Dielectrophoresis of gold nanoparticles conjugated to DNA origami structures

• Anja Henning-Knechtel,
• Matthew Wiens,
• Mathias Lakatos,
• Andreas Heerwig,
• Frieder Ostermaier,
• Nora Haufe and
• Michael Mertig

Beilstein J. Nanotechnol. 2016, 7, 948–956, doi:10.3762/bjnano.7.87

• Chemistry, University of Alberta, Edmonton, T6G2G2, Canada Kurt-Schwabe-Institut für Mess- und Sensortechnik Meinsberg e.V., 04736 Waldheim, Germany 10.3762/bjnano.7.87 Abstract DNA nanostructures are promising construction materials to bridge the gap between self-assembly of functional molecules and

• hybrid structures. Keywords: gold nanoparticles; dielectrophoresis; DNA nanotechnology; DNA origami; self-assembly; Introduction The DNA origami method facilitates high throughput synthesis of identical and fully addressable two- (2D) or three-dimensional (3D) nanoscaled structures [1][2][3]. Such DNA

• constructs constitute promising template structures to combine different organic and inorganic nanomaterials into tailored hybrid nanodevices, and hence, hold the potential to combine self-assembly of functional molecules with conventional fabrication methods in nanotechnology [4][5][6][7][8][9][10][11]. To

Reconstitution of the membrane protein OmpF into biomimetic block copolymer–phospholipid hybrid membranes

• Matthias Bieligmeyer,
• Franjo Artukovic,
• Stephan Nussberger,
• Thomas Hirth,
• Thomas Schiestel and
• Michaela Müller

Beilstein J. Nanotechnol. 2016, 7, 881–892, doi:10.3762/bjnano.7.80

• for the reconstitution of transmembrane proteins under preservation of protein function, independent of the membrane thickness. Keywords: biomimetics; block copolymer; lipopolymer mixture; OmpF reconstitution; self-assembly; Introduction Protein pores facilitate the transfer of molecules across

• been assessed yet [46][47]. In the present work, we studied the reconstitution of OmpF from Escherichia coli into biomimetic lipopolymer membranes, generated by self-assembly of amphiphilic poly(1,4-isoprene-block-ethylene oxide) block copolymers (PIPEO) and 1,2-diphytanoyl-sn-glycero-3-phosphocholine

• monomer-activated approach [52]. However, an incomplete initiation of the second block could be excluded as side reaction since no tailing within the size exclusion chromatography traces has been observed. Thus, effects on the self-assembly behavior of the block copolymers in aqueous solutions were not

Optical absorption signature of a self-assembled dye monolayer on graphene

• Tessnim Sghaier,
• Sylvain Le Liepvre,
• Céline Fiorini,
• Ludovic Douillard and
• Fabrice Charra

Beilstein J. Nanotechnol. 2016, 7, 862–868, doi:10.3762/bjnano.7.78

• -3,4,9,10-diimide (PTCDI); scanning tunnelling microscopy; self-assembly; self-organization; Introduction Close-packed assemblies of dye molecules exhibit drastically altered photonic properties as compared with the isolated or diluted species [1]. These changes find their origin in near-field optical

• original photonic processes. An atomically precise positioning of self-associated molecular dyes can be achieved either in vacuum or at the solution–substrate interface by self-assembly techniques. In particular, perylene-3,4,9,10-tetracarboxylic-3,4,9,10-diimide (PTCDI) and its sibling molecule perylene

• -packed PTCDA molecules deposited on epitaxial graphene have also been observed [21]. In turn, self-assembly of adsorbed conjugated molecules can influence the electronic properties of its substrate. Such a non-covalent functionalization is especially suitable in the case of graphene because of its

Direct formation of gold nanorods on surfaces using polymer-immobilised gold seeds

• Majid K. Abyaneh,
• Pietro Parisse and
• Loredana Casalis

Beilstein J. Nanotechnol. 2016, 7, 809–816, doi:10.3762/bjnano.7.72

• noble metal NRs or NWs with various techniques, such as electron-beam lithography [14][15], Langmuir–Blodgett (L–B) methods [16], stretched polymer matrices [17], self-assembly [18][19][20], and electric fields [21]. However, both direct and indirect surface-growth approaches present significant

Assembling semiconducting molecules by covalent attachment to a lamellar crystalline polymer substrate

• Rainhard Machatschek,
• Patrick Ortmann,
• Renate Reiter,
• Stefan Mecking and
• Günter Reiter

Beilstein J. Nanotechnol. 2016, 7, 784–798, doi:10.3762/bjnano.7.70

• that the overall thickness CPE45 nanocrystals does not depend solely on the thickness of the crystalline core, which is predefined by the distance between regularly spaced side-groups. Formation of monolayers of nanocrystals Self-assembly of nanocrystals at the air–water interface For electrostatically

• stabilized colloids, self-assembly at the air–water interface has been demonstrated to be an efficient route to generate close packed monolayers with virtually crystalline order up to sizes of square-centimeters [7]. While repulsive forces introduced by surfactants are often used to support the assembly

Magnetic switching of nanoscale antidot lattices

• Ulf Wiedwald,
• Joachim Gräfe,
• Kristof M. Lebecki,
• Maxim Skripnik,
• Felix Haering,
• Gisela Schütz,
• Paul Ziemann,
• Eberhard Goering and
• Ulrich Nowak

Beilstein J. Nanotechnol. 2016, 7, 733–750, doi:10.3762/bjnano.7.65

• -up techniques based on the self-assembly of nanoscale spheres [2][11][12] allow precise control over diameter and distance of the antidots. In the present work, we make use of bottom-up nanosphere lithography in combination with reactive ion etching resulting in hexagonally arranged, non-close packed

• of sphere diameters at relatively narrow size distributions. However, the control of the self-assembly process leading to optimized samples is still challenging. Figure 1 presents the entire preparation process of magnetic antidot arrays. In order to prepare such arrays on a large scale with

• self-assembly of monodisperse PS spheres on the chosen substrate; (b) the homogeneous reduction of the PS sphere diameter by setting the plasma etching time while maintaining their initial positions on the substrate. Then, the nanoscale masks are ready for the deposition of a magnetic film and a

Hierarchical coassembly of DNA–triptycene hybrid molecular building blocks and zinc protoporphyrin IX

• Rina Kumari,
• Sumit Singh,
• Mohan Monisha,
• Sourav Bhowmick,
• Anindya Roy,
• Neeladri Das and
• Prolay Das

Beilstein J. Nanotechnol. 2016, 7, 697–707, doi:10.3762/bjnano.7.62

• composite DNA nanostructures by the self-assembly of complementary symmetrical 2,6,14-triptycenetripropiolic acid (TPA)–DNA building blocks and zinc protoporphyrin IX (Zn PpIX). DNA–organic molecule scaffolds for the composite DNA nanostructure were constructed through covalent conjugation of TPA with 5

• desorption/ionization time-of-flight (MALDI-TOF). The biologically relevant photosensitizer Zn PpIX was used to direct the hybridization-mediated self-assembly of DNA–TPA molecular building blocks as well as a model guest molecule within the DNA–TPA supramolecular self-assembly. The formation of fiber-like

• therapy (PDT) applications as well as photocatalytic reactions. Keywords: DNA nanostructure; DNA–organic hybrid; DNA self-assembly; 2,6,14-triptycenetripropiolic acid; zinc protoporphyrin IX; Introduction Hybrid nanomaterials resulting from the covalent conjugation of DNA with organic molecules [1][2][3

Gold nanoparticles covalently assembled onto vesicle structures as possible biosensing platform

• M. Fátima Barroso,
• M. Alejandra Luna,
• Juan S. Flores Tabares,
• Cristina Delerue-Matos,
• N. Mariano Correa,
• Fernando Moyano and
• Patricia G. Molina

Beilstein J. Nanotechnol. 2016, 7, 655–663, doi:10.3762/bjnano.7.58

• bilayers with the aim of using this nanomaterial as platform for the future design of immunosensors. A novel methodology for the self-assembly of AuNPs onto large unilamellar vesicle structures is described. The vesicles were formed with 1,2-dioleoyl-sn-glycero-3-phosphocholine (DOPC) and 1-undecanethiol

• fulfil performance criteria such as high sensitivity and low limit of detection. In this context, vesicles can be used in the construction of biosensors as supporting film to coat Au or Ag electrodes [3]. Self-assembly of nanoparticles onto organised systems combines the advantages of nanomaterials

• acts as the solvent for the synthesis reaction as well as the reducing agent. Therefore, this work describes the self-assembly of AuNPs photochemically synthesized with two different irradiation times (8 and 13 min) in glycerol onto vesicle structures. After the optimization of some analytical features

Cantilever bending based on humidity-actuated mesoporous silica/silicon bilayers

• Christian Ganser,
• Gerhard Fritz-Popovski,
• Roland Morak,
• Parvin Sharifi,
• Benedetta Marmiroli,
• Barbara Sartori,
• Heinz Amenitsch,
• Thomas Griesser,
• Christian Teichert and
• Oskar Paris

Beilstein J. Nanotechnol. 2016, 7, 637–644, doi:10.3762/bjnano.7.56

• Institute of Inorganic Chemistry, Graz University of Technology, Austria Chair of Chemistry of Polymeric Materials, Montanuniversitaet Leoben, Austria 10.3762/bjnano.7.56 Abstract We use a soft templating approach in combination with evaporation induced self-assembly to prepare mesoporous films containing

• applicable. Experimental Sample preparation AFM cantilevers and silicon wafers were coated with a mesoporous silica film using evaporation-induced self-assembly [14][15][16]. We employed tipless NSG30 cantilevers from NT-MDT (about 130 µm long, 45 µm wide, and about 4.5 µm thick) with a gold reflective

Novel roles for well-known players: from tobacco mosaic virus pests to enzymatically active assemblies

• Claudia Koch,
• Fabian J. Eber,
• Carlos Azucena,
• Alexander Förste,
• Stefan Walheim,
• Thomas Schimmel,
• Alexander M. Bittner,
• Holger Jeske,
• Hartmut Gliemann,
• Sabine Eiben,
• Fania C. Geiger and
• Christina Wege

Beilstein J. Nanotechnol. 2016, 7, 613–629, doi:10.3762/bjnano.7.54

• consists of 158 amino acids. Numerous studies have investigated the self-assembly of TMV in vitro and provided many pieces of the puzzle, with most of them evidencing a bidirectional tube growth starting at an origin of assembly (OAs) site in the 3'-portion of the viral RNA [33][47], as illustrated in

• particle, with the RNA not depicted as it is completely enclosed in the CP helix (golden). Self-assembly process of TMV. Model for the bidirectional self-assembly of nanotubular TMV particles, based on the formation and consumption of different CP oligomers, i.e. "A-protein" and disks, in vitro. RNA is

• canonical cysteine), GPx activity could be conferred to the TMV CP building blocks. Under conditions favoring their self-assembly devoid of RNA, enzymatically active nanotubes with H2O2-reducing outer surfaces were generated. Adapted with permission from [133], copyright 2012 American Chemical Society

Comparison of the interactions of daunorubicin in a free form and attached to single-walled carbon nanotubes with model lipid membranes

• Dorota Matyszewska

Beilstein J. Nanotechnol. 2016, 7, 524–532, doi:10.3762/bjnano.7.46

• controlled way [21][22]. Due to the presence of a thiol group in the polar headgroup region, this lipid has negative charge and it is possible to transfer monolayers onto solid support by means of both Langmuir–Blodgett method and self-assembly, which results in the differences in the packing of the

Bacteriorhodopsin–ZnO hybrid as a potential sensing element for low-temperature detection of ethanol vapour

• Saurav Kumar,
• Sudeshna Bagchi,
• Senthil Prasad,
• Anupma Sharma,
• Ritesh Kumar,
• Rishemjit Kaur,
• Jagvir Singh and
• Amol P. Bhondekar

Beilstein J. Nanotechnol. 2016, 7, 501–510, doi:10.3762/bjnano.7.44

• sensor design [1][2][3][4]. Novel approaches towards sensor design that employ biological material as the active element or associated active element have been widely explored [5][6]. Over the last few decades, the research in this domain has been directed towards the bio-inspired, self-assembly of

Length-extension resonator as a force sensor for high-resolution frequency-modulation atomic force microscopy in air

• Hannes Beyer,
• Tino Wagner and
• Andreas Stemmer

Beilstein J. Nanotechnol. 2016, 7, 432–438, doi:10.3762/bjnano.7.38

• favourable configurations may exist for the adsorption of nitrogen molecules. Further theoretical as well as experimental studies are needed to gain deeper insight into the self-assembly of such molecules on surfaces through water layers. Atomic resolution on graphite To further demonstrate the high

Rigid multipodal platforms for metal surfaces

• Michal Valášek,
• Marcin Lindner and
• Marcel Mayor

Beilstein J. Nanotechnol. 2016, 7, 374–405, doi:10.3762/bjnano.7.34

• electrical properties [20]. Moreover, transistor-type devices from the same molecule have displayed fundamentally different transport characteristics [21][22]. The organization of the molecules within the junction is usually based on some sort of self-assembly using chemisorption or physisorption methods to

• , two, or three gold atoms, respectively [68]. Furthermore, the high reactivity of the thiol group not only guarantees a robust functionalization of gold electrodes. It can also lead to complication during the self-assembly process. The intermolecular linking of bifunctional dithiols due to disulfide

• through three anchoring groups. An extended study by Katano et al. investigated by UHV-STM analysis at 4.7 K also confirmed the three-point contacts of 17 on Au(111) surfaces and showed that these tripodal molecules form a highly ordered “two-tiered” hierarchical chiral self-assembly on a gold surface [86

Hemolysin coregulated protein 1 as a molecular gluing unit for the assembly of nanoparticle hybrid structures

• Tuan Anh Pham,
• Andreas Schreiber,
• Elena V. Sturm (née Rosseeva),
• Stefan Schiller and
• Helmut Cölfen

Beilstein J. Nanotechnol. 2016, 7, 351–363, doi:10.3762/bjnano.7.32

• ; nanoparticles; self-assembly; SERS; Introduction Self-assembly plays a pivotal role in bottom-up strategies for the synthesis of advanced nanostructures [1]. The resulting assemblies can be one-, two- or three-dimensional. One-dimensional nanostructures show particularly great promise due to their large

• of the magnetic spin in the Fe3O4 NPs. In all other cases, Hcp1_cys3 acts as a glue and leads to self-assembly of the NPs into linear structures of limited length. This occurs until branches are formed by the statistical adsorption of two protein rings on one NP, forming a branch. Therefore, only

• Au NPs containing 2 equiv Hcp1_cys3 with 0 and 6 mM NaCl concentration. B) Details of the UV–vis spectra in A). C) UV–vis spectra of Au NP mixture containing 12 mM NaCl with and without 2 equiv Hcp1_cys3. A) Overview of time-resolved UV–vis spectra during the self-assembly reaction of the Hcp1_cys3

Case studies on the formation of chalcogenide self-assembled monolayers on surfaces and dissociative processes

• Yongfeng Tong,
• Tingming Jiang,
• Azzedine Bendounan,
• Makri Nimbegondi Kotresh Harish,
• Angelo Giglia,
• Stefan Kubsky,
• Fausto Sirotti,
• Luca Pasquali,
• Srinivasan Sampath and
• Vladimir A. Esaulov

Beilstein J. Nanotechnol. 2016, 7, 263–277, doi:10.3762/bjnano.7.24

• . We discuss some recent studies based on X-ray photoelectron spectroscopy that shed light on these aspects for a series of such organic molecules. Keywords: copper; nickel; palladium; reactivity; selenol; selenophene; self-assembly; thiol; thiophene; Introduction In recent years research related to

• conductance pathway than sulfur. Besides the case of self-assembly on bulk metal surfaces, the knowledge of the physics and chemistry of chalcogenide SAMs on metal nanoparticle surfaces is also very important as they are widely used in different areas. In this paper, we focus on recent work where the

• species. It should be noted that in many cases the conclusions of the above mentioned investigations of dissociation processes in thiol self-assembly rely on the knowledge of the characteristic S 2p core level binding energies (CLBEs) for atomic S adsorption and the thiolate sulfur. These are usually

3D solid supported inter-polyelectrolyte complexes obtained by the alternate deposition of poly(diallyldimethylammonium chloride) and poly(sodium 4-styrenesulfonate)

• Eduardo Guzmán,
• Armando Maestro,
• Sara Llamas,
• Jesús Álvarez-Rodríguez,
• Francisco Ortega,
• Ángel Maroto-Valiente and
• Ramón G. Rubio

Beilstein J. Nanotechnol. 2016, 7, 197–208, doi:10.3762/bjnano.7.18

• -micrometric scale, has become necessary [1][2][3]. Among these techniques, the layer-by-layer (LbL) self-assembly has become probably one of the most promising [4][5], due to its high versatility and low costs [6][7]. Furthermore, a very broad range of compounds can be assembled through LbL: synthetic

• The electrostatic self-assembly, using the LbL approach, of polyelectrolyte layers formed by PSS as polyanion and PDADMAC as polycation has been studied through different techniques that allowed for a better understanding of the multilayer internal composition and interactions. Different

Linear and nonlinear optical properties of hybrid metallic–dielectric plasmonic nanoantennas

• Mario Hentschel,
• Bernd Metzger,
• Bastian Knabe,
• Karsten Buse and
• Harald Giessen

Beilstein J. Nanotechnol. 2016, 7, 111–120, doi:10.3762/bjnano.7.13

• achieve this goal. In all these cases, these techniques such as high-resolution electron beam lithography [78][79], self-assembled molecular monolayers [77], spacer layer engineering via atomic layer deposition [45], self-assembly of metallic nanoparticles with DNA and other molecular binding units [46

Fabrication and characterization of novel multilayered structures by stereocomplexion of poly(D-lactic acid)/poly(L-lactic acid) and self-assembly of polyelectrolytes

• Elena Dellacasa,
• Li Zhao,
• Gesheng Yang,
• Laura Pastorino and
• Gleb B. Sukhorukov

Beilstein J. Nanotechnol. 2016, 7, 81–90, doi:10.3762/bjnano.7.10

• medical materials made from PLA, such as surgical suture, implants, as well as drug carriers, are in high demand. Recently PLA-based polymers have been used for the fabrication of drug carriers by a LBL self-assembly technique [15][17][34]. As an example, the stepwise assembly of poly(L-lactic acid) (PLLA

Controlled graphene oxide assembly on silver nanocube monolayers for SERS detection: dependence on nanocube packing procedure

• Martina Banchelli,
• Bruno Tiribilli,
• Roberto Pini,
• Luigi Dei,
• Paolo Matteini and
• Gabriella Caminati

Beilstein J. Nanotechnol. 2016, 7, 9–21, doi:10.3762/bjnano.7.2

• with two different approaches: Langmuir–Blodgett (LB) transfer onto the solid support of a floating monolayer of AgNCs (procedure A) and sequential self-assembly of AgNCs by physisorption onto the surface (procedure B). The standard LB technique implies the preparation of a stable floating monolayer at

• interfaces [27]. Although the encouraging successful results in SERS amplification of LB samples, reports on the fabrication procedure are often contradictory and fine experimental control of the resulting structure is not always satisfactory. Self-assembly of metal nanoparticles through surface adsorption

• GO. Although fabrication of GO-covered nanoparticles has been explored using several methods such as voltammetric co-reduction [33], formation of composite graphene oxide/PAMAM–silver nanoparticles through self-assembly followed by microwave irradiation [34] and GO drop-casting onto amino

pH-Triggered release from surface-modified poly(lactic-co-glycolic acid) nanoparticles

• Manuel Häuser,
• Klaus Langer and
• Monika Schönhoff

Beilstein J. Nanotechnol. 2015, 6, 2504–2512, doi:10.3762/bjnano.6.260

• nanoparticles are coated by polyelectrolytes using the layer-by-layer self-assembly technique, employing poly(acrylic acid) (PAA) as a pH-sensitive component and poly(diallyldimethylammonium chloride) (PDADMAC) as the releasable polycation. The pH during multilayer deposition plays a major role and influences

• the nanoparticles with high concentrations of sodium chloride shows no further release and thus demonstrates the pH-driven release to be quantitative. Keywords: layer-by-layer self-assembly; pH-triggered release; PLGA nanoparticles; polyelectrolyte multilayers; weak polyelectrolyte; Introduction The

• established these days, such as covalent ligand binding via crosslinking agents [12][13] and different adsorption strategies [14]. The layer-by-layer (LbL) self-assembly technique, introduced by Decher and Hong in the early 1990s [15] has proven to be an outstandingly valuable method for the fabrication of

Chemiresistive/SERS dual sensor based on densely packed gold nanoparticles

• Sanda Boca,
• Cosmin Leordean,
• Simion Astilean and
• Cosmin Farcau

Beilstein J. Nanotechnol. 2015, 6, 2498–2503, doi:10.3762/bjnano.6.259

• demonstrated by the detection of a biologically relevant model analyte, 4-mercaptophenyl boronic acid. Keywords: colloidal nanoparticles; convective self-assembly; interparticle gaps; surface enhanced Raman scattering; chemiresistor; Introduction The development of optical sensors is still following an

• same fabrication tools (colloidal self-assembly) could in principle yield novel nano-enabled devices with both optical and electrical functionalities. A graphical summary describing the envisaged DEOS concept is given in Figure 1. An array of noble metal colloids assembled between electrodes on a solid

• stability of the folic acid-capped AuNPs in the aqueous system [8]. Assembly of gold nanoparticles on IDE In the conventional way, convective self-assembly (CSA) was used for growing thin colloidal films on planar substrates, by particle deposition from a colloidal suspension along the substrate–liquid–air

Two step formation of metal aggregates by surface X-ray radiolysis under Langmuir monolayers: 2D followed by 3D growth

• Smita Mukherjee,
• Marie-Claude Fauré,
• Michel Goldmann and
• Philippe Fontaine

Beilstein J. Nanotechnol. 2015, 6, 2406–2411, doi:10.3762/bjnano.6.247

• -assembly properties of surfactant molecules in solution. By the choice of the organic molecule, we can tune the surface charge of the formed self-assembly in order to attract the ions in their vicinity. Therefore, we expect that during the irradiation process, the aggregation of the reduced atoms takes

• more recently X-rays [4][5] are used to perform the irradiation. In order to increase the variety of shapes of the formed nano-objects and to vary their properties, we have proposed a technique that brings together the advantages of both – the radiolytic reduction of metal ions to atoms and the self

Nanostructured surfaces by supramolecular self-assembly of linear oligosilsesquioxanes with biocompatible side groups

• Maria Nowacka,
• Anna Kowalewska and
• Tomasz Makowski

Beilstein J. Nanotechnol. 2015, 6, 2377–2387, doi:10.3762/bjnano.6.244

• structure of the applied oligomers and primers. Keywords: atomic force microscopy; hydrophilicity; oligosilsesquioxanes; self-assembly; surface; Introduction The modification of surface properties can be used as a versatile tool in materials engineering for biological and medical purposes [1][2][3][4

Self-organization of gold nanoparticles on silanated surfaces

• Htet H. Kyaw,
• Salim H. Al-Harthi,
• Azzouz Sellai and
• Joydeep Dutta

Beilstein J. Nanotechnol. 2015, 6, 2345–2353, doi:10.3762/bjnano.6.242

• Molecular self-assembly or self-organization is a technique which is widely used for the spontaneous arrangement of nanomaterials. Coupling agents such as thiol-terminated, amine-terminated, alkyl-terminated and phenyl-terminated silanes on metal nanoparticles (so called adsorbates) attach on various

• and deposition time [6]. To achieve NH2 groups as the interface between APTES molecule and nanoparticles is a major issue in silanization processes. During the self-assembly process, terminal amine (NH2) can be folded to form hydrogen bonds with free silanol groups, which leads to multilayer

• -assembled orientation of APTES molecules on glass substrate surface Four possible types of interfaces between an APTES molecule and the glass surface can be obtained during self-assembly as shown in Figure 2. One or two of the ethoxy groups from the APTES molecules bonded with hydroxylated glass (type I and