Forming nanoparticles of water-soluble ionic molecules and embedding them into polymer and glass substrates

• Stella Kiel,
• Olga Grinberg,
• Nina Perkas,
• Jerome Charmet,
• Herbert Kepner and
• Aharon Gedanken

Beilstein J. Nanotechnol. 2012, 3, 267–276, doi:10.3762/bjnano.3.30

• were created by the application of ultrasonic waves to the aqueous solutions of these salts. When the sonication was carried out in the presence of a glass microscope slide, a parylene-coated glass slide, or a silicon wafer the ionic NPs were embedded in these substrates by a one-step, ultrasound

• synthesized nanoparticles or those purchased from commercial sources ("throwing stones" mode of deposition) [19]. The present work describes an additional route for the deposition of nanoparticles. It was found that the sonication of aqueous solutions of inorganic compounds (NaCl, CuSO4, KI) resulted in the

Self-assembly of octadecyltrichlorosilane: Surface structures formed using different protocols of particle lithography

• ChaMarra K. Saner,
• Kathie L. Lusker,
• Zorabel M. LeJeune,
• Wilson K. Serem and
• Jayne C. Garno

Beilstein J. Nanotechnol. 2012, 3, 114–122, doi:10.3762/bjnano.3.12

• handled carefully. After acid cleaning, the substrates were rinsed with copious amounts of deionized water and dried in air. Size-sorted, monodisperse polystyrene latex mesospheres (200 nm diameter) were used as surface masks for patterning (Thermo-Fisher Scientific, Waltman, MA). Aqueous solutions of

Self-assembled monolayers and titanium dioxide: From surface patterning to potential applications

• Yaron Paz

Beilstein J. Nanotechnol. 2011, 2, 845–861, doi:10.3762/bjnano.2.94

• groups/nm2 for H3Si(CH2)8SiH3. Unlike organosilane SAMs, whose tendency to form on TiO2 and SiO2 is quite similar, SAMs having phosphonic acid as their connecting head group are not formed on silicon dioxide but are formed easily from aqueous solutions on TiO2, Al2O3, Ta2O5 and Nb2O5 [27]. FTIR

• adsorbed on the nonexposed domains of a p-tolyltrichlorosilane SAM, was added prior to the TiO2 growth step [76]. This shielding reagent, dodecylbenzene sodium sulfonate, was chosen based on its tendency, in aqueous solutions, to attach only to hydrophobically-terminated SAMs, due to its amphiphilic nature

Synthesis and catalytic applications of combined zeolitic/mesoporous materials

• Jarian Vernimmen,
• Vera Meynen and
• Pegie Cool

Beilstein J. Nanotechnol. 2011, 2, 785–801, doi:10.3762/bjnano.2.87

• -Evonik/Headwaters developed a new technology based on the use of aqueous solutions of H2O2 and a fixed-bed TS-1 reactor. At the end of 2008, the largest plant using this new process was started up in Antwerp by BASF/Dow. Although the implementation of TS-1 has been successful, there are still some

Approaches to nanostructure control and functionalizations of polymer@silica hybrid nanograss generated by biomimetic silica mineralization on a self-assembled polyamine layer

• Jian-Jun Yuan and
• Ren-Hua Jin

Beilstein J. Nanotechnol. 2011, 2, 760–773, doi:10.3762/bjnano.2.84

• nanograss as prepared by mineralization of the nanostructured LPEI layer, which was formed from LPEI aqueous solutions with concentrations of 3.0 wt % (Figure 5a–c) and 5.0 wt % (Figure 5d–f). The silica-mineralization reaction was performed by using a source mixture of 15 mL water and 0.5 mL MS51 for 40

Lifetime analysis of individual-atom contacts and crossover to geometric-shell structures in unstrained silver nanowires

• Christian Obermair,
• Holger Kuhn and
• Thomas Schimmel

Beilstein J. Nanotechnol. 2011, 2, 740–745, doi:10.3762/bjnano.2.81

• , except for a small region with less than 25 µm in diameter around the gap, in order to keep the electrochemical leakage currents low (below 0.1%). This arrangement was exposed to electrolytes consisting of 1 mM AgNO3 (p.a., Merck) and 0.1 M HNO3 (suprapure, Merck) as aqueous solutions within an

The atomic force microscope as a mechano–electrochemical pen

• Christian Obermair,
• Andreas Wagner and
• Thomas Schimmel

Beilstein J. Nanotechnol. 2011, 2, 659–664, doi:10.3762/bjnano.2.70

• were measured both before and after each experiment. Aqueous solutions of 50 mM H2SO4 (Suprapur, Merck) with 1 mM CuSO4 (p.a., Merck) were used as electrolytes. The potentials given in this article were measured against Cu/Cu2+ electrodes. Electrochemical deposition was performed at an overpotential of

Dynamics of capillary infiltration of liquids into a highly aligned multi-walled carbon nanotube film

• Sławomir Boncel,
• Krzysztof Z. Walczak and
• Krzysztof K. K. Koziol

Beilstein J. Nanotechnol. 2011, 2, 311–317, doi:10.3762/bjnano.2.36

• infiltration of the HACNT film by three different aqueous solutions, characterised by various dielectric constant, namely distilled water (as a reference) (left), saturated saline (centre) and saturated sucrose solution (right). Water and saline solution both formed droplets that slide on the highly

• allows us to qualify the herein considered HACNTs film as a “superhydrophobic” material [27]. In contrast, an unexpected behaviour in the series of aqueous solutions was observed for sucrose, which slowly, but entirely, infiltrated the HACNT film. Theoretically, two requirements for a successful

• different aqueous solutions. Each image contains a droplet of water (left), saturated saline solution (centre) and saturated sucrose aqueous solution (right). Time of infiltration of HACNTs film as a function of the dynamic viscosity of a range of viscous liquids. Infiltration time (t) of the HACNT film

Room temperature synthesis of indium tin oxide nanotubes with high precision wall thickness by electroless deposition

• Mario Boehme,
• Emanuel Ionescu,
• Ganhua Fu and
• Wolfgang Ensinger

Beilstein J. Nanotechnol. 2011, 2, 119–126, doi:10.3762/bjnano.2.14

• below yields open end nanotubes with well defined outer diameter and wall thickness. In the past, zinc oxide films were mostly preferred and were synthesized using electroless deposition based on aqueous solutions. All these methods previously developed, are not adaptable in the case of ITO nanotubes

• growth mechanism of the ITO-NTs was proposed on the basis of the experimental results. Previously zinc oxide films have been prepared by electroless deposition in aqueous solutions under different conditions as shown in Table 1. Ito et al. obtained highly oriented crystalline films, grown directly on a

• substrate in aqueous solutions containing urea [19]. Crystalline zinc oxide films were prepared in alkaline aqueous solutions containing ethane-1,2-diamine as a chelating agent [20]. Well aligned ZnO microrods within a thin film were formed by the thermal decomposition of an amino complex based on Zn2+ and

Twofold role of calcined hydrotalcites in the degradation of methyl parathion pesticide

• Alvaro Sampieri,
• Geolar Fetter,
• María Elena Villafuerte-Castrejon,
• Adriana Tejeda-Cruz and
• Pedro Bosch

Beilstein J. Nanotechnol. 2011, 2, 99–103, doi:10.3762/bjnano.2.11

• its degradation products have to be retained and/or decomposed in aqueous solutions. Studies concerning the surface modification of cationic clays and hydrotalcites with organic ions, as pesticide sorbents, have been reviewed by Cornejo et al. [5]. For instance, MP undergoes degradation when it is

Precursor concentration and temperature controlled formation of polyvinyl alcohol-capped CdSe-quantum dots

• Chetan P. Shah,
• Madhabchandra Rath,
• Manmohan Kumar and
• Parma N. Bajaj

Beilstein J. Nanotechnol. 2010, 1, 119–127, doi:10.3762/bjnano.1.14

• measured volumes of the aqueous solutions of the precursors, Cd(OAc)2 and Na2SeSO3, of various concentrations, in the presence of the required concentration of PVA, and stirring the mixture constantly at different temperatures until completion of the reaction. The reaction was carried out in a jacketed