Synthesis of quinoline-3-carboxylates by a Rh(II)-catalyzed cyclopropanation-ring expansion reaction of indoles with halodiazoacetates

Scholarly Works

• Chen, Y.; Feng, G.; Shen, Y.; Liu, Z.; Sun, C.; Ji, W.; Huang, H.; Pang, S. Electrochemical Indole Skeletal Editing via Single-Carbon Atom Insertion. Journal of the American Chemical Society 2026. doi:10.1021/jacs.5c19912
• Wang, Y.; Zhou, X.; Ke, X.; Wang, Y.; Ni, S.; Shi, F. Skeletal Editing of Hydroxyl Oxindoles via Organoiodine‐Catalyzed Oxygen Atom Insertion Reaction. Angewandte Chemie 2025. doi:10.1002/ange.202519764
• Wang, Y.; Zhou, X.-Z.; Ke, X.-Y.; Wang, Y.; Ni, S.-F.; Shi, F. Skeletal Editing of Hydroxyl Oxindoles via Organoiodine-Catalyzed Oxygen Atom Insertion Reaction. Angewandte Chemie (International ed. in English) 2025, e19764. doi:10.1002/anie.202519764
• Spreckelmeyer, N.; Kim, J.; Lammert, J.; Horst, E. S.; Zhang, J.; Studer, A. Reductive rearrangement of substituted quinolines to 2,3-disubstituted indoles enabled by water activation. Chemical science 2025. doi:10.1039/d5sc08793g
• Kafle, P.; Herndon, D.; Sharma, I. Sulfenylcarbenes and sulfenylnitrenes in organic synthesis. Chemical Society reviews 2025, 54, 10344–10362. doi:10.1039/d5cs00278h
• Wang, Z.; Xu, H.; Han, X.; Zhu, J. Indole ring expansion into quinolines with TMSCCl3/TMSCBr3. Chemical communications (Cambridge, England) 2025, 61, 16400–16403. doi:10.1039/d5cc04994f
• Yang, Y.; Liu, H.; Wang, Z.; Julaiti, Y.; Lu, Y.; Wan, B.; Wu, X.; Chen, Q. Construction of meta ‐Disubstituted Triaryls via Iodine‐Catalyzed Oxidative Aromatization Coupling of Cycloalkenes with Indoles. Advanced Synthesis & Catalysis 2025, 367. doi:10.1002/adsc.70130
• Zhou, G.; Yao, Y.; He, X.; Zhang, W.; Liu, S.; Shen, X. Modular synthesis of fluoroalkyl-substituted cyclopropenes with fluoroalkylacylsilanes as carbynyl cation equivalents. Chem 2025, 102721. doi:10.1016/j.chempr.2025.102721
• Esteve Guasch, J.; Pal, D.; Suero, M. G. Catalytic Oxidative Ligand Transfer of Rh-Carbynoids and Alkyl Iodides. Journal of the American Chemical Society 2025, 147, 31444–31449. doi:10.1021/jacs.5c09559
• Sarró, P.; Díaz, N.; Esteve Guasch, J.; Teo, W. J.; Suero, M. G. Rh-catalysed single-carbon insertion to 1,3-dienes. Chemical science 2025, 16, 13042–13047. doi:10.1039/d5sc03161c
• Morimoto, T.; Nishimoto, Y.; Suzuki-Osborne, T.; Chong, S.-G.; Okamoto, K.; Yoneda, T.; Kikuchi, A.; Yokogawa, D.; Atobe, M.; Shida, N. Electrochemical Single-Carbon Insertion via Distonic Radical Cation Intermediates. Journal of the American Chemical Society 2025, 147, 25635–25641. doi:10.1021/jacs.5c06798
• Li, B.; Alfonso, V. G.; Puggioli, A.; Solé-Daura, A.; Maseras, F.; Suero, M. G. Rh-Catalyzed Atroposelective Single-Carbon Insertion. Journal of the American Chemical Society 2025, 147, 24206–24212. doi:10.1021/jacs.5c06139
• Köhler, T.; Fuhr, O.; Bräse, S. [2.2]Paracyclophane-substituted quinolines by skeletal editing strategies. Organic Chemistry Frontiers 2025, 12, 3546–3550. doi:10.1039/d5qo00505a
• Pang, Y.; Wang, E.; Ye, J. Photocatalytic Boron Insertion into Thiaarenes via Boryl Radicals. Angewandte Chemie 2025, 137. doi:10.1002/ange.202508379
• Pang, Y.; Wang, E.; Ye, J. Photocatalytic Boron Insertion into Thiaarenes via Boryl Radicals. Angewandte Chemie (International ed. in English) 2025, 64, e202508379. doi:10.1002/anie.202508379
• Zhang, X.; Zhu, Y.; Jiang, W.; Zhang, Z.; Jiang, Y. Skeletal Editing of 6‐(Hetero)arenes via Single‐Carbon‐Atom Insertion. Advanced Synthesis & Catalysis 2025, 367. doi:10.1002/adsc.202500336
• Liu, L.; Tian, M.; Lang, Z.; Wang, Y.; He, C.; Chen, Y.; Han, W. Indole‐Quinoline Transmutation Enabled by a Formal Rhodium Carbynoid. Angewandte Chemie 2025, 137. doi:10.1002/ange.202501966
• Liu, L.-J.; Tian, M.-Y.; Lang, Z.-Y.; Wang, Y.-L.; He, C.-Y.; Chen, Y.-Z.; Han, W.-Y. Indole-Quinoline Transmutation Enabled by a Formal Rhodium Carbynoid. Angewandte Chemie (International ed. in English) 2025, 64, e202501966. doi:10.1002/anie.202501966
• Tyagi, A.; Gaur, K.; Goswami, A.; Seal, A.; Joddar, M.; Jindal, G. A combined experimental and computational study reveals a crossover between conventional cross-coupling and carbene insertion pathways in a Pd catalyzed C(sp2)-H insertion. Chemical science 2025, 16, 6793–6804. doi:10.1039/d5sc00777a
• Kafle, P.; Herndon, D.; Sharma, I. Sulfenylcarbene-Mediated Carbon Atom Insertion for the Late-Stage Functionalization of N-Heterocycles. Journal of the American Chemical Society 2025, 147, 13824–13832. doi:10.1021/jacs.5c02012

Explore citations to this article at