2014, 5, 2275–2292, doi:10.3762/bjnano.5.237

• anti-Stokes Raman scattering (SE-CARS). They can be considered as the nonlinear counterpart and/or combination of the linear surface-enhanced infrared absorption (SEIRA) and surface-enhanced Raman scattering (SERS) techniques, respectively, which are themselves a branching of the conventional IR and

• spontaneous Raman spectroscopies. Compared to their linear equivalent, those nonlinear vibrational spectroscopies have proved to reach higher sensitivity down to the single molecule level, opening the way to astonishing perspectives for molecular analysis. Keywords: coherent anti-Stokes Raman scattering

• chemical selectivity, and to identify specific molecules with no added labels. The two major techniques that have dominated for a long time in this field are infrared (IR) spectroscopy and spontaneous (incoherent) Raman scattering. In IR spectroscopy, IR radiation is absorbed by matter at specific

Properties of plasmonic arrays produced by pulsed-laser nanostructuring of thin Au films

• Katarzyna Grochowska,
• Katarzyna Siuzdak,
• Peter A. Atanasov,
• Carla Bittencourt,
• Anna Dikovska,
• Nikolay N. Nedyalkov and
• Gerard Śliwiński

Beilstein J. Nanotechnol. 2014, 5, 2102–2112, doi:10.3762/bjnano.5.219

• (1.6–3.7) × 105 indicating that the latter are slightly lower. Given the fluorescence cross section σF of R6G equal to 10−16 cm2 at 514 nm, and that of Raman scattering σSC ≈ 10−30 cm2 and taking into account that Raman scattering of R6G is enhanced by about 104 due to resonance at 514 nm, the factor

PVP-coated, negatively charged silver nanoparticles: A multi-center study of their physicochemical characteristics, cell culture and in vivo experiments

• Sebastian Ahlberg,
• Alexandra Antonopulos,
• Jörg Diendorf,
• Ralf Dringen,
• Matthias Epple,
• Rebekka Flöck,
• Wolfgang Goedecke,
• Christina Graf,
• Nadine Haberl,
• Jens Helmlinger,
• Fabian Herzog,
• Frederike Heuer,
• Stephanie Hirn,
• Christian Johannes,
• Stefanie Kittler,
• Manfred Köller,
• Katrin Korn,
• Wolfgang G. Kreyling,
• Fritz Krombach,
• Jürgen Lademann,
• Kateryna Loza,
• Eva M. Luther,
• Marcelina Malissek,
• Martina C. Meinke,
• Daniel Nordmeyer,
• Anne Pailliart,
• Jörg Raabe,
• Fiorenza Rancan,
• Barbara Rothen-Rutishauser,
• Eckart Rühl,
• Carsten Schleh,
• Andreas Seibel,
• Christina Sengstock,
• Lennart Treuel,
• Annika Vogt,
• Katrin Weber and
• Reinhard Zellner

Beilstein J. Nanotechnol. 2014, 5, 1944–1965, doi:10.3762/bjnano.5.205

Synthesis of Pt nanoparticles and their burrowing into Si due to synergistic effects of ion beam energy losses

• Pravin Kumar,
• Udai Bhan Singh,
• Kedar Mal,
• Sunil Ojha,
• Indra Sulania,
• Dinakar Kanjilal,
• Dinesh Singh and
• Vidya Nand Singh

Beilstein J. Nanotechnol. 2014, 5, 1864–1872, doi:10.3762/bjnano.5.197

• performance, Pt NPs are used in fabricating super capacitors [35]. The Pt NPs in core–shell structures (Pt forms the shell) are used in surface enhanced Raman scattering (SERS) studies [36] as well. Moreover, Pt is relatively inert in atmosphere and ex situ characterization of irradiated samples can also be

Fringe structures and tunable bandgap width of 2D boron nitride nanosheets

• Peter Feng,
• Muhammad Sajjad,
• Eric Yiming Li,
• Hongxin Zhang,
• Jin Chu,
• Ali Aldalbahi and
• Gerardo Morell

Beilstein J. Nanotechnol. 2014, 5, 1186–1192, doi:10.3762/bjnano.5.130

• efficiently control bandgap width. The characterizations are based on Raman scattering spectroscopy, X-ray diffraction (XRD), and FTIR transmittance spectra. Red shifts of spectral lines are clearly visible after the functionalization, indicating the bandgap width of the BNNSs has been changed. However

• Raman scattering spectroscopy, XRD, and FTIR. From these spectral line profiles and shifts we could investigate variations of the bandgap width and crystalline structures. Figure 7a shows the Raman spectra of the BNNSs using triple monochromator with an excitation wavelength of 514 nm (Ar+ ion Laser

• . These experimental data probably indicate that the BNNSs have extremely flexible mechanic properties. We conclude that functionalization can be used to realize tunable bandgap width. Red shifts of Raman scattering spectroscopy, XRD, and FTIR transmittance spectral lines confirm that after the treatment

Hole-mask colloidal nanolithography combined with tilted-angle-rotation evaporation: A versatile method for fabrication of low-cost and large-area complex plasmonic nanostructures and metamaterials

• Jun Zhao,
• Bettina Frank,
• Frank Neubrech,
• Chunjie Zhang,
• Paul V. Braun and
• Harald Giessen

Beilstein J. Nanotechnol. 2014, 5, 577–586, doi:10.3762/bjnano.5.68

• surface-enhanced Raman scattering (SERS), in particular when the particle plasmon resonance was tuned to the pump laser wavelength. Novel applications such as coupling of plasmons to atomic gases are on the horizon [14]. Most of these fundamental effects as well as the early applications have been

Optical near-fields & nearfield optics

• Alfred J. Meixner and
• Paul Leiderer

Beilstein J. Nanotechnol. 2014, 5, 186–187, doi:10.3762/bjnano.5.19

• ” with a length of a few nanometers. This effect of strong near-field enhancement around sharp structures of noble metals has been known from Surface Enhanced Raman Scattering (SERS) for a long time [1]. Yet, the well-controlled tailoring of nanostructures necessary to quantitatively control the optical

• near-field has only emerged a few years ago. In this issue, Katrin and Harald Kneipp [2] address in their contribution the possibility to probe the plasmonic near-fields by one- and two-photon excited surface enhanced Raman scattering at the level of single molecules. In addition to SERS, there are

Dye-doped spheres with plasmonic semi-shells: Lasing modes and scattering at realistic gain levels

• Nikita Arnold,
• Boyang Ding,
• Calin Hrelescu and
• Thomas A. Klar

Beilstein J. Nanotechnol. 2013, 4, 974–987, doi:10.3762/bjnano.4.110

• used for important applications such as biosensing [18], plasmon-enhanced solar cells [19][20], or as substrates for surface-enhanced Raman scattering [21][22] and coherent anti-Stokes Raman scattering [23]. A severe problem for all plasmonic applications is the damping of plasmons due to Ohmic losses

Template based precursor route for the synthesis of CuInSe₂ nanorod arrays for potential solar cell applications

• Mikhail Pashchanka,
• Jonas Bang,
• Niklas S. A. Gora,
• Ildiko Balog,
• Rudolf C. Hoffmann and
• Jörg J. Schneider

Beilstein J. Nanotechnol. 2013, 4, 868–874, doi:10.3762/bjnano.4.98

• their deposition onto a copper grid, hence, the nanorod bundles can be partially disassemble and individual nanorods unhinge from the structures. The phase and purity of the CuInSe2 material were further confirmed by Raman scattering (a typical micro Raman spectrum is presented in Figure 5). Copper

Probing the plasmonic near-field by one- and two-photon excited surface enhanced Raman scattering

• Katrin Kneipp and
• Harald Kneipp

Beilstein J. Nanotechnol. 2013, 4, 834–842, doi:10.3762/bjnano.4.94

• particularly also for optical spectroscopy. Surface enhanced Raman signatures of single molecules can provide us with important information about the optical near-field. We discuss one- and two-photon excited surface enhanced Raman scattering at the level of single molecules as a tool for probing the plasmonic

• . Keywords: near-field; plasmonics; silver nanoaggregates; single molecule; surface-enhanced Raman scattering (SERS); Introduction The resonance frequencies of collective oscillations of the electrons in the conduction band in metal nanostructures, which are called surface plasmons, fall in the optical

• such plasmonic structures [1][2]. Exploiting these optical near-fields opens up exciting new capabilities for photon-driven processes and particularly for optical spectroscopy. Surface-enhanced Raman scattering (SERS) might be one of the most prominent effects to demonstrate the potential of

Mapping of plasmonic resonances in nanotriangles

• Simon Dickreuter,
• Julia Gleixner,
• Andreas Kolloch,
• Johannes Boneberg,
• Elke Scheer and
• Paul Leiderer

Beilstein J. Nanotechnol. 2013, 4, 588–602, doi:10.3762/bjnano.4.66

• , in particular metallic nanoparticles, which display pronounced plasmon resonances. These highly localized near fields of plasmonic particles have been demonstrated to be a very efficient tool for nanomachining [1], optical pumping of nanoscale objects such as quantum dots [2], surface enhanced Raman

• scattering [3][4] and extreme light confinement for nonlinear effects [5][6][7]. While the basic principles of computing plasmonic resonances are well understood (i.e., by using Maxwell´s equations on small objects), it has proven to be difficult to predict the field distribution for a given nanoscopic

Photoelectrochemical and Raman characterization of In₂O₃ mesoporous films sensitized by CdS nanoparticles

• Mikalai V. Malashchonak,
• Sergey K. Poznyak,
• Eugene A. Streltsov,
• Anatoly I. Kulak,
• Olga V. Korolik and
• Alexander V. Mazanik

Beilstein J. Nanotechnol. 2013, 4, 255–261, doi:10.3762/bjnano.4.27

• temperature by using a Nanofinder High End (Lotis TII, Belarus–Japan) confocal-microscope-based setup. Raman scattering was excited by using a 473 nm solid-state laser. The laser power level at the sample was maintained at ca. 25 μW to minimize laser-induced damage to the CdS nanoparticles. The backscattered

Characterization and properties of micro- and nanowires of controlled size, composition, and geometry fabricated by electrodeposition and ion-track technology

• Maria Eugenia Toimil-Molares

Beilstein J. Nanotechnol. 2012, 3, 860–883, doi:10.3762/bjnano.3.97

Assessing the plasmonics of gold nano-triangles with higher order laser modes

• Laura E. Hennemann,
• Andreas Kolloch,
• Andreas Kern,
• Josip Mihaljevic,
• Johannes Boneberg,
• Paul Leiderer,
• Alfred J. Meixner and
• Dai Zhang

Beilstein J. Nanotechnol. 2012, 3, 674–683, doi:10.3762/bjnano.3.77

• thirdly with the employed substrate. Moreover, we obtained strongly enhanced Raman spectra of an adenine (sub-)monolayer on gold Fischer patterns on glass. We thus showed that gold Fischer patterns are promising surface-enhanced Raman scattering (SERS) substrates. Keywords: Fischer pattern; higher order

• laser modes; localised surface plasmons; near field; surface-enhanced Raman scattering; Introduction The interaction of light and matter is especially intriguing in those cases where the size of the matter particle is comparable to or smaller than the wavelength of the light. When illuminating metallic

• arrays are long known to yield particle-enhanced Raman spectra [13][14][15]. Hence, there have also been several works [16][17][18] using the near field of Fischer patterns for surface-enhanced Raman scattering (SERS [19][20]). However, to our knowledge, no investigations of Fischer patterns by higher

The morphology of silver nanoparticles prepared by enzyme-induced reduction

• Henrik Schneidewind,
• Thomas Schüler,
• Katharina K. Strelau,
• Karina Weber,
• Dana Cialla,
• Marco Diegel,
• Roland Mattheis,
• Andreas Berger,
• Robert Möller and
• Jürgen Popp

Beilstein J. Nanotechnol. 2012, 3, 404–414, doi:10.3762/bjnano.3.47

• -enhanced Raman scattering (SERS) substrates. Recently Strelau et al. reported the correlation between electrical conductivity and SERS activity [7]. For a fast, specific, and sensitive detection of molecules at low concentration, EGNP were applied for qualitative as well as quantitative SERS measurements

Nano-FTIR chemical mapping of minerals in biological materials

• Sergiu Amarie,
• Paul Zaslansky,
• Yusuke Kajihara,
• Erika Griesshaber,
• Wolfgang W. Schmahl and
• Fritz Keilmann

Beilstein J. Nanotechnol. 2012, 3, 312–323, doi:10.3762/bjnano.3.35

• the acquisition time by 160,000× for a constant S/N ratio. Note that this positive perspective is in sharp contrast to tip-enhanced Raman scattering (TERS) for which up to 10 mW is readily available, but intrinsically weak cross sections leave little room for future signal improvement [57]. A

Approaches to nanostructure control and functionalizations of polymer@silica hybrid nanograss generated by biomimetic silica mineralization on a self-assembled polyamine layer

• Jian-Jun Yuan and
• Ren-Hua Jin

Beilstein J. Nanotechnol. 2011, 2, 760–773, doi:10.3762/bjnano.2.84

• surface. As shown in Figure 9e and f, the fibrous surface nanostructure is still clearly observable, although some local fusion appears. The titania deposition was further confirmed by Raman scattering. As shown in Supporting Information File 1, Figure S4, silica@titanis nanograss shows characteristic

Transport through molecular junctions

• Jan M. van Ruitenbeek

Beilstein J. Nanotechnol. 2011, 2, 691–692, doi:10.3762/bjnano.2.74

• problem and help build confidence in our interpretations. Apart from direct conductance measurements, one now measures properties such as thermopower, shot noise, Raman scattering, photo-induced switching, and gate-induced level shifts, all at the single-molecule level. Moreover, by systematic variation

Distinction of nucleobases – a tip-enhanced Raman approach

• Regina Treffer,
• Xiumei Lin,
• Elena Bailo,
• Tanja Deckert-Gaudig and
• Volker Deckert

Beilstein J. Nanotechnol. 2011, 2, 628–637, doi:10.3762/bjnano.2.66

• of labeling or amplification steps. Here we investigate the intrinsic properties of tip-enhanced Raman scattering (TERS) towards the development of a novel, label-free, direct sequencing method. It is known that TERS allows the acquisition of spectral information with high lateral resolution and

• with reasonable costs and expenditure of time [3]. Tip-enhanced Raman scattering (TERS) is the combination of Raman spectroscopy with a scanning probe microscope, most often an atomic force microscope (AFM). A metal nanoparticle at the apex of the AFM tip leads to a large enhancement of the

• a sequencing procedure with TERS is the fact that the four nucleobases reveal remarkably different Raman scattering cross sections. It was shown that in SERS experiments on an equimolar mixture of the bases, the intensities of the ring breathing modes of the distinct bases are as follows: Poly

Towards multiple readout application of plasmonic arrays

• Dana Cialla,
• Karina Weber,
• René Böhme,
• Uwe Hübner,
• Henrik Schneidewind,
• Matthias Zeisberger,
• Roland Mattheis,
• Robert Möller and
• Jürgen Popp

Beilstein J. Nanotechnol. 2011, 2, 501–508, doi:10.3762/bjnano.2.54

• information without the need for external labels. The drawback of the intrinsically small Raman scattering cross sections not allowing for trace analytics and fast detections times can be overcome by applying surface-enhanced Raman spectroscopy (SERS). The enhancement of the inherently small Raman cross

Room temperature synthesis of indium tin oxide nanotubes with high precision wall thickness by electroless deposition

• Mario Boehme,
• Emanuel Ionescu,
• Ganhua Fu and
• Wolfgang Ensinger

Beilstein J. Nanotechnol. 2011, 2, 119–126, doi:10.3762/bjnano.2.14

• waver. (b) Normalized Raman Scattering spectrum of the ITO-NTs. (c) Normalized PL spectra of the ITO-NTs excited at 270 nm. XPS spectra of the synthesized ITO-NTs (a) In(3d) spectrum; (b) Sn(3d) spectrum; (c) In-O(1s) and Sn-O(1s) spectrum. ZnO films prepared in aqueous solution. Diagram of ITO