Septipyridines as conformationally controlled substitutes for inaccessible bis(terpyridine)-derived oligopyridines in two-dimensional self-assembly

• Daniel Caterbow,
• Daniela Künzel,
• Michael G. Mavros,
• Axel Groß,
• Katharina Landfester and
• Ulrich Ziener

Beilstein J. Nanotechnol. 2011, 2, 405–415, doi:10.3762/bjnano.2.46

• . The structures are investigated by scanning tunneling microscopy (STM) and a combination of force-field and first-principles electronic structure calculations. Keywords: oligopyridines; self-assembled monolayer; STM; Introduction Two-dimensional molecular self-assembly is a common approach to build

Influence of water on the properties of an Au/Mpy/Pd metal/molecule/metal junction

• Jan Kučera and
• Axel Groß

Beilstein J. Nanotechnol. 2011, 2, 384–393, doi:10.3762/bjnano.2.44

• one-fold bond between the oxygen atom of the water molecule and a Pd atom. An isolated H2O molecule adsorbs preferentially in a flat-lying geometry on top of a palladium atom that is at the same time also bound to the nitrogen atom of a Mpy molecule of the underlying self-assembled monolayer. The

• containing metal cations is brought into contact with a self-assembled monolayer (SAM) consisting of organic molecules on a metal substrate, thus forming metal cation/molecule complexes. Then the cationic solution is exchanged with a cation-free electrolyte, and the cation/molecule complexes are reduced

Manipulation of gold colloidal nanoparticles with atomic force microscopy in dynamic mode: influence of particle–substrate chemistry and morphology, and of operating conditions

• Samer Darwich,
• Karine Mougin,
• Akshata Rao,
• Enrico Gnecco,
• Shrisudersan Jayaraman and
• Hamidou Haidara

Beilstein J. Nanotechnol. 2011, 2, 85–98, doi:10.3762/bjnano.2.10

• being dip-coated, the polymer was removed by oxygen plasma treatment (see Figure 6). Self-assembled monolayer coated silicon wafer The molecular surfaces were prepared by self-assembling organosilane molecules onto silicon wafers Si(111) with a native thin oxide (SiO2) layer of ~1.5 nm. The organosilane