Organic and inorganic–organic thin film structures by molecular layer deposition: A review

• Pia Sundberg and
• Maarit Karppinen

Beilstein J. Nanotechnol. 2014, 5, 1104–1136, doi:10.3762/bjnano.5.123

Photocatalysis

• Rong Xu

Beilstein J. Nanotechnol. 2014, 5, 1071–1072, doi:10.3762/bjnano.5.119

• bismuth vanadium oxide cluster exemplifies these characteristics. Besides solar fuel production, photocatalysis has a long history in water treatment. In this Thematic Series, there is also a report on the latest development in the utilization of mesoporous cerium oxide for visible light-driven dye

Designing magnetic superlattices that are composed of single domain nanomagnets

• Derek M. Forrester,
• Feodor V. Kusmartsev and
• Endre Kovács

Beilstein J. Nanotechnol. 2014, 5, 956–963, doi:10.3762/bjnano.5.109

• have been successfully doped (with, for example, vanadium or chromium [2]) to lower the saturation magnetization of the compound. In doing so the energy barrier between stable states of the magnetization remains at a surmountable level. This is of high significance for designing magnetic logic elements

Visible light photooxidative performance of a high-nuclearity molecular bismuth vanadium oxide cluster

• Johannes Tucher and
• Carsten Streb

Beilstein J. Nanotechnol. 2014, 5, 711–716, doi:10.3762/bjnano.5.83

• Johannes Tucher Carsten Streb Ulm University, Institute of Inorganic Chemistry I, Albert-Einstein-Allee 11, 89081 Ulm, Germany 10.3762/bjnano.5.83 Abstract The visible light photooxidative performance of a new high-nuclearity molecular bismuth vanadium oxide cluster, H3[{Bi(dmso)3}4V13O40], is

• turnover numbers (TON ca. 1200) and turnover frequencies up to TOF ca. 3.44 min−1 are observed, illustrating the practical applicability of the cluster species. Keywords: photocatalysis; photooxidation; polyoxometalate; self-assembly; vanadium oxide; Introduction The bottom-up self-assembly of molecular

• ]. POMs are anionic metal oxide clusters formed primarily from early transition metals, mainly vanadium, molybdenum and tungsten [8]. The cluster assembly proceeds in solution by oligo-condensation reactions between reactive fragments, often by using templates to control the final cluster architecture [9

Artificial sunlight and ultraviolet light induced photo-epoxidation of propylene over V-Ti/MCM-41 photocatalyst

• Van-Huy Nguyen,
• Shawn D. Lin,
• Jeffrey Chi-Sheng Wu and
• Hsunling Bai

Beilstein J. Nanotechnol. 2014, 5, 566–576, doi:10.3762/bjnano.5.67

• charge transfer band of tetra-coordinated vanadium in the V5+ state [32]. The overlap of catalyst absorbance and light emission spectra, in the wavelength range from 260 to 380 nm, is the main contribution to the photo-reaction activity. Figure 2 shows the low-angle XRD pattern of V-Ti/MCM-41

• distinctive feature of MCM-41. The pore diameters of catalyst estimated from TEM was approximately 3 nm. We previously proposed that the titanium in V-Ti/MCM-41 should be Ti4+ with a tetrahedral coordination [17]. The K-edge XANES of vanadium (Figure 4) suggests its oxidation state to be V5+. A possible local

• (XANES) of the vanadium K-edge was carried out with synchrotron radiation at the beam line 16A, National Synchrotron Radiation Research Center, Taiwan. The standard metal foil and V oxides (V2O5 and V2O3) powders were used as references. High resolution transmission electron microscope (HRTEM) was

Functionalization of vertically aligned carbon nanotubes

• Eloise Van Hooijdonk,
• Carla Bittencourt,
• Rony Snyders and
• Jean-François Colomer

Beilstein J. Nanotechnol. 2013, 4, 129–152, doi:10.3762/bjnano.4.14

• without a coaxial layer of vanadium oxide (V2O5) as cathode and anode, respectively. Due to their unique properties (e.g., large surface area, electrical conductivity, regular pore structure, electrolyte accessibility, charge transport), they are candidates for replacing traditional electrodes. Instead of

Strong spin-filtering and spin-valve effects in a molecular V–C₆₀–V contact

• Mohammad Koleini and
• Mads Brandbyge

Beilstein J. Nanotechnol. 2012, 3, 589–596, doi:10.3762/bjnano.3.69

• and magnetic adatom on a Cu(111) surface using first-principles calculations. For the case of a vanadium tip/adatom, we demonstrate how spin coupling between the magnetic V atoms, mediated by the C60, can be observed in the electronic transport, which display a strong spin-filtering effect, allowing

• –Co system on a Cu(001) surface contacted by a Cr tip [23]. The magnetic properties and spin transport have also been calculated for organometallic “multidecker” wires, where magnetic atoms are sandwiched between organic parts [24]. Multidecker systems involving vanadium are very promising due to

• the magnetic ligand atoms. Here, we employ first-principles calculations to predict the spin transport through a spintronic model system consisting of a C60 molecule contacted by magnetic atoms in an STM setup. In particular, we predict that vanadium is a magnetic material which will show pronounced

Switching adhesion forces by crossing the metal–insulator transition in Magnéli-type vanadium oxide crystals

• Bert Stegemann,
• Matthias Klemm,
• Siegfried Horn and
• Mathias Woydt

Beilstein J. Nanotechnol. 2011, 2, 59–65, doi:10.3762/bjnano.2.8

• , Universitätsstr. 1, D-86135 Augsburg, Germany 10.3762/bjnano.2.8 Abstract Magnéli-type vanadium oxides form the homologous series VnO2n-1 and exhibit a temperature-induced, reversible metal–insulator first order phase transition (MIT). We studied the change of the adhesion force across the transition temperature

• between the cleavage planes of various vanadium oxide Magnéli phases (n = 3 … 7) and spherical titanium atomic force microscope (AFM) tips by systematic force–distance measurements with a variable-temperature AFM under ultrahigh vacuum conditions (UHV). The results show, for all investigated samples, that

• crossing the transition temperatures leads to a distinct change of the adhesion force. Low adhesion corresponds consistently to the metallic state. Accordingly, the ability to modify the electronic structure of the vanadium Magnéli phases while maintaining composition, stoichiometry and crystallographic