Enantioconvergent catalysis

Scholarly Works

• Lan, S.; Luo, Y.; Jiang, C.; Xu, C.; Zhao, L.; Lei, X.; Dong, J.; Liu, J.; Yang, S.; Zhang, Q.; Fang, X. Ruthenium-Catalyzed Diversified Kinetic Resolutions of Diaryl-Substituted Cyclobutenones via Asymmetric Transfer Hydrogenation. Angewandte Chemie (International ed. in English) 2025, e202512543. doi:10.1002/anie.202512543
• Lan, S.; Luo, Y.; Jiang, C.; Xu, C.; Zhao, L.; Lei, X.; Dong, J.; Liu, J.; Yang, S.; Zhang, Q.; Fang, X. Ruthenium‐Catalyzed Diversified Kinetic Resolutions of Diaryl‐Substituted Cyclobutenones via Asymmetric Transfer Hydrogenation. Angewandte Chemie 2025. doi:10.1002/ange.202512543
• Boddie, E. C.; Cooper, P.; Hammarback, L. A.; Mudd, R. J.; Feron, L. J.; Bower, J. F. The Discovery and Development of an Iridium-Catalyzed N→C Alkyl Transfer Reaction. Angewandte Chemie (International ed. in English) 2025, 64, e202509193. doi:10.1002/anie.202509193
• Boddie, E. C.; Cooper, P.; Hammarback, L. A.; Mudd, R. J.; Feron, L. J.; Bower, J. F. The Discovery and Development of an Iridium‐Catalyzed N→C Alkyl Transfer Reaction. Angewandte Chemie 2025, 137. doi:10.1002/ange.202509193
• Zhao, W.; Shen, Y.; Wu, X.; Xia, T.; Hu, J.; Qu, J.; Chen, Y. Cobalt-Catalyzed Asymmetric Reductive Coupling of Isocyanates with Tertiary Alkyl Halides for Sterically Bulky Chiral Amide Synthesis. Journal of the American Chemical Society 2025, 147, 27155–27164. doi:10.1021/jacs.5c06669
• Khatua, A.; Shyamal, P.; Nandy, M.; Mondal, D.; Shaw, K.; Bisai, A. Synthetic Approaches to Dimeric and Oligomeric Hexahydropyrrolo[2,3-b]indole Alkaloids. Chemistry, an Asian journal 2025, 20, e202401424. doi:10.1002/asia.202401424
• Preinfalk, A.; Oost, R.; Menger, M. F. S. J.; Simaan, M.; Lemouzy, S.; Senoner, S.; Shaaban, S.; Maryasin, B.; González, L.; Maulide, N. Enantioconvergent Negishi Cross-Couplings of Racemic Secondary Organozinc Reagents to Access Privileged Scaffolds: A Combined Experimental and Theoretical Study. Angewandte Chemie (International ed. in English) 2024, 63, e202414868. doi:10.1002/anie.202414868
• Preinfalk, A.; Oost, R.; Menger, M. F. S. J.; Simaan, M.; Lemouzy, S.; Senoner, S.; Shaaban, S.; Maryasin, B.; González, L.; Maulide, N. Enantiokonvergente Negishi‐Kreuzkupplungen von Racemischen Sekundären Organozink‐Reagenzien zur Herstellung Privilegierter Gerüste: Eine Kombinierte Experimentelle und Theoretische Studie. Angewandte Chemie 2024, 136. doi:10.1002/ange.202414868
• Vu, J.; Haug, G. C.; Li, Y.; Zhao, B.; Chang, C. J.; Paton, R. S.; Dong, Y. Enantioconvergent Cross-Nucleophile Coupling: Copper-Catalyzed Deborylative Cyanation. Angewandte Chemie (International ed. in English) 2024, 63, e202408745. doi:10.1002/anie.202408745
• Vu, J.; Haug, G. C.; Li, Y.; Zhao, B.; Chang, C. J.; Paton, R. S.; Dong, Y. Enantioconvergent Cross‐Nucleophile Coupling: Copper‐Catalyzed Deborylative Cyanation. Angewandte Chemie 2024, 136. doi:10.1002/ange.202408745
• Bennett, S. H.; Bestwick, J. S.; Demertzidou, V. P.; Jones, D. J.; Jones, H. E.; Richard, F.; Homer, J. A.; Street-Jeakings, R.; Tiberia, A. F.; Lawrence, A. L. Stereoretentive enantioconvergent reactions. Nature chemistry 2024, 16, 1177–1183. doi:10.1038/s41557-024-01504-1
• Li, R.; Hu, Z.; Shuai, Z.; Yang, X. Catalytic Enantioconvergent C(sp3)−N Coupling to Access Chiral Amines: A Concept Review. ChemCatChem 2024, 16. doi:10.1002/cctc.202400049
• Han, J.; Liu, X.; Jin, H.; Guo, P.; Xu, L.; Li, P.; Zhan, M. Iridium-catalyzed doubly stereoconvergent allylic alkylation of racemic α-boryl organozinc reagents. Chem Catalysis 2024, 4, 100858. doi:10.1016/j.checat.2023.100858
• Carrillo-Cabrera, W.; Simon, P.; Schmidt, M.; König, M.; Borrmann, H.; Winkelmann, A.; Burkhardt, U.; Grin, Y. Enantiomorph conversion in single crystals of the Weyl semimetal CoSi. Communications Materials 2023, 4. doi:10.1038/s43246-023-00434-8
• Mao, R.; Taylor, D. M.; Wackelin, D. J.; Wu, S. J.; Sicinski, K. M.; Arnold, F. H. Biocatalytic, Stereoconvergent Alkylation of (Z/E)-Trisubstituted Silyl Enol Ethers. Nature synthesis 2023, 3, 256–264. doi:10.1038/s44160-023-00431-2
• Usman, F. O.; Gogoi, A. R.; Mixdorf, J. C.; Gutierrez, O.; Nguyen, H. M. Rhodium‐Catalyzed Asymmetric Synthesis of 1,2‐Disubstituted Allylic Fluorides. Angewandte Chemie 2023, 135. doi:10.1002/ange.202314843
• Usman, F. O.; Gogoi, A. R.; Mixdorf, J. C.; Gutierrez, O.; Nguyen, H. M. Rhodium-Catalyzed Asymmetric Synthesis of 1,2-Disubstituted Allylic Fluorides. Angewandte Chemie (International ed. in English) 2023, 62, e202314843. doi:10.1002/anie.202314843
• Yus, M.; Nájera, C.; Foubelo, F.; Sansano, J. M. Metal-Catalyzed Enantioconvergent Transformations. Chemical reviews 2023, 123, 11817–11893. doi:10.1021/acs.chemrev.3c00059
• Ričko, S.; Bitsch, R. S.; Kaasik, M.; Otevřel, J.; Højgaard Madsen, M.; Keimer, A.; Jørgensen, K. A. Enantioconvergent 6π Electrocyclization Enabled by Photoredox Racemization. Journal of the American Chemical Society 2023, 145, 20913–20926. doi:10.1021/jacs.3c06227
• Arachchi, M. K.; Schaugaard, R. N.; Schlegel, H. B.; Nguyen, H. M. Scope and Mechanistic Probe into Asymmetric Synthesis of α-Trisubstituted-α-Tertiary Amines by Rhodium Catalysis. Journal of the American Chemical Society 2023, 145, 19642–19654. doi:10.1021/jacs.3c04211

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