Beilstein J. Nanotechnol.2018,9, 301–310, doi:10.3762/bjnano.9.30
. This result cannot be explained by hydrodynamic effects, including the asymmetric vertical position of the particles in the gap. Instead we attribute it to an electroviscous effect. For strong confinement of less than 120 nm gap distance, we detect the onset of subdiffusion, which can be correlated to
the motion of the particles along high-gap-distance paths.
Keywords: Au nanospheres; confinement; nanofluidics; subdiffusion; Introduction
A fundamental understanding of the motion of micrometer- and nanometer-scaled objects in nanofluidic confinement is important for many biological and technical
). The fit parameter α indicating subdiffusion for α < 1 is shown in Figure 4b. At a confinement d < 120 nm, a scale-dependent diffusion coefficient is observed, see also the increasing deviation of the dashed and solid lines in Figure 4a. This effect has been attributed to the presence of lateral
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Figure 1:
(a) The optical setup consist of a laser, an acousto-optic deflector (AOD), and a telecentric syste...