Enantioconvergent catalysis

Scholarly Works

• Han, J.; Liu, X.; Jin, H.; Guo, P.; Xu, L.; Li, P.; Zhan, M. Iridium-catalyzed doubly stereoconvergent allylic alkylation of racemic α-boryl organozinc reagents. Chem Catalysis 2024, 4, 100858. doi:10.1016/j.checat.2023.100858
• Carrillo-Cabrera, W.; Simon, P.; Schmidt, M.; König, M.; Borrmann, H.; Winkelmann, A.; Burkhardt, U.; Grin, Y. Enantiomorph conversion in single crystals of the Weyl semimetal CoSi. Communications Materials 2023, 4. doi:10.1038/s43246-023-00434-8
• Mao, R.; Taylor, D. M.; Wackelin, D. J.; Rogge, T.; Wu, S. J.; Sicinski, K. M.; Houk, K. N.; Arnold, F. H. Biocatalytic, stereoconvergent alkylation of (Z/E)-trisubstituted silyl enol ethers. Nature Synthesis 2023, 3, 256–264. doi:10.1038/s44160-023-00431-2
• Usman, F. O.; Gogoi, A. R.; Mixdorf, J. C.; Gutierrez, O.; Nguyen, H. M. Rhodium‐Catalyzed Asymmetric Synthesis of 1,2‐Disubstituted Allylic Fluorides. Angewandte Chemie 2023, 135. doi:10.1002/ange.202314843
• Usman, F. O.; Gogoi, A. R.; Mixdorf, J. C.; Gutierrez, O.; Nguyen, H. M. Rhodium-Catalyzed Asymmetric Synthesis of 1,2-Disubstituted Allylic Fluorides. Angewandte Chemie (International ed. in English) 2023, 62, e202314843. doi:10.1002/anie.202314843
• Yus, M.; Nájera, C.; Foubelo, F.; Sansano, J. M. Metal-Catalyzed Enantioconvergent Transformations. Chemical reviews 2023, 123, 11817–11893. doi:10.1021/acs.chemrev.3c00059
• Ričko, S.; Bitsch, R. S.; Kaasik, M.; Otevřel, J.; Højgaard Madsen, M.; Keimer, A.; Jørgensen, K. A. Enantioconvergent 6π Electrocyclization Enabled by Photoredox Racemization. Journal of the American Chemical Society 2023, 145, 20913–20926. doi:10.1021/jacs.3c06227
• Arachchi, M. K.; Schaugaard, R. N.; Schlegel, H. B.; Nguyen, H. M. Scope and Mechanistic Probe into Asymmetric Synthesis of α-Trisubstituted-α-Tertiary Amines by Rhodium Catalysis. Journal of the American Chemical Society 2023, 145, 19642–19654. doi:10.1021/jacs.3c04211
• Sun, T.; Zhang, Z.; Su, Y.; Cao, H.; Zhou, Y.; Luo, G.; Cao, Z.-C. Nickel-Catalyzed Enantioconvergent Transformation of Anisole Derivatives via Cleavage of C-OMe Bond. Journal of the American Chemical Society 2023, 145, 15721–15728. doi:10.1021/jacs.3c05845
• Zhou, B.; Ye, C.; Meggers, E. N‐Boc‐Protected α‐Amino Acids by 1,3‐Migratory Nitrene C(sp3)−H Insertion. European Journal of Organic Chemistry 2023, 26. doi:10.1002/ejoc.202300296
• Cui, T.; Ye, C.; Thelemann, J.; Jenisch, D.; Meggers, E. Enantioselective and Enantioconvergent Iron‐Catalyzed C(sp3)‐H Aminations to Chiral 2‐Imidazolidinones. Chinese Journal of Chemistry 2023, 41, 2065–2070. doi:10.1002/cjoc.202300162
• Ozawa, Y. Modification of QuinoxP*-Type Bisphosphine Ligands for High-Performance Asymmetric Boryl Substitution of Racemic Allyl Electrophiles. Springer Theses; Springer Nature Singapore, 2023; pp 19–112. doi:10.1007/978-981-99-1098-4_2
• Mao, R.; Wackelin, D. J.; Jamieson, C. S.; Rogge, T.; Gao, S.; Das, A.; Taylor, D. M.; Houk, K. N.; Arnold, F. H. Enantio- and Diastereoenriched Enzymatic Synthesis of 1,2,3-Polysubstituted Cyclopropanes from (Z/E)-Trisubstituted Enol Acetates. 2023. doi:10.21203/rs.3.rs-2802333/v1
• Yang, J.; Massaro, L.; Hu, W.; Peters, B. B. C.; Birke, N.; Chantana, C.; Singh, T.; Andersson, P. G. Iridium-Catalyzed Double Convergent 1,3-Rearrangement/Hydrogenation of Allylic Alcohols. Journal of the American Chemical Society 2022, 145, 626–633. doi:10.1021/jacs.2c11289
• Gais, H. Palladium‐ and Iridium‐Catalyzed Deracemization of Allylic Oxygen Compounds with Oxygen Nucleophiles. European Journal of Organic Chemistry 2022, 2022. doi:10.1002/ejoc.202201016
• Du, J.-Y.; Balan, T.; Claridge, T. D. W.; Smith, M. D. Counterion-Mediated Enantioconvergent Synthesis of Axially Chiral Medium Rings. Journal of the American Chemical Society 2022, 144, 14790–14797. doi:10.1021/jacs.2c05485
• Toda, Y.; Sato, K.; Sato, K.; Nagasaki, K.; Nakajima, H.; Kikuchi, A.; Sukegawa, K.; Suga, H. Asymmetric Cycloadditions of Acyclic Carbonyl Ylides with Aldehydes Catalyzed by a Chiral Binaphthyldiimine-Ni(II) Complex: Enantioselective Synthesis of 1,3-Dioxolanes and Mechanistic Studies by DFT Calculations. Organic letters 2022, 24, 4739–4744. doi:10.1021/acs.orglett.2c01682
• Pu, X.; Dang, Q.-D.; Yang, L.; Zhang, X.; Niu, D. Doubly stereoconvergent construction of vicinal all-carbon quaternary and tertiary stereocenters by Cu/Mg-catalyzed propargylic substitution. Nature communications 2022, 13, 2457. doi:10.1038/s41467-022-29986-y
• Khatua, A.; Shyamal, P.; Pal, S.; Mondal, A.; Bisai, A. Concise total syntheses of bis(cyclotryptamine) alkaloids via thio-urea catalyzed one-pot sequential Michael addition. Chemical communications (Cambridge, England) 2022, 58, 3929–3932. doi:10.1039/d2cc01008a
• Papadopulu, Z.; Kazeroonian, N.; Irran, E.; Oestreich, M. One out of Four: Kinetic Resolution of Stereoisomeric Mixtures of Secondary Alcohols with a Quaternary Carbon Atom in the β-Position by Cu-H-Catalyzed Enantioselective Silylation. ACS organic & inorganic Au 2021, 2, 164–168. doi:10.1021/acsorginorgau.1c00050

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