Carbenoid-mediated nucleophilic “hydrolysis” of 2-(dichloromethylidene)-1,1,3,3-tetramethylindane with DMSO participation, affording access to one-sidedly overcrowded ketone and bromoalkene descendants§

Rudolf Knorr, Thomas Menke, Johannes Freudenreich and Claudio Pires
Beilstein J. Org. Chem. 2014, 10, 307–315. https://doi.org/10.3762/bjoc.10.28

Supporting Information

Supporting Information File 1: Alternative synthesis of ketone 38b; preparation of [2-D]10, 33, 39a, 39b, 42b, and 43; FBW ring expansion of carbenoid 12; SNV reactions of 12 with PhCH2K and with KN(SiMe3)2.
Format: PDF Size: 234.5 KB Download

Cite the Following Article

Carbenoid-mediated nucleophilic “hydrolysis” of 2-(dichloromethylidene)-1,1,3,3-tetramethylindane with DMSO participation, affording access to one-sidedly overcrowded ketone and bromoalkene descendants§
Rudolf Knorr, Thomas Menke, Johannes Freudenreich and Claudio Pires
Beilstein J. Org. Chem. 2014, 10, 307–315. https://doi.org/10.3762/bjoc.10.28

How to Cite

Knorr, R.; Menke, T.; Freudenreich, J.; Pires, C. Beilstein J. Org. Chem. 2014, 10, 307–315. doi:10.3762/bjoc.10.28

Download Citation

Citation data can be downloaded as file using the "Download" button or used for copy/paste from the text window below.
Citation data in RIS format can be imported by all major citation management software, including EndNote, ProCite, RefWorks, and Zotero.

Citations to This Article

Up to 20 of the most recent references are displayed here.

Scholarly Works

  • Gusarova, N. K.; Trofimov, B. A. Organophosphorus chemistry based on elemental phosphorus: advances and horizons. Russian Chemical Reviews 2020, 89, 225–249. doi:10.1070/rcr4903
  • Knorr, R.; Menke, T.; Hennig, K.-O.; Freudenreich, J.; Böhrer, P.; Schubert, B. Ring expansion and vinylic nucleophilic substitution competing for (tert-alkyl)2CC(Li)–Cl in carbenoid chain processes ☆. Tetrahedron 2014, 70, 2703–2710. doi:10.1016/j.tet.2014.03.004
Other Beilstein-Institut Open Science Activities