Beilstein J. Nanotechnol.2012,3, 524–532, doi:10.3762/bjnano.3.60
research efforts have been recently directed to improve their power-conversion efficiency (PCE), in order to make these cells commercially viable [2]. The most promising active materials for organic cells are semiconducting polymers and fullerene derivatives, whose mixtures result in the formation of an
the fullerene derivative acts as an electron acceptor [6]. The holes move in the polymeric phase towards the anode, while the electrons hop along the fullerenes and eventually reach the cathode. Since the diffusion length of the exciton in the polymers is very low, recombination is highly probable
]. Many approaches have been proposed in order to overcome such fundamental issues and to improve the performances of P3HT:PCBM solar cells. In particular, very promising advances can be gained by increasing the nanoscale ordering of the polymer/fullerene composite. Different means have been proposed
PDF
Figure 1:
SEM images of MWCNTs grown on ITO-coated glass by CVD at: (a) 550 °C, (b) 525 °C, (c) 500 °C.
Beilstein J. Nanotechnol.2011,2, 845–861, doi:10.3762/bjnano.2.94
of a modified C60 [87]. An agreement between the measured photocurrent action spectrum and the absorption spectrum of the modified fullerene served as an indication that the photoactive species was the modified fullerene. A photon-to-current conversion efficiency as high as 15% was measured
PDF
Figure 1:
Schematic representation of binding modes between phosphonic acid SAMs and titanium dioxide (1) mon...