Molecular assemblies on surfaces: towards physical and electronic decoupling of organic molecules

• Sabine Maier and
• Meike Stöhr

Beilstein J. Nanotechnol. 2021, 12, 950–956, doi:10.3762/bjnano.12.71

• monitor the STM-induced nucleation, growth, and ripening of self-assembled monolayers in a more controlled fashion. Söngen et al. [77] provide insight into the interaction of organic molecules with bulk insulators by discussing the adsorption of ethanol on both calcite and magnesite using three

• -dimensional AFM experiments. Although molecules adsorbed on bulk insulators are electronically decoupled, molecular self-assemblies can experience a substrate templating effect due to the presence of heterogeneous adsorption sites. Therefore, Söngen et al. [77] found on bulk calcite and magnesite that the

Three-dimensional solvation structure of ethanol on carbonate minerals

• Hagen Söngen,
• Ygor Morais Jaques,
• Peter Spijker,
• Christoph Marutschke,
• Stefanie Klassen,
• Ilka Hermes,
• Ralf Bechstein,
• Lidija Zivanovic,
• John Tracey,
• Adam S. Foster and
• Angelika Kühnle

Beilstein J. Nanotechnol. 2020, 11, 891–898, doi:10.3762/bjnano.11.74

• ), Kanazawa University, Kakumamachi, Kanazawa 920-1192, Japan 10.3762/bjnano.11.74 Abstract Calcite and magnesite are important mineral constituents of the earth’s crust. In aqueous environments, these carbonates typically expose their most stable cleavage plane, the (10.4) surface. It is known that these

• resolution. However, the majority of 3D AFM studies have been focused on the arrangement of water at carbonate surfaces. Here, we present an analysis of the assembly of ethanol – an organic molecule with a single hydroxy group – at the calcite and magnesite (10.4) surfaces by using high-resolution 3D AFM and

• simulations. The qualitative difference in the lateral order can be understood by the differing chemical environment: While the first layer adopts specific binding positions on the ionic carbonate surface, the second layer resides on top of the organic ethyl layer. A comparison of calcite and magnesite