Beilstein J. Nanotechnol.2011,2, 459–472, doi:10.3762/bjnano.2.50
, the contact area of particle and substrate is clearly dependent on the initial size of the colloid. Finally, the distribution of the Pt precursor inside the colloidal particle may also play an important role.
To clarify this last point, TEM and EDX (energy dispersive X-rayspectroscopy) investigations
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Scheme 1:
Simplified model of a seeded emulsion polymerization process to clarify the desired reaction pathwa...
Beilstein J. Nanotechnol.2011,2, 237–251, doi:10.3762/bjnano.2.28
backscattering atoms than in the bulk material, although the average composition determined by energy-dispersive X-rayspectroscopy (EDS) is the same for the two samples. This difference is not a conflict between EXAFS and EDS results, but simply reflects the fact that an averaging technique such as EDS does not
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Figure 1:
Effective backscattering amplitude of O, Fe, and Pt as a function of wave number and phase shift. A...