Supporting Information
| Supporting Information File 1: Experimental spectra for compound 2: FTIR, NMR (1H, 13C, DEPT, HMBC, HSQC, NOESY), ESIMS and the proposed fragmentation mechanism for 2 and 12. | ||
| Format: PDF | Size: 566.2 KB | Download |
| Supporting Information File 2: Calculations of the NMR chemical shifts for the assignment of the configuration at carbon atom 3A in compound 2. | ||
| Format: GIF | Size: 1.4 MB | Download |
| Supporting Information File 3: Calculations for Strecker degradation via zwitterions in the case of glyoxal and ninhydrin. | ||
| Format: PDF | Size: 747.1 KB | Download |
| Supporting Information File 4: Calculated reaction (IRC path) via the transition state 6g → 11. | ||
| Format: PDF | Size: 919.4 KB | Download |
| Supporting Information File 5: Calculated reaction (IRC path) via the transition state 6g → 8. | ||
| Format: GIF | Size: 4.3 MB | Download |
| Supporting Information File 6: Calculated reaction (IRC path) via the transition state 7a → 8. | ||
| Format: GIF | Size: 3.0 MB | Download |
| Supporting Information File 7: Calculated reaction (IRC path) via the transition state 7b → 10. | ||
| Format: GIF | Size: 1.0 MB | Download |
| Supporting Information File 8: Calculated reaction (IRC path) via the transition state glyoxal/glycine, CO2 loss. | ||
| Format: GIF | Size: 4.2 MB | Download |
| Supporting Information File 9: Calculated reaction (IRC path) via the transition state imine ninhydrine/glycine, zwitterion, azomethine ylide formation. | ||
| Format: GIF | Size: 2.8 MB | Download |
| Supporting Information File 10: Calculated reaction (IRC path) via the transition state imine ninhydrine/glycine, CO2 loss. | ||
| Format: GIF | Size: 1.2 MB | Download |
Cite the Following Article
Strecker degradation of amino acids promoted by a camphor-derived sulfonamide
M. Fernanda N. N. Carvalho, M. João Ferreira, Ana S. O. Knittel, Maria da Conceição Oliveira, João Costa Pessoa, Rudolf Herrmann and Gabriele Wagner
Beilstein J. Org. Chem. 2016, 12, 732–744.
https://doi.org/10.3762/bjoc.12.73
How to Cite
Carvalho, M. F. N. N.; Ferreira, M. J.; Knittel, A. S. O.; Oliveira, M. d. C.; Costa Pessoa, J.; Herrmann, R.; Wagner, G. Beilstein J. Org. Chem. 2016, 12, 732–744. doi:10.3762/bjoc.12.73
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Presentation Graphic
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